{"id":48752,"date":"2023-08-24T08:30:53","date_gmt":"2023-08-24T00:30:53","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48752"},"modified":"2023-08-07T10:31:39","modified_gmt":"2023-08-07T02:31:39","slug":"%e5%85%b0%e5%b7%9e%e5%8c%96%e7%89%a9%e6%89%80%e5%88%98%e8%b6%85%e5%9b%a2%e9%98%9fchem%ef%bc%9a%e5%88%a9%e7%94%a8%c2%b9%e2%81%b0bf%e2%82%83%e5%90%88%e6%88%90%e9%ab%98%e4%b8%b0%e5%ba%a6%c2%b9%e2%81%b0b","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%85%b0%e5%b7%9e%e5%8c%96%e7%89%a9%e6%89%80%e5%88%98%e8%b6%85%e5%9b%a2%e9%98%9fchem%ef%bc%9a%e5%88%a9%e7%94%a8%c2%b9%e2%81%b0bf%e2%82%83%e5%90%88%e6%88%90%e9%ab%98%e4%b8%b0%e5%ba%a6%c2%b9%e2%81%b0b\/","title":{"rendered":"\u5170\u5dde\u5316\u7269\u6240\u5218\u8d85\u56e2\u961fChem\uff1a\u5229\u7528\u00b9\u2070BF\u2083\u5408\u6210\u9ad8\u4e30\u5ea6\u00b9\u2070B\u8054\u787c\u8bd5\u5242"},"content":{"rendered":"<p>\u672c\u6587\u6765\u6e90 | \u5c0f\u67ef\u5316\u5b66<\/p>\n<p>&nbsp;<\/p>\n<section>\n<section>\n<section>\n<section>\n<section>2023\u5e747\u670824\u65e5\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u7269\u6240\u7fb0\u57fa\u5408\u6210\u4e0e\u9009\u62e9\u6c27\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5218\u8d85\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u5728<em><strong>Chem<\/strong><\/em><strong>\u671f\u520a<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cEnriched\u00a0<sup>10<\/sup>B-diboron reagents synthesis from\u00a0<sup>10<\/sup>BF<sub>3<\/sub>\u201d\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u4ed6\u4eec\u5229\u7528<sup>10<\/sup>BF<sub>3<\/sub>\u5408\u6210\u9ad8\u4e30\u5ea6<sup>10<\/sup>B\u8054\u787c\u8bd5\u5242\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u5408\u6210\u5bcc\u542b<sup>10<\/sup>B\u7684\u5206\u5b50\u8f7d\u4f53\u3002\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u4e3a<strong>\u5218\u8d85\u7814\u7a76\u5458<\/strong>\uff0c<strong>\u5728\u8bfb\u535a\u58eb\u751f\u9648\u90fd<\/strong>\u4e3a\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\uff0c<strong>\u5728\u8bfb\u535a\u58eb\u751f\u5f90\u826f\u8f69\u548c\u7855\u58eb\u751f\u738b\u5b50\u5b89<\/strong>\u4e5f\u4e3a\u53cd\u5e94\u7684\u5f00\u5c55\u505a\u4e86\u91cd\u8981\u8d21\u732e\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230802\/1690943769603834.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\u764c\u75c7\u88ab\u89c6\u4e3a\u5168\u7403\u516c\u5171\u5a01\u80c1\u3002\u5c3d\u7ba1\u5305\u62ec\u624b\u672f\u3001\u9776\u5411\u836f\u7269\u6cbb\u7597\u3001\u653e\u5c04\u6cbb\u7597\u3001\u514d\u75ab\u6cbb\u7597\u7b49\u5728\u5185\u7684\u5168\u7403\u6cbb\u7597\u6280\u672f\u4e0d\u65ad\u6539\u8fdb\uff0c\u4f46\u764c\u75c7\u7684\u53d1\u75c5\u7387\u548c\u6b7b\u4ea1\u7387\u4ecd\u7136\u5c45\u9ad8\u4e0d\u4e0b\u3002\u787c\u4e2d\u5b50\u4fd8\u83b7\u7597\u6cd5\uff08BNCT\uff09\u662f\u4e00\u79cd\u9009\u62e9\u6027\u9776\u5411\u80bf\u7624\u7684\u7c92\u5b50\u653e\u5c04\u6cbb\u7597\uff0c\u662f\u4e00\u79cd\u57fa\u4e8e\u6838\u7d20\u787c-10\uff08<sup>10<\/sup>B\uff09\u72ec\u7279\u7684\u9ad8\u4e2d\u5b50\u5438\u6536\u6027\u80fd\u7684\u4e8c\u5143\u6cbb\u7597\u65b9\u6cd5\u3002\u5b83\u65e2\u9700\u8981\u9ad8\u8d28\u91cf\u7684\u4e2d\u5b50\u675f\uff0c\u53c8\u9700\u8981\u5177\u6709\u9ad8\u9776\u5411\u6027\u7684\u542b\u787c\u836f\u7269\uff0c\u4e24\u8005\u7f3a\u4e00\u4e0d\u53ef\u3002\u5f53\u80bf\u7624\u7ec6\u80de\u4e2d\u5bcc\u96c6\u4e86\u8db3\u591f\u7684<sup>10<\/sup>B\u6d53\u5ea6\u540e\uff0c\u70ed\u4e2d\u5b50\u8f90\u7167\u4f1a\u9009\u62e9\u6027\u5730\u8bf1\u5bfc<sup>10<\/sup>B\uff08n\uff0c\u03b1\uff0c\u03b3\uff09<sup>7<\/sup>Li\u6838\u53cd\u5e94\uff0c\u4ea7\u751f\u8def\u5f84\u957f\u5ea6\u5c0f\u4e8e10\u5fae\u7c73\u7684\u9ad8\u80fd\u03b1\u7c92\u5b50\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u89e6\u53d1\u80bf\u7624\u7ec6\u80de\u6b7b\u4ea1\uff0c\u540c\u65f6\u907f\u514d\u5bf9\u5065\u5eb7\u7ec4\u7ec7\u7684\u635f\u4f24\uff08\u56fe1A\uff09\u3002BNCT\u7684\u6210\u529f\u9700\u8981\u9ad8\u8d28\u91cf\u7684\u70ed\u4e2d\u5b50\u675f\u548c\u80bf\u7624\u7ec6\u80de\u4e2d\u8db3\u591f\u7684<sup>10<\/sup>B\u6d53\u5ea6\u3002\u8fd9\u4e24\u8005\u90fd\u662f\u5b9e\u73b0\u7ec6\u80de\u6c34\u5e73\u9776\u5411\u6740\u706d\u80bf\u7624\u7684\u5fc5\u4e0d\u53ef\u5c11\u7684\u6761\u4ef6\u3002\u76ee\u524d\uff0cBNCT\u5728\u764c\u75c7\u6cbb\u7597\u4e2d\u4ecd\u9762\u4e34\u6311\u6218\u3002\u968f\u7740\u52a0\u901f\u5668\u4e2d\u5b50\u6e90\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u9ad8\u6548\u5408\u6210\u5bcc\u542b<sup>10<\/sup>B\u7684\u5206\u5b50\u8f7d\u4f53\u6210\u4e3a\u5f00\u53d1BNCT\u836f\u7269\u7684\u5173\u952e\u6311\u6218\u3002\u76ee\u524d\uff0c\u53ea\u6709\u4e24\u79cd\u542b\u787c\u5206\u5b50L-\u787c\u82ef\u4e19\u6c28\u9178\uff08L-BPA\uff09\u548c\u787c\u9178\u94a0\uff08BSH\uff09\u83b7\u5f97\u4e86FDA\u6279\u51c6\u8fdb\u884c\u4e34\u5e8a\u7814\u7a76\uff0c\u5e76\u4e14\u53ea\u6709L-BPA\u57282020\u5e74\u83b7\u5f97\u4e86\u65e5\u672c\u6279\u51c6\u4f5c\u4e3a\u5168\u7403\u9996\u4e2a\u4e0a\u5e02BNCT\u836f\u7269\u3002\u9274\u4e8e\u764c\u75c7\u6cbb\u7597\u7684\u7406\u60f3\u524d\u666f\uff0c\u4e16\u754c\u5404\u5730\u6b63\u5728\u7814\u7a76\u5176\u4ed6\u542b\u787c\u5206\u5b50\u7528\u4e8eBNCT\u7684\u53ef\u80fd\u6027\u3002\u5176\u4e2d\u4e00\u4e2a\u4e3b\u8981\u5de5\u4f5c\u662f\u5408\u6210\u5177\u6709\u9ad8<sup>10<\/sup>B\u5bb9\u91cf\u7684\u787c\u8f7d\u4f53\u3002\u7531\u4e8e\u787c-10\u7684\u81ea\u7136\u4e30\u5ea6\u4ec5\u4e3a19.8\uff05\uff0c\u5982\u82e5\u4f7f\u7528\u81ea\u7136\u4e30\u5ea6\u7684\u787c.\u6e90\u8fdb\u884c\u5408\u6210\uff0c\u5728\u6700\u7ec8\u7684\u8f7d\u4f53\u4e2d\uff0c\u5c06\u542b\u670980.2\uff05\u7684\u4e0d\u5177\u6d3b\u6027\u7684\u787c-11\u6210\u5206\u3002\u5229\u7528\u9ad8\u5ea6\u5bcc\u96c6\u7684<sup>10<\/sup>B\u539f\u6750\u6599\u5408\u6210\u787c\u8f7d\u4f53\u53ef\u4ee5\u5927\u5927\u63d0\u9ad8<sup>10<\/sup>B\u7684\u542b\u91cf\uff0c\u5e76\u51cf\u5c11BNCT\u6cbb\u7597\u4e2d\u787c\u836f\u7684\u5242\u91cf\u3002\u7136\u800c\uff0c\u76ee\u524d\u7f3a\u4e4f\u53ef\u65b9\u4fbf\u7528\u4e8e\u5728\u5404\u79cd\u8f7d\u4f53\u4e2d\u5b89\u88c5<sup>10<\/sup>B\u7684\u9ad8\u4e30\u5ea6<sup>10<\/sup>B\u8bd5\u5242\u3002<\/p>\n<p><sup>10<\/sup>B\u7684\u5bcc\u96c6\u901a\u5e38\u901a\u8fc7\u5de5\u4e1a\u89c4\u6a21\u751f\u4ea7\u4e2d\u7684\u4e09\u6c1f\u5316\u787c\uff08BF<sub>3<\/sub>\uff09\u7684\u5316\u5b66\u4ea4\u6362\u84b8\u998f\u8fdb\u884c\u3002\u4f5c\u4e3a\u9ad8\u4e30\u5ea6<sup>10<\/sup>B\u7684\u8d77\u59cb\u539f\u6750\u6599\uff0c<sup>10<\/sup>BF<sub>3<\/sub>\u4e3b\u8981\u8f6c\u5316\u4e3a<sup>10<\/sup>B(OH)<sub>3<\/sub>\uff0c\u8be5\u5316\u5408\u7269\u4e3b\u8981\u7528\u4e8e\u6838\u5de5\u4e1a\uff08\u56fe1B\uff09\u3002\u65e0\u8bba\u662f<sup>10<\/sup>BF<sub>3<\/sub>\u8fd8\u662f<sup>10<\/sup>B(OH)<sub>3<\/sub>\u90fd\u4e0d\u80fd\u5f88\u597d\u7684\u4f5c\u4e3a\u787c\u5316\u8bd5\u5242\u5c06\u787c-10\u65b9\u4fbf\u7684\u5f15\u5165\u5230\u5927\u91cf\u6709\u673a\u5206\u5b50\u4e2d\u3002\u4ece\u5408\u6210\u7684\u89d2\u5ea6\u6765\u770b\uff0cBF<sub>3<\/sub>\u4e3b\u8981\u88ab\u7528\u4f5c\u8def\u6613\u65af\u9178\uff0c\u800c\u4e0d\u662f\u5c06\u787c\u5f15\u5165\u6709\u673a\u5206\u5b50\u4e2d\u3002\u76ee\u524d\uff0c\u5c06\u5bcc\u96c6\u7684<sup>10<\/sup>B\u65b9\u4fbf\u5730\u5f15\u5165\u5230\u5404\u79cd\u6709\u673a\u5206\u5b50\u4e2d\u4ecd\u662f\u8feb\u5207\u800c\u5177\u6709\u6311\u6218\u7684\u8bfe\u9898\u3002<\/p>\n<p>\u81ea\u4ece\u8054\u787c\u8bd5\u5242\uff0c\u5c24\u5176\u662f\u8054\u787c\u9891\u54ea\u9187\u787c\u9178\u916f\uff08B<sub>2<\/sub>pin<sub>2<\/sub>\uff09\uff0c\u88ab\u5408\u6210\u4ee5\u6765\uff0c\u5404\u79cd\u787c\u5316\u6280\u672f\u84ec\u52c3\u53d1\u5c55\uff0c\u901a\u8fc7\u5229\u7528B<sub>2<\/sub>pin<sub>2<\/sub>\u4f5c\u4e3a\u787c\u5316\u8bd5\u5242\u5408\u6210\u4e86\u5927\u91cf\u7684\u6709\u673a\u787c\u5316\u7269\uff0c\u6781\u5927\u5730\u4fc3\u8fdb\u4e86\u6709\u673a\u787c\u5316\u7269\u5728\u5404\u4e2a\u9886\u57df\u7684\u5e94\u7528\uff08\u56fe1C\uff09\u3002\u8054\u787c\u8bd5\u5242\u5df2\u6210\u4e3a\u76ee\u524d\u5408\u6210\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u5de5\u5177\u8bd5\u5242\u3002\u5728\u73b0\u4ee3\u5408\u6210\u5316\u5b66\u4e2d\uff0cB<sub>2<\/sub>pin<sub>2<\/sub>\u7684\u4f7f\u7528\u4ecd\u7ee7\u7eed\u5feb\u901f\u589e\u957f\uff0c\u7528\u4e8e\u5408\u6210\u5404\u79cd\u6709\u673a\u787c\u5316\u7269\u3002\u6beb\u65e0\u7591\u95ee\uff0c\u6709\u6548\u5408\u6210\u5bcc\u542b<sup>10<\/sup>B\u7684<sup>10<\/sup>B<sub>2<\/sub>pin<sub>2<\/sub>\u548c\u5176\u4ed6\u7684<sup>10<\/sup>B\u8054\u787c\u8bd5\u5242\uff0c\u5c06\u6709\u52a9\u4e8e\u5927\u89c4\u6a21\u5408\u6210\u542b\u6709\u9ad8\u4e30\u5ea6<sup>10<\/sup>B\u7684\u6709\u673a\u787c\u5316\u7269\uff0c\u4ee5\u7528\u4e8eBNCT\u836f\u7269\u7684\u7814\u53d1\uff08\u56fe1D\uff09\u3002\u7136\u800c\uff0c\u76ee\u524d\u8fd8\u6ca1\u6709\u65b9\u6cd5\u5408\u6210\u9ad8\u4e30\u5ea6\u787c-10\u8054\u787c\u8bd5\u5242\u3002\u81ea\u7136\u4e30\u5ea6\u7684B<sub>2<\/sub>pin<sub>2<\/sub>\u901a\u5e38\u7531\u4e09\u6c2f\u5316\u787c\u6216\u4e09\u6eb4\u5316\u787c\u5408\u6210\u800c\u6765\uff0c\u7136\u800c\u76f8\u5e94\u9ad8\u4e30\u5ea6\u787c-10\u7684\u4e09\u6c2f\u5316\u787c\u6216\u4e09\u6eb4\u5316\u787c\u96be\u4ee5\u83b7\u5f97\u3002\u9274\u4e8e\u9ad8\u4e30\u5ea6\u787c-10\u7684\u4e3b\u8981\u6765\u6e90\u662f\u901a\u8fc7\u5206\u79bb\u4e09\u6c1f\u5316\u787c\u83b7\u5f97\u7684\uff0c\u56e0\u6b64\uff0c\u7531<sup>10<\/sup>BF<sub>3<\/sub>\u5408\u6210<sup>10<\/sup>B<sub>2<\/sub>pin<sub>2<\/sub>\u4ee5\u53ca\u5176\u4ed6<sup>10<\/sup>B\u7684\u8054\u787c\u8bd5\u5242\u65e0\u7591\u5177\u6709\u91cd\u8981\u7684\u7814\u7a76\u610f\u4e49\u548c\u5e94\u7528\u4ef7\u503c\uff08\u56fe1D\uff09\u3002<\/p>\n<\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230802\/1690943778238049.png\" alt=\"2\" \/><\/section>\n<section>\u56fe1\uff1a\u540c\u4f4d\u7d20\u787c-10\u53ca\u8054\u787c\u8bd5\u5242\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n<\/section>\n<section>\n<section><strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u7269\u6240\u7fb0\u57fa\u5408\u6210\u4e0e\u9009\u62e9\u6c27\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5218\u8d85\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u957f\u671f\u81f4\u529b\u4e8e\u6709\u673a\u787c\u8bd5\u5242\u5316\u5b66\u7814\u7a76\u3002\u5728\u524d\u671f\u7814\u7a76\u4e2d\uff0c\u5229\u7528\u81ea\u7136\u4e30\u5ea6\u7684\u8054\u787c\u8bd5\u5242B<sub>2<\/sub>pin<sub>2<\/sub>\u53d1\u5c55\u4e86\u591a\u79cd\u787c\u5316\u65b9\u6cd5\u5408\u6210\u5055\u4e8c\u787c\u548c\u5055\u7845\u787c\u8bd5\u5242\uff08<em>Nat. Synth.<\/em>\u00a02023, 2, 413\uff1b<em>Org. Chem. Front.<\/em>\u00a02019, 6, 900\uff1b<em>J. Am. Chem. Soc.<\/em>\u00a02017, 139, 5257\uff09\u3001\u70ef\u57fa\u787c\u8bd5\u5242\uff08<em>Angew. Chem. Int. Ed.\u00a0<\/em>2019, 58, 15813\uff09\u3001\u70f7\u57fa\u787c\u8bd5\u5242\uff08<em>Angew. Chem. Int. Ed.<\/em>\u00a02018, 57, 10318\uff1b<em>Chin. J. Catal.\u00a0<\/em>2018, 39, 1725\uff09\u3002\u5229\u7528\u787c\u5316\u7269\u7684\u53cd\u5e94\u591a\u6837\u6027\u53d1\u5c55\u4e86\u591a\u79cd\u8bd5\u5242\u548c\u53cd\u5e94\u65b0\u4f53\u7cfb\uff08<em>Nat. Synth.<\/em>\u00a02023, 2, 413\uff1b<em>Angew. Chem. Int. Ed.<\/em>\u00a02023, 62, e202215168\uff1b<em>CCS Chem.<\/em>\u00a02021, 3, 1718\uff1b<em>Angew. Chem. Int. Ed.<\/em>\u00a02020, 59, 2745\uff1b<em>Nat. Commun.<\/em>\u00a02020, 11, 3113\uff1b<em>Angew. Chem. Int. Ed.<\/em>\u00a02018, 57, 5501\uff09\u3002<\/p>\n<p>\u57fa\u4e8e\u8054\u787c\u8bd5\u5242\u5982B<sub>2<\/sub>pin<sub>2<\/sub>\u5728\u5408\u6210\u4e2d\u7684\u5e7f\u6cdb\u5e94\u7528\u4ef7\u503c\uff0c\u7784\u51c6BNCT\u6280\u672f\u5bf9\u787c\u5316\u5b66\u7684\u9700\u6c42\uff0c\u5218\u8d85\u7814\u7a76\u5458\u56e2\u961f\u901a\u8fc7\u4e0d\u65ad\u5c1d\u8bd5\uff0c\u9996\u5148\u4ee5\u81ea\u7136\u4e30\u5ea6\u7684\u4e09\u6c1f\u5316\u787c\u4f5c\u4e3a\u539f\u6599\u8fdb\u884c\u5408\u6210\u65b9\u6cd5\u7684\u6700\u6709\u6761\u4ef6\u63a2\u7d22\uff08\u8be6\u7ec6\u5185\u5bb9\u89c1\u8bba\u6587\uff09\uff0c\u786e\u5b9a\u4e86\u4ee5\u4e09\u6c1f\u5316\u787c\u548c\u4e8c\u80fa\u4e3a\u539f\u6599\uff0c\u4ee5\u6c2f\u7845\u70f7\u4f5c\u4e3a\u6c2f\u5316\u8bd5\u5242\uff0c\u901a\u8fc7\u6c1f\/\u6c2f\u4ea4\u6362\u3001\u8fd8\u539fB-B\u6210\u952e\u7b56\u7565\u6210\u529f\u5b9e\u73b0\u4e86\u7528\u4e09\u6c1f\u5316\u787c\u76f4\u63a5\u5408\u6210\u8054\u787c\u5316\u5408\u7269\u3002\u5728\u83b7\u5f97\u6700\u4f18\u5408\u6210\u65b9\u6cd5\u540e\uff0c\u9996\u5148\u4ee5\u5546\u4e1a\u53ef\u8d2d\u4e70\u7684\u9ad8\u4e30\u5ea6<sup>10<\/sup>BF<sub>3<\/sub>\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u4ee5\u514b\u7ea7\u89c4\u6a21\u5408\u6210\u4e86\u5bcc\u542b<sup>10<\/sup>B\u7684\u8054\u787c\u8bd5\u5242<sup>10<\/sup>B<sub>2<\/sub>dmeda<sub>2<\/sub>\u548c<sup>10<\/sup>B<sub>2<\/sub>dmbda<sub>2<\/sub>\uff08\u56fe2A\uff09\u3002\u4ee5\u5408\u6210\u7684<sup>10<\/sup>B<sub>2<\/sub>dmeda<sub>2<\/sub>\u4f5c\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u916f\u4ea4\u6362\u6216\u80fa\u4ea4\u6362\u5408\u6210\u4e86\u9ad8\u4e30\u5ea6\u7684<sup>10<\/sup>B<sub>2<\/sub>pin<sub>2<\/sub>\u3001<sup>10<\/sup>B<sub>2<\/sub>Epin<sub>2<\/sub>\u3001<sup>10<\/sup>B<sub>2<\/sub>cat<sub>2<\/sub>\u3001<sup>10<\/sup>B<sub>2<\/sub>neop<sub>2<\/sub>\u4ee5\u53ca<sup>10<\/sup>Bpin-<sup>10<\/sup>Bdan\uff08\u56fe2B\uff09\u3002\u5229\u7528<sup>10<\/sup>B<sub>2<\/sub>pin<sub>2<\/sub>\u5728\u6c22\u6c14\u6761\u4ef6\u4e0b\u7684\u94f1\u50ac\u5316\u6c22\u89e3\u53cd\u5e94\u5408\u6210\u4e86H<sup>10<\/sup>Bpin\u3002\u8fd9\u4e9b\u540c\u4f4d\u7d20\u787c-10\u8bd5\u5242\u7684\u76f8\u5e94\u81ea\u7136\u4e30\u5ea6\u8bd5\u5242\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5408\u6210\u7ed3\u6784\u591a\u6837\u7684\u6709\u673a\u787c\u5316\u7269\u3002\u8fd9\u4e9b\u787c-10\u8bd5\u5242\u7684\u5408\u6210\u65e0\u7591\u5c06\u4e3a\u5408\u6210\u5927\u91cf\u7684\u6709\u673a\u787c-10\u5316\u5408\u7269\u63d0\u4f9b\u91cd\u8981\u7684\u7269\u8d28\u57fa\u7840\u3002\u6838\u78c1\u548c\u63a7\u5236\u5b9e\u9a8c\u8868\u660e\uff0c\u53cd\u5e94\u53ef\u80fd\u7684\u673a\u7406\u4e3a\uff1aBF<sub>3<\/sub>-OEt<sub>2<\/sub>\u9996\u5148\u5728\u4e8c\u5f02\u4e19\u57fa\u4e59\u57fa\u80fa\u5b58\u5728\u4e0b\u4e0eDMBDA\u53cd\u5e94\u751f\u62102a-F\u548c\u56db\u6c1f\u787c\u9178\u76d0[DIPEA-H]BF<sub>4<\/sub>\u30022a-F\u5728DIPEA\u548cSiCl<sub>4<\/sub>\u5b58\u5728\u4e0b\u8fdb\u4e00\u6b65\u8f6c\u5316\u4e3a2a\u3002\u540c\u65f6\uff0cSiCl<sub>4<\/sub>\u5bf9HBF<sub>4<\/sub>-DIPEA\u8fdb\u884c\u6c2f\u5316\u751f\u6210\u6c2f\u6c1f\u787c\u9178\u76d0\uff0c\u5728DMBDA\u548cSiCl<sub>4<\/sub>\u5b58\u5728\u4e0b\u8fdb\u4e00\u6b65\u8f6c\u5316\u4e3a2a\uff08\u56fe2D\uff09\u3002\u6700\u540e\u6c2f\u4ee3\u4e8c\u80fa\u787c\u5728\u91d1\u5c5e\u94a0\u5b58\u5728\u4e0b\u8fd8\u539f\u751f\u6210\u8054\u787c\u8bd5\u5242B<sub>2<\/sub>dmbda<sub>2<\/sub>\u3002<\/p>\n<\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230802\/1690943787138390.png\" alt=\"3\" \/><\/section>\n<section>\u56fe2\uff1a\u5bcc\u542b<sup>10<\/sup>B\u7684\u8054\u787c\u8bd5\u5242\u7684\u5408\u6210\u53ca\u53cd\u5e94\u673a\u7406\u3002<\/p>\n<\/section>\n<section><\/section>\n<section>\n<section>\u4ee5<sup>10<\/sup>B<sub>2<\/sub>pin<sub>2<\/sub>\u4e3a\u539f\u6599\uff0c\u5229\u7528\u591a\u79cd\u787c\u5316\u6280\u672f\u5408\u6210\u4e86\u5bcc\u542b<sup>10<\/sup>B\u7684\u6f5c\u5728\u787c\u836f\u5206\u5b50\uff0c\u5982\u4ee5\u5546\u4e1a\u5316\u7684BNCT\u836f\u7269<sup>10<\/sup>B-L-BPA\u7b49\u3002\u5bf9\u4e8e<sup>10<\/sup>B-L-BPA\u7684\u5408\u6210\uff0c\u76f8\u6bd4\u5df2\u62a5\u9053\u65b9\u6cd5\u5177\u6709\u660e\u663e\u7684\u5408\u6210\u4f18\u52bf\uff08\u56fe3\uff09\u3002\u4ee5\u9ad8\u4e30\u5ea6\u787c-10\u7684\u8054\u787c\u8bd5\u5242\u4e3a\u57fa\u7840\uff0c\u5229\u7528\u4e30\u5bcc\u591a\u6837\u7684\u787c\u5316\u6280\u672f\u5c06\u4e3a\u540e\u671f<sup>10<\/sup>B\u836f\u7269\u8bc4\u4f30\u63d0\u4f9b\u91cd\u8981\u7684\u5206\u5b50\u57fa\u7840\u3002<\/p>\n<\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230802\/1690943794799241.png\" alt=\"4\" \/><\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230802\/1690943805377198.png\" alt=\"5\" \/><\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\u56fe3\uff1a\u5bcc\u542b<sup>10<\/sup>B\u7684\u8054\u787c\u8bd5\u5242\u7684\u8f6c\u5316\u5e94\u7528\u3002<\/p>\n<\/section>\n<section>\n<section>\u8be5\u5de5\u4f5c\u53d7\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0822022113\uff09\u7684\u652f\u6301\u3002<\/p>\n<\/section>\n<\/section>\n<section>\u8bba\u6587\u76f8\u5173\u4fe1\u606f\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1016\/j.chempr.2023.06.019<\/p>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u672c\u6587\u6765\u6e90 | \u5c0f\u67ef\u5316\u5b66 &nbsp; 2023\u5e747\u670824\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u7269\u6240\u7fb0\u57fa\u5408\u6210\u4e0e\u9009\u62e9\u6c27\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48752","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48752","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48752"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48752\/revisions"}],"predecessor-version":[{"id":48753,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48752\/revisions\/48753"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48752"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48752"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48752"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}