{"id":48728,"date":"2023-08-19T08:01:09","date_gmt":"2023-08-19T00:01:09","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48728"},"modified":"2023-08-02T10:01:32","modified_gmt":"2023-08-02T02:01:32","slug":"angew-chem-%ef%bc%9a%e9%98%b4%e7%a6%bb%e5%ad%90%e5%a2%9e%e5%bc%ba%e7%9a%84%e6%ba%b6%e5%89%82%e5%8c%96%e7%bb%93%e6%9e%84%e5%8a%a9%e5%8a%9b%e9%94%82%e6%b0%a7%e6%b0%94%e7%94%b5%e6%b1%a0%e9%87%91","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e9%98%b4%e7%a6%bb%e5%ad%90%e5%a2%9e%e5%bc%ba%e7%9a%84%e6%ba%b6%e5%89%82%e5%8c%96%e7%bb%93%e6%9e%84%e5%8a%a9%e5%8a%9b%e9%94%82%e6%b0%a7%e6%b0%94%e7%94%b5%e6%b1%a0%e9%87%91\/","title":{"rendered":"Angew. Chem. \uff1a\u9634\u79bb\u5b50\u589e\u5f3a\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u52a9\u529b\u9502\u6c27\u6c14\u7535\u6c60\u91d1\u5c5e\u8d1f\u6781\u9ad8\u7a33\u5b9a\u6027"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u9502\u6c27\u6c14\u7535\u6c60\u5177\u6709\u8d85\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff08~3,500 Wh kg\u00a0<sup>-1<\/sup>\uff09\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u4e0b\u4e00\u4ee3\u7535\u52a8\u6c7d\u8f66\u548c\u822a\u7a7a\u822a\u5929\u9886\u57df\u7684\u50a8\u80fd\u88c5\u7f6e\u3002\u5408\u7406\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\uff0c\u6709\u52a9\u4e8e\u89e3\u51b3\u6b63\u6781\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u7f13\u6162\u7684\u95ee\u9898\uff0c\u4f46\u662f\u8d1f\u6781\u4e00\u4fa7\u4ecd\u7136\u7f3a\u4e4f\u80fd\u4e0e\u9502\u91d1\u5c5e\u9002\u914d\u7684\u7535\u89e3\u6db2\u3002\u7535\u89e3\u6db2\u7684\u7a33\u5b9a\u6027\u4e0e\u9502\u79bb\u5b50\u6eb6\u5242\u5316\u7ed3\u6784\u5bc6\u5207\u76f8\u5173\u3002\u957f\u78b3\u94fe\u919a\u7c7b\u6eb6\u5242\uff0c\u56e0\u5176\u9ad8\u7a33\u5b9a\u6027\u548c\u4f4e\u6325\u53d1\u6027\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u9502\u6c27\u6c14\u7535\u6c60\u3002\u7136\u800c\uff0c\u5176\u6eb6\u5242\u5316\u7ed3\u6784\u5185\u9633\u79bb\u5b50\u4e0e\u919a\u7c7b\u6eb6\u5242\u8fc7\u5f3a\u7684\u87af\u5408\u4f5c\u7528\uff0c\u9020\u6210\u8d1f\u6781\u52a8\u529b\u5b66\u7f13\u6162\u4e14\u526f\u53cd\u5e94\u589e\u591a\u3002\u4e0d\u53ef\u9006\u9502\u6c89\u79ef\/\u5265\u79bb\u5bfc\u81f4\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u63a7\u7684\u9502\u679d\u6676\u751f\u957f\uff0c\u5feb\u901f\u8017\u5c3d\u6709\u9650\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u5e76\u9020\u6210\u5b89\u5168\u9690\u60a3\u3002\u56e0\u6b64\uff0c\u8c03\u63a7\u7535\u89e3\u6db2\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u6784\u5efa\u7a33\u5b9a\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u819c\uff08SEI\uff09\uff0c\u52a0\u5feb\u754c\u9762\u8131\u6eb6\u5242\u5316\u52a8\u529b\u5b66\uff0c\u5bf9\u9502\u6c27\u6c14\u7535\u6c60\u8d1f\u6781\u7a33\u5b9a\u6027\u7684\u63d0\u5347\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u674e\u798f\u519b\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u56db\u4e59\u4e8c\u9187\u4e8c\u7532\u919a\uff08G4\uff09\u7684\u4e09\u6c1f\u4e59\u9178\u9502\uff08LiTFA\uff09\u548c\u53cc\uff08\u4e09\u6c1f\u7532\u78fa\u9170\u57fa\uff09\u4e9a\u80fa\u9502\uff08LiTFSI\uff09\u7684\u53cc\u76d0\u7535\u89e3\u6db2\u4f53\u7cfb\uff0c\u6210\u529f\u6784\u5efa\u4e86\u9634\u79bb\u5b50\u589e\u5f3a\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u5728\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u5b9e\u73b0\u4e86\u72ec\u7279\u7684\u9634\u79bb\u5b50\u8d1f\u6781\u8fc1\u79fb\u3002\u65e0\u673a\u7ec4\u5206\u4e3a\u4e3b\u7684SEI\u5f62\u6210\u6e90\u81ea\u4e8e\u8d1f\u6781\u9634\u79bb\u5b50\u7684\u4f18\u5148\u5206\u89e3\uff0c\u5176\u6709\u6548\u6291\u5236\u4e86\u679d\u6676\u751f\u957f\u5e76\u63d0\u5347\u4e86\u5e93\u4f26\u6548\u7387\uff0c\u5728\u4f7f\u7528\u6709\u9650\u9502\u6e90\u4f5c\u4e3a\u8d1f\u6781\u7684\u6761\u4ef6\u4e0b\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u9502\u6c27\u6c14\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230729\/1690604678402306.jpg\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5404\u79cd\u8868\u5f81\u6280\u672f\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u5206\u6790\uff0cLiTFA\u52a0\u5165LiTFSI\/G4\u5355\u76d0\u7535\u89e3\u6db2\u540e\uff0c\u9502\u79bb\u5b50\u4e0eG4\u7684\u87af\u5408\u4f5c\u7528\u51cf\u5f31\u800c\u4e0e\u9634\u79bb\u5b50\u4f5c\u7528\u589e\u5f3a\u3002\u968f\u7740\u66f4\u591a\u7684TFA-\u9634\u79bb\u5b50\u53c2\u4e0e\u914d\u4f4d\uff0cG4\u5728\u6eb6\u5242\u5316\u7ed3\u6784\u4e2d\u7684\u7ed3\u5408\u80fd\u9010\u6e10\u964d\u4f4e\uff0c\u56e0\u6b64\u9502\u79bb\u5b50\u5728\u6eb6\u6db2\u4e2d\u7684\u8fc1\u79fb\u80fd\u529b\u63d0\u5347\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230729\/1690604686228640.png\" alt=\"7\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8868\u660e\u9502\u6c89\u79ef\u8fc7\u7a0b\u4e2d\uff0cTFA<sup>&#8211;<\/sup>\u4e0eTFSI<sup>&#8211;<\/sup>\u7684\u8fd0\u52a8\u65b9\u5411\u76f8\u53cd\uff0cTFA<sup>&#8211;<\/sup>\u66f4\u503e\u5411\u4e8e\u8fc1\u79fb\u5230\u8d1f\u6781\u754c\u9762\uff0c\u8fd9\u6709\u52a9\u4e8e\u9634\u79bb\u5b50\u53d1\u751f\u5206\u89e3\u53cd\u5e94\u5e76\u53c2\u4e0e\u754c\u9762\u4fdd\u62a4\u819c\u6784\u7b51\u3002XPS\u6d4b\u8bd5\u8868\u660e\uff0c\u5728\u53cc\u76d0\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u751f\u6210\u7684SEI\uff0c\u5bcc\u542b\u66f4\u591a\u9634\u79bb\u5b50\u5206\u89e3\u7684\u65e0\u673a\u4ea7\u7269\u3002\u591a\u79cd\u7535\u5316\u5b66\u6d4b\u8bd5\u8fdb\u4e00\u6b65\u8bc1\u5b9e\uff0c\u9634\u79bb\u5b50\u589e\u5f3a\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u964d\u4f4e\u4e86\u53bb\u6eb6\u5242\u5316\u80fd\u5792\uff0c\u52a0\u5feb\u4e86\u754c\u9762\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Solvation Structure with Enhanced Anionic Coordination for Stable Anodes in Lithium-Oxygen Batteries<\/p>\n<p>Yaohui Huang, Jiarun Geng, Zhuoliang Jiang, Meng Ren,\u00a0Bo\u00a0Wen,\u00a0Jun Chen, and Fujun Li*<\/p>\n<p>\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u5f00\u5927\u5b66\u7684\u7855\u58eb\u7814\u7a76\u751f\u9ec4\u8000\u8f89<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202306236<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u9502\u6c27\u6c14\u7535\u6c60\u5177\u6709\u8d85\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff08~3,500 Wh kg\u00a0-1\uff09\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u4e0b\u4e00\u4ee3\u7535\u52a8\u6c7d\u8f66\u548c\u822a\u7a7a\u822a\u5929\u9886\u57df\u7684\u50a8\u80fd [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48728","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48728","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48728"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48728\/revisions"}],"predecessor-version":[{"id":48729,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48728\/revisions\/48729"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48728"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48728"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48728"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}