{"id":48607,"date":"2023-08-07T08:53:17","date_gmt":"2023-08-07T00:53:17","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48607"},"modified":"2023-07-21T09:53:43","modified_gmt":"2023-07-21T01:53:43","slug":"%e5%85%b0%e4%ba%9a%e4%b9%be%e6%95%99%e6%8e%88%ef%bc%8c%e6%9c%80%e6%96%b0angew-%ef%bc%81%e7%ba%af%e6%b0%b4%e4%b8%ad%e5%85%89%e5%90%88%e6%88%90%e8%bf%87%e6%b0%a7%e5%8c%96%e6%b0%a2","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%85%b0%e4%ba%9a%e4%b9%be%e6%95%99%e6%8e%88%ef%bc%8c%e6%9c%80%e6%96%b0angew-%ef%bc%81%e7%ba%af%e6%b0%b4%e4%b8%ad%e5%85%89%e5%90%88%e6%88%90%e8%bf%87%e6%b0%a7%e5%8c%96%e6%b0%a2\/","title":{"rendered":"\u5170\u4e9a\u4e7e\u6559\u6388\uff0c\u6700\u65b0Angew.\uff01\u7eaf\u6c34\u4e2d\u5149\u5408\u6210\u8fc7\u6c27\u5316\u6c22"},"content":{"rendered":"
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\u6210\u679c\u7b80\u4ecb<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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\u7814\u7a76\u80cc\u666f<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\u56fe\u6587\u5bfc\u8bfb<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\"1\"<\/section>\n
\u56fe1.<\/strong>\u00a0Co14<\/sub>(L-H)24<\/sub>\u7684\u6676\u4f53\u7ed3\u6784<\/strong><\/section>\n
\u7528-CH3<\/sub>\u57fa\u56e2\u5c06HL-H\u914d\u4f53\u7684\u82ef\u73af\u529f\u80fd\u5316\uff0c\u5f97\u5230\u4e86HL-CH3<\/sub>\u914d\u4f53\u3002\u5b83\u4eec\u53ef\u4ee5\u4e0e\u94b4\u91d1\u5c5e\u79bb\u5b50\u7ed3\u5408\u5f62\u6210\u94b4\u57fa\u91d1\u5c5e\u6709\u673a\u7b3c\uff0cCo14<\/sub>\u00a0(L-H)\u00a024<\/sub>\u3002\u5bf9\u4e8eCo14<\/sub>(L-H)24<\/sub>\u548cCo14<\/sub>(L-CH3<\/sub>)24<\/sub>\uff0c\u6709\u673a\u7b3c\u7684\u8154\u5f84\u5206\u522b\u7ea6\u4e3a6.61 \u00c5\u548c6.55 \u00c5\u3002\u5982\u679cCo1\u7684\u6c34\u5206\u5b50\u8131\u79bb\uff0c\u7a7a\u8154\u7684\u76f4\u5f84\u5206\u522b\u589e\u52a0\u523010.93 \u00c5\u548c10.88 \u00c5(\u56fe1d-e)\u3002\u53cd\u5e94\u5206\u5b50\u5982H2<\/sub>O\u548cO2<\/sub>\u5bb9\u6613\u5230\u8fbe\u8154\u4f53\u3002\u56e0\u6b64\uff0c\u5b83\u4eec\u53ef\u4ee5\u4ece\u7a7a\u8154\u5185\u5916\u653b\u51fb\u6d3b\u6027\u4f4d\u70b9\uff0c\u6709\u5229\u4e8e\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002<\/section>\n
\"2\"<\/section>\n
\u56fe2. Co14<\/sub>(L-H)24<\/sub>\u548cCo14<\/sub>(LCH3<\/sub>)24<\/sub>\u7684\u5149\u5b66\u6027\u8d28\u8868\u5f81<\/strong><\/section>\n
\u56fa\u6001\u7d2b\u5916\u3001\u53ef\u89c1\u5149\u548c\u8fd1\u7ea2\u5916\u6f2b\u53cd\u5c04\u5149\u8c31\u8868\u660eCo14<\/sub>(L-CH3<\/sub>)2<\/sub>\u5177\u6709\u66f4\u5f3a\u7684\u5149\u5438\u6536\u80fd\u529b\u3002\u7ed3\u5408\u8096\u7279\u57fa\u6d4b\u8bd5\u7ed3\u679c\u8bc1\u660e\u4e86\u8fd9\u4e9b\u50ac\u5316\u5242\u7684LUMO\u4f4d\u7f6e\u6bd4O2<\/sub>\/H2<\/sub>O2<\/sub>\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u66f4\u8d1f\uff0c\u5b83\u4eec\u7684HOMO\u4f4d\u7f6e\u6bd4H2<\/sub>O\/H2<\/sub>O2<\/sub>\u7684\u6c27\u5316\u7535\u4f4d\u66f4\u6b63\u3002\u56e0\u6b64\uff0c\u8fd9\u4e24\u79cd\u6676\u4f53\u90fd\u6709\u53ef\u80fd\u4f5c\u4e3aORR\u548cWOR\u7684\u5149\u50ac\u5316\u5242\uff0c\u4fc3\u8fdbH2<\/sub>O2<\/sub>\u7684\u751f\u6210\u3002\u7535\u5316\u5b66\u963b\u6297\u8c31, \u5149\u7535\u6d41\u54cd\u5e94\uff0c\u7a33\u6001\u5149\u81f4\u53d1\u5149\u4ee5\u53ca\u8367\u5149\u8870\u51cf\u6d4b\u8bd5\u8868\u660eCH3<\/sub>-\u4fee\u9970\u7684\u5149\u50ac\u5316\u5242\u8868\u9762\u5177\u6709\u66f4\u9ad8\u7684\u5149\u751f\u7535\u8377\u5bc6\u5ea6\uff0c\u56e0\u6b64Co14<\/sub>(L-CH3<\/sub>)24<\/sub>\u5bf9ORR\u548cWOR\u5177\u6709\u66f4\u9ad8\u7684\u5149\u50ac\u5316\u6d3b\u6027\u3002<\/section>\n
\"3\"<\/section>\n
\u56fe3. Co14<\/sub>(L-H)24<\/sub>\u548cCo14<\/sub>(L-CH3<\/sub>)24<\/sub>\u5149\u5408\u6210\u8fc7\u6c27\u5316\u6c22\u7684\u6027\u80fd\u3002<\/strong><\/section>\n
\u5149\u50ac\u5316\u751f\u4ea7H2<\/sub>O2<\/sub>\u7684\u6d3b\u6027\u8bc4\u4f30\u5728O2<\/sub>\u9971\u548c\u7684\u7eaf\u6c34\u4e2d\u8fdb\u884c(UV\/Vis-NIR (\u03bb = 300-1100 nm))\uff0c\u672a\u4f7f\u7528\u727a\u7272\u5242\u3001\u5149\u654f\u5242\u548cpH\u8c03\u8282\u3002H2<\/sub>O2<\/sub>\u4ea7\u7387\u4e0e\u53cd\u5e94\u65f6\u95f4\u57fa\u672c\u6210\u7ebf\u6027\u5173\u7cfb\u3002Co14<\/sub>(L-H)24<\/sub>\u548cCo14<\/sub>(LCH3<\/sub>)24<\/sub>\u5728\u7a7a\u6c14\u4e2d\u5149\u5408\u6210H2<\/sub>O2<\/sub>\u7684\u901f\u7387\u5206\u522b\u4e3a74.27 \u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\u548c120.04 \u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\u3002\u4e09\u6b21\u5faa\u73af\u8bd5\u9a8c\u540e\uff0c\u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u5408\u6210\u901f\u7387\u57fa\u672c\u6ca1\u6709\u53d8\u5316\u3002H2<\/sub>O\u548cO2<\/sub>\u90fd\u662f\u5149\u50ac\u5316\u5408\u6210H2<\/sub>O2<\/sub>\u7684\u539f\u6599\uff0c\u5e76\u4e14WOR\u548cORR\u5408\u6210H2<\/sub>O2<\/sub>\u7684\u539f\u5b50\u5229\u7528\u7387\u63a5\u8fd1100%\u3002<\/section>\n
\"9\"<\/section>\n
\u56fe4. Co14<\/sub>(L-H)24<\/sub>\u548cCo14<\/sub>(L-CH3<\/sub>)24<\/sub>\u5149\u5408\u6210\u8fc7\u6c27\u5316\u6c22\u7684\u7406\u8bba\u8ba1\u7b97\u53ca\u53cd\u5e94\u673a\u7406\u3002<\/strong><\/section>\n
\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u4e24\u79cd\u5149\u50ac\u5316\u5242\u7684\u54aa\u5511\u4f4d\u70b9\u5747\u4e3aH2<\/sub>O\u6c27\u5316\u53cd\u5e94\u7684\u6d3b\u6027\u4f4d\u70b9\uff0cO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u4e3aCo\u4f4d\u70b9\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cCo2\u662f\u5b8c\u5168\u914d\u4f4d\u7684\uff0cCo1\u7684\u4e24\u4e2a\u914d\u4f4d\u6c34\u5206\u5b50\u5f88\u5bb9\u6613\u79bb\u5f00\u5f62\u6210\u6d3b\u6027\u4f4d\u70b9\uff0c\u56e0\u6b64\u50ac\u5316ORR\u7684\u8fd8\u539f\u4f4d\u70b9\u4e3aCo1\u4f4d\u70b9\u3002\u5728\u5149\u7167\u5c04\u4e0b\uff0c\u5149\u50ac\u5316\u5242\u5438\u6536\u5149\u80fd\u4ea7\u751f\u5149\u751f\u7535\u8377\u3002\u5149\u751f\u7535\u5b50\u8fc1\u79fb\u5230Co\u4f4d\uff0c\u4f7f\u5438\u9644\u5728Co\u4f4d\u4e0a\u7684O2<\/sub>\u5206\u5b50\u88ab\u8fd8\u539f\uff0c\u7ecf\u8fc7\u8d28\u5b50\/\u7535\u5b50\u53cd\u5e94\u8fc7\u7a0b\uff0c\u9010\u6e10\u751f\u6210*O2<\/sub>–<\/sup>, *OOH\u548c*HOOH\u3002\u540c\u65f6\uff0c\u54aa\u5511\u4f4d\u70b9\u7684C2\u2212H\u901a\u8fc7\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u5438\u6536\u548c\u6d3b\u5316H2<\/sub>O\u5206\u5b50\u3002\u7136\u540e\uff0c\u5149\u751f\u7a7a\u7a74\u8f6c\u79fb\u5230\u54aa\u5511\u4f4d\u70b9\uff0c\u5bfc\u81f4\u5438\u9644\u5728\u8be5\u4f4d\u70b9\u7684H2<\/sub>O\u5206\u5b50\u6c27\u5316\uff0c\u9010\u6e10\u751f\u6210*OH\u548c*HOOH\u3002\u6700\u540e\uff0c*HOOH\u4eceCo\u548c\u54aa\u5511\u4f4d\u70b9\u89e3\u5438\u5f97\u5230H2<\/sub>O2<\/sub>\u3002<\/section>\n
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\u603b\u7ed3\u5c55\u671b<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
<\/section>\n
\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7-CH3<\/sub>\u57fa\u56e2\u529f\u80fd\u5316\u914d\u4f53\u5236\u5907\u4e86\u4e24\u4e2a\u7a33\u5b9a\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\uff0cCo14<\/sub>(L-H)24<\/sub>\u548cCo14<\/sub>(L-CH3<\/sub>)24<\/sub>\u3002\u5b83\u4eec\u53ef\u4ee5\u4f5c\u4e3a\u53cc\u529f\u80fd\u5149\u50ac\u5316\u5242\uff0c\u540c\u65f6\u50ac\u5316H2<\/sub>O\u6c27\u5316\u53cd\u5e94\u548cO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u5408\u6210H2<\/sub>O2<\/sub>\u3002\u7531\u4e8e-CH3<\/sub>\u7684\u914d\u4f53\u4fee\u9970\u589e\u52a0\u4e86\u5149\u50ac\u5316\u5242\u7684\u5438\u5149\u6027\uff0c\u964d\u4f4e\u4e86\u5149\u751f\u7535\u8377\u7684\u91cd\u7ec4\u6548\u7387\uff0c\u56e0\u6b64Co14<\/sub>(L-CH3<\/sub>)24<\/sub>\u5728\u7eaf\u6c34\u4e2d\u5177\u6709\u8f83\u9ad8\u7684H2<\/sub>O2<\/sub>\u50ac\u5316\u6d3b\u6027\u3002\u5728O2<\/sub>\u548c\u7a7a\u6c14\u6c14\u6c1b\u4e0b\uff0cCo14<\/sub>(L-CH3<\/sub>)24<\/sub>\u7684H2<\/sub>O2<\/sub>\u751f\u6210\u901f\u7387\u5206\u522b\u4e3a 146.60 \u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\u548c120.04 \u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\u3002\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7ed3\u679c\u8bc1\u660eCo\u4f4d\u70b9\u548c\u54aa\u5511\u4f4d\u70b9\u5206\u522b\u50ac\u5316\u4e24\u7535\u5b50O2<\/sub>\u8fd8\u539f\u53cd\u5e94\u548c\u4e24\u7535\u5b50\u7684H2<\/sub>O\u6c27\u5316\u53cd\u5e94\u3002\u672c\u5de5\u4f5c\u9996\u6b21\u8bc1\u660e\u4e86\u91d1\u5c5e-\u6709\u673a\u7b3c\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\u5728H2<\/sub>O2<\/sub>\u5408\u6210\u9886\u57df\u7684\u5de8\u5927\u6f5c\u529b\uff0c\u5e76\u51ed\u501f\u5176\u72ec\u7279\u7684\u91d1\u5c5e\u975e\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u534f\u540c\u50ac\u5316\u4f5c\u7528\uff0c\u6709\u6548\u63d0\u9ad8\u4e86\u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u5408\u6210\u7684\u6027\u80fd\u3002<\/section>\n
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\u6587\u732e\u4fe1\u606f<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
<\/section>\n
Synergistic Metal-Nonmetal Active Sites in a Metal-Organic Cage for Efficient Photocatalytic Synthesis of Hydrogen Peroxide in Pure Water.\u00a0Angew. Chem. Int. Ed.<\/em>\u00a02023<\/strong>, e202308505.<\/section>\n
https:\/\/doi.org\/10.1002\/anie.202308505<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u6210\u679c\u7b80\u4ecb   \u5149\u50ac\u5316\u5408\u6210\u8fc7\u6c27\u5316\u6c22\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u6e05\u6d01\u65b9\u6cd5\uff0c\u4f46\u662f\u5149\u50ac\u5316\u5242\u4e2d\u6c27\u5316\u548c\u8fd8\u539f\u4f4d\u70b9\u4e4b\u95f4\u7684\u8f83\u8fdc\u8ddd\u79bb\u963b\u788d […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48607","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48607","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48607"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48607\/revisions"}],"predecessor-version":[{"id":48608,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48607\/revisions\/48608"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48607"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48607"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48607"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}