{"id":48574,"date":"2023-08-03T08:04:10","date_gmt":"2023-08-03T00:04:10","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48574"},"modified":"2023-07-18T10:04:42","modified_gmt":"2023-07-18T02:04:42","slug":"jacs%ef%bc%9a%e9%95%bf%e7%a8%8b%e8%b4%a8%e5%ad%90%e8%be%93%e8%bf%90%e7%ab%8b%e5%a4%a7%e5%8a%9f%ef%bc%8c%e5%8a%a9%e5%8a%9b%e6%ba%b6%e8%a7%a3%e7%a2%b3%e9%85%b8%e7%9b%90%e5%92%8c%e8%bf%91%e9%9b%b6co2aq","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/jacs%ef%bc%9a%e9%95%bf%e7%a8%8b%e8%b4%a8%e5%ad%90%e8%be%93%e8%bf%90%e7%ab%8b%e5%a4%a7%e5%8a%9f%ef%bc%8c%e5%8a%a9%e5%8a%9b%e6%ba%b6%e8%a7%a3%e7%a2%b3%e9%85%b8%e7%9b%90%e5%92%8c%e8%bf%91%e9%9b%b6co2aq\/","title":{"rendered":"JACS\uff1a\u957f\u7a0b\u8d28\u5b50\u8f93\u8fd0\u7acb\u5927\u529f\uff0c\u52a9\u529b\u6eb6\u89e3\u78b3\u9178\u76d0\u548c\u8fd1\u96f6CO2(aq)\u5149\u50ac\u5316\u8fd8\u539fCO2"},"content":{"rendered":"
\u5728\u7ea60 mM CO2<\/sub>(aq)\u6761\u4ef6\u4e0b\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f(CO2<\/sub>RR)\u53cd\u5e94\u662f\u4e00\u9879\u51cf\u5c11CO2<\/sub>\u6392\u653e\u548c\u751f\u4ea7\u9ad8\u9644\u52a0\u503c\u4ea7\u54c1\u7684\u6709\u6548\u65b9\u6cd5\u3002\u5c3d\u7ba1\u6700\u8fd1\u8be5\u6280\u672f\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u5c55\uff0c\u4f46\u662f\u5bf9\u4e8eCO2<\/sub>\u50ac\u5316\u8fd8\u539f\u548c\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u7684\u7814\u7a76\u5374\u5f88\u5c11\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u5bf9\u5149\u50ac\u5316\u53cd\u5e94\u4e2d\u6d89\u53ca\u7684\u76f8\u4e92\u4f9d\u8d56\u7684\u8fc7\u7a0b(\u5305\u62ecCO2<\/sub>\u5438\u9644\u3001\u7535\u8377\u5206\u79bb\u3001\u957f\u7a0b\u5316\u5b66\u8f93\u8fd0(100 nm\u8ddd\u79bb)\u548c\u78b3\u9178\u6c22\u76d0\u7f13\u51b2\u7269\u79cd\u5f62\u6210)\u8fdb\u884c\u673a\u7406\u7814\u7a76\u3002\u57280 mM CO2<\/sub>(aq)\u4e2d\u5149\u50ac\u5316CO2<\/sub>RR\u7684\u78b3\u6355\u83b7\u4e0e\u5229\u7528(CCU)\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u4f46\u5bf9\u5176\u7814\u7a76\u8f83\u5c11\u3002<\/section>\n

 <\/p>\n

\u57fa\u4e8e\u6b64\uff0c\u8036\u9c81\u5927\u5b66\u80e1\u6f8d<\/strong>\u8bfe\u9898\u7ec4\u4f7f\u7528\u591a\u91cd\u7269\u7406\u6709\u9650\u5143\u5206\u6790\u6765\u89e3\u91ca\u8026\u5408\u53cd\u5e94\u548c\u5316\u5b66\u8f93\u8fd0\uff0c\u5b83\u4eec\u4e0e\u534a\u5bfc\u4f53\u7535\u8377\u5206\u79bb\u662f\u76f8\u4e92\u4f9d\u8d56\u7684\u3002<\/section>\n
\"1\"<\/section>\n
\"2\"<\/section>\n
\u5177\u4f53\u800c\u8a00\uff0c\u5728pH\u4e3a7\u76840.1 M KHCO3<\/sub>(aq)\u4e2d(\u4f46\u6ca1\u6709\u8fde\u7eed\u901a\u5165CO2<\/sub>)\uff0c\u7814\u7a76\u4eba\u5458\u4f7f\u7528\u8d1f\u8f7d\u5728GaInP2<\/sub>\u4e0a\u7684Ag@CrOx<\/sub>\u7eb3\u7c73\u9897\u7c92\u5b9e\u73b0\u4e860.1%\u7684\u592a\u9633\u80fd-\u71c3\u6599\u8f6c\u5316\u6548\u7387\u3002\u9996\u5148\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528HCO3<\/sub>\u2212<\/sup>\u81ea\u89e3\u79bb(Le Chatelier\u539f\u7406)\u533a\u5206\u4e86H+<\/sup>\u9a71\u52a8\u7684\u8fc7\u91cfCO2<\/sub>\u4ea7\u751f(\u6765\u81ea\u8fdc\u7a0bH+<\/sup>)\u7684\u8d21\u732e\u3002<\/section>\n
\u7814\u7a76\u53d1\u73b0\uff0c\u4e0eHCO3<\/sub>\u2212<\/sup>\u81ea\u89e3\u79bb\u76f8\u6bd4\uff0cH+<\/sup>\u9a71\u52a8\u7684HCO3<\/sub>\u2212<\/sup>\u89e3\u79bb\u589e\u5f3a\u4e86\u5c40\u90e8CO2<\/sub>\u6d53\u5ea6\u548cCO2<\/sub>RR\u901f\u7387\uff0c\u57284.2 \u03bcmol h-1<\/sup>\u00a0cm-2<\/sup>\u7684\u901f\u7387\u4e0b\uff0cH+<\/sup>\u9a71\u52a8\u7684HCO3<\/sub>\u2212<\/sup>\u7269\u79cd\u89e3\u79bb\u6bd4HCO3<\/sub>\u2212<\/sup>\u81ea\u89e3\u79bb\u4ea7\u751f\u5927\u7ea6\u591a\u4e09\u500d\u7684CO2<\/sub>\u3002<\/section>\n
\"3\"<\/section>\n
\"5\"<\/section>\n
\u5176\u6b21\uff0c\u5c40\u90e8\u4ea7\u751f\u7684H+<\/sup>\u88ab\u53d1\u73b0\u6709\u4e24\u4e2a\u4f5c\u7528\uff0c\u5176\u4e00\u5c31\u662f\u5230\u8fbeCO2<\/sub>RR\u4f4d\u70b9\u53c2\u4e0eCO2<\/sub>RR\u53cd\u5e94\uff0c\u53e6\u4e00\u4e2a\u662f\u901a\u8fc7\u6cbf\u7740\u957f\u7a0b\u8fd0\u8f93\u8def\u5f84\u91ca\u653eCO2<\/sub>\uff0c\u4f46\u4e0d\u4f1a\u5f15\u8d77pH\u6ce2\u52a8\u3002\u9633\u6781\u9644\u8fd1\u4ea7\u751f\u7684H+<\/sup>\u53ef\u4ee5\u539f\u4f4d\u4ea7\u751f\u8db3\u591f\u7684CO2<\/sub>\uff0c\u4fc3\u8fdbCO2<\/sub>RR\u53cd\u5e94\uff0c\u56e0\u6b64\u7535\u8377\u5206\u79bb\u6548\u7387\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u4ece\u9633\u6781\u5230\u9634\u6781\u7684\u5c40\u90e8CO2<\/sub>\u901a\u91cf\uff0c\u800c\u9634\u6781\u7684CO2<\/sub>\u901a\u91cf\u63a5\u8fd1\u96f6\u3002<\/section>\n
\u57fa\u4e8e\u4e0a\u8ff0\u7ed3\u8bba\uff0c\u6d3b\u6027\u78b3\u6355\u83b7\u548c\u5229\u7528(CCU)\u53ef\u4ee5\u4e00\u6b65\u5b8c\u6210\uff0c\u5176\u4e2d\u6301\u7eed\u4f9b\u5e94\u78b3\u9178\u6c22\u76d0\u6eb6\u6db2\u53ef\u4ee5\u53d6\u4ee3\u7eafCO2<\/sub>\u6c14\u4f53\u4f5c\u4e3aCO2<\/sub>\u8f6c\u5316\u7684\u5e38\u89c4\u6765\u6e90\uff1b\u5229\u7528\u78b3\u9178\u6c22\u76d0\u7f13\u51b2\u6db2\u7684\u9002\u5f53pH\u503c\u548cDIC\u53ef\u4ee5\u539f\u4f4d\u4ea7\u751fCO2<\/sub>\u4ee5\u7ef4\u6301\u5149\u50ac\u5316CO2<\/sub>RR\u7684\u8fdb\u884c\u3002\u540c\u65f6\uff0c\u4ece\u80fd\u6e90\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u4e00\u6b65CCU\u514b\u670d\u4e86\u6d89\u53ca\u5206\u6b65\u6355\u83b7\u3001\u538b\u7f29\u548c\u8f6c\u5316CO2<\/sub>\u7684\u80fd\u6e90\u6d88\u8017\u3002<\/section>\n
Photocatalytic CO2<\/sub>\u00a0Reduction with Dissolved Carbonates and Near-Zero CO2<\/sub>(aq) by Employing Long-Range Proton Transport. Journal of the American Chemical Society, 2023. DOI: 10.1021\/jacs.3c03281<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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