{"id":48349,"date":"2023-07-03T08:49:04","date_gmt":"2023-07-03T00:49:04","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48349"},"modified":"2023-06-16T09:49:29","modified_gmt":"2023-06-16T01:49:29","slug":"%e8%8c%83%e5%87%a4%e8%8c%b9-%e6%9d%8e%e5%89%91%e9%94%8bjacs%ef%bc%9a%e9%80%9a%e8%bf%87%e8%b6%85%e8%96%84pd%e6%8f%92%e5%b1%82%e4%b8%ad%e7%9a%84%e6%b4%bb%e6%80%a7%e6%b0%a2%e6%8f%90%e5%8d%87ru%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e8%8c%83%e5%87%a4%e8%8c%b9-%e6%9d%8e%e5%89%91%e9%94%8bjacs%ef%bc%9a%e9%80%9a%e8%bf%87%e8%b6%85%e8%96%84pd%e6%8f%92%e5%b1%82%e4%b8%ad%e7%9a%84%e6%b4%bb%e6%80%a7%e6%b0%a2%e6%8f%90%e5%8d%87ru%e7%9a%84\/","title":{"rendered":"\u8303\u51e4\u8339\/\u674e\u5251\u950bJACS\uff1a\u901a\u8fc7\u8d85\u8584Pd\u63d2\u5c42\u4e2d\u7684\u6d3b\u6027\u6c22\u63d0\u5347Ru\u7684\u6c22\u6c14\u6c27\u5316\u53cd\u5e94\u901f\u7387"},"content":{"rendered":"<section data-role=\"title\" data-tools=\"135\u7f16\u8f91\u5668\" 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src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230610\/1686357673426734.png\" alt=\"3\" \/><\/section>\n<section><\/section>\n<section>\u8981\u70b9\u4e09\uff1a\u5c06\u5b9e\u9a8c\u6570\u636e\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u5408\uff0c\u63a2\u660eAu@Pd@Ru\u50ac\u5316\u5242\u5728HOR\u4e2d\u7684\u65b0\u53cd\u5e94\u673a\u7406\u3002\u5728HOR\u7535\u4f4d\u8303\u56f4\u5185\uff0c\u5c24\u5176\u662f\u5728\u9ad8\u7535\u4f4d\u4e0b\uff0cRu\u8868\u9762\u5bb9\u6613\u5f62\u6210Ru-OH<sub>ad<\/sub>\u6216Ru-O<sub>ad<\/sub>\uff08\u5df2\u7ecf\u88ab\u539f\u4f4dSERS\u786e\u8ba4\uff09\uff0c\u56e0\u6b64Ru\u4e0d\u518d\u80fd\u591f\u652f\u6301\u6c22\u7684\u89e3\u79bb\u548c\u5438\u9644\uff0c\u4ece\u800c\u5931\u6d3b\u3002<\/section>\n<section>\u7136\u800c\uff0c\u4e0a\u8ff0\u8ba8\u8bba\u7684HOR\u6d3b\u6027\u6570\u636e\u8868\u660e\uff0cAu@Pd@Ru\u57280.6 V vs. RHE\u4e0b\u4ecd\u7136\u4fdd\u6301\u7740\u9ad8\u6c27\u5316\u7535\u6d41\uff0c\u8fd9\u4f3c\u4e4e\u5f88\u4e0d\u5bfb\u5e38\u3002\u6362\u53e5\u8bdd\u8bf4\uff0c\u5728\u88ab\u6c27\u5316\u7269\u5360\u636e\u7684\u672a\u5408\u91d1\u5316Ru\u8868\u9762\u4e0a\uff0cVolmer\u6b65\u9aa4\u4ecd\u7136\u53d1\u751f\uff0c\u8fd9\u4f3c\u4e4e\u4e0e\u4f20\u7edf\u7406\u89e3\u4e0d\u4e00\u81f4\u3002<\/section>\n<section>\u4f17\u6240\u5468\u77e5\uff0c\u7531\u4e8e\u6c22\u7684\u539f\u5b50\u534a\u5f84\u6781\u5c0f\uff0c\u5b83\u53ef\u4ee5\u8f7b\u677e\u7a7f\u900f\u91d1\u5c5e\u5c42\u3002\u4f8b\u5982\uff0cSorok\u7b49\u4eba\u62a5\u9053\u4e86\u6c22\u53ef\u4ee5\u7a7f\u8fc77 nm\u7684Ru\u91d1\u5c5e\u5c42\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u6c22\u4e5f\u53ef\u4ee5\u7a7f\u8fc7\u91d1\u5c5e\u5c42\u6216\u76f4\u63a5\u50a8\u5b58\u5728Pd\u6676\u683c\u4e2d\u3002<\/section>\n<section>\u901a\u8fc7\u7ed3\u5408\u539f\u4f4dXRD\u3001\u7535\u5316\u5b66\u8868\u5f81\u548c\u7406\u8bba\u8ba1\u7b97\u3002\u6211\u4eec\u53d1\u73b0\u5939\u5c42Pd\u5bf9\u6c22\u7684\u7279\u6b8a\u80fd\u529b\u5bf9\u754c\u9762Ru\u6d3b\u6027\u4f4d\u7684\u50ac\u5316\u6027\u80fd\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u5373Au@Pd@Ru\u7eb3\u7c73\u50ac\u5316\u5242\u53ef\u4ee5\u5229\u7528Pd\u63d2\u5c42\u7684\u6c22\u50a8\u5b58\u80fd\u529b\u6765\u201c\u6682\u65f6\u201d\u5b58\u50a8\u754c\u9762\u5bcc\u96c6\u7684\u6d3b\u5316\u6c22\uff0c\u4e14\u5728\u201c\u6c22\u7f3a\u4e4f\u754c\u9762\u201d\u81ea\u53d1\u6ea2\u51fa\uff0c\u4e0eRu\u4e0a\u5438\u9644\u7684OH<sub>ad<\/sub>\u53d1\u751f\u53cd\u5e94\u3002\u540c\u65f6\u901a\u8fc7\u7cbe\u786e\u63a7\u5236\u5939\u5c42Pd\u7684\u539a\u5ea6\u5bf9\u6bd4\u53d1\u73b0\u6676\u683c\u81a8\u80c0\u7684\u8d85\u8584\u63d2\u5c42Pd\u66f4\u6709\u5229\u4e8e\u6d3b\u6027\u6c22\u7684\u9ad8\u6548\u50a8\u5b58\u548c\u91ca\u653e\uff0c\u5728\u6709\u6548\u964d\u4f4e\u53cd\u5e94\u901f\u7387\u51b3\u5b9a\u6027Volmer\u6b65\u9aa4\u7684\u80fd\u5792\u4e2d\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230610\/1686357685897895.png\" alt=\"6\" \/><\/section>\n<section><\/section>\n<section>\u8fd9\u4e00\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728<strong>Journal of the American Chemical Society<\/strong>\u4e0a\uff0c\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u53a6\u95e8\u5927\u5b66\u535a\u58eb\u751f<strong>\u5b8b\u73b0\u5b5f<\/strong>\u3001<strong>\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u526f\u6559\u6388\u5f20\u971e\u5149<\/strong>\u548c\u53a6\u95e8\u5927\u5b66\u7855\u58eb\u751f<strong>\u9093\u6c38\u4eae<\/strong>\u3002\u53a6\u95e8\u5927\u5b66<strong>\u8303\u51e4\u8339<\/strong>\u6559\u6388\u3001<strong>\u674e\u5251\u950b<\/strong>\u6559\u6388\u548c<strong>\u5357\u5b50\u6602<\/strong>\u535a\u58eb\u4e3a\u8be5\u5de5\u4f5c\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u7eb3\u7c73\u6676\u7ed3\u6784\u7684HS-LEIS\u6d4b\u8bd5\u5f97\u5230\u4e86\u53a6\u95e8\u5927\u5b66<strong>\u9648\u660e\u6811<\/strong><strong>\u6559\u6388<\/strong>\u7684\u5927\u529b\u652f\u6301\u3002\u539f\u4f4dXRD\u7684\u8868\u5f81\u662f\u4e0e\u53a6\u95e8\u5927\u5b66<strong>\u8c22\u5146\u96c4<\/strong><strong>\u6559\u6388<\/strong>\u56e2\u961f\u5408\u4f5c\u5b8c\u6210\u3002<\/section>\n<section data-role=\"title\" data-tools=\"135\u7f16\u8f91\u5668\" data-id=\"us-4152855\">\n<section>\n<section>\n<section>\n<section data-brushtype=\"text\"><strong>\u6587\u732e\u4fe1\u606f<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>https:\/\/doi.org\/10.1021\/jacs.3c02604<\/section>\n<section>Improving the Hydrogen Oxidation Reaction Rate of Ru by Active Hydrogen in the Ultrathin Pd Interlayer<\/section>\n<section>Xianmeng Song, Xia-Guang Zhang, Yong-Liang Deng, Zi-Ang Nan,* Weishen Song, Yanjie Wang, Linzhe Lv, Qiaorong Jiang, Xi Jin, Yanping Zheng, Mingshu Chen, Zhaoxiong Xie, Jian-Feng Li,* Zhong-Qun Tian, and Feng Ru Fan*<\/section>\n<section>DOI: 10.1021\/jacs.9b07172<\/section>\n<section data-role=\"title\" data-tools=\"135\u7f16\u8f91\u5668\" data-id=\"us-4152855\">\n<section>\n<section>\n<section>\n<section data-brushtype=\"text\"><strong>\u5bfc\u5e08\u4ecb\u7ecd<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u8303\u51e4\u8339\u6559\u6388<\/strong><\/section>\n<section>https:\/\/chem.xmu.edu.cn\/info\/1420\/9282.htm<\/section>\n<section><strong>\u674e\u5251\u950b\u6559\u6388<\/strong><\/section>\n<section>https:\/\/chem.xmu.edu.cn\/info\/1418\/1227.htm<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7814\u7a76\u80cc\u666f &nbsp; \u6c22\u6c14\u6c27\u5316\u53cd\u5e94\uff08HOR\uff09\u662f\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\uff08AEMFCs\uff09\u4e2d\u7684\u57fa\u672c\u53cd\u5e94\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48349","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48349","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48349"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48349\/revisions"}],"predecessor-version":[{"id":48350,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48349\/revisions\/48350"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48349"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48349"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48349"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}