{"id":48244,"date":"2023-06-16T08:07:40","date_gmt":"2023-06-16T00:07:40","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48244"},"modified":"2023-05-31T10:08:08","modified_gmt":"2023-05-31T02:08:08","slug":"%e6%9c%b1%e5%ae%97%e9%be%99-%e5%be%90%e6%94%bf%e6%b6%9b-%e7%8e%8b%e5%ad%90%e9%be%99am%ef%bc%9a%e8%bf%87%e7%94%b5%e4%bd%8d%e4%bd%8e%e8%87%b3280-mv%ef%bc%81%e6%96%b0%e5%9e%8bni-mof%e5%ae%9e%e7%8e%b0","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e6%9c%b1%e5%ae%97%e9%be%99-%e5%be%90%e6%94%bf%e6%b6%9b-%e7%8e%8b%e5%ad%90%e9%be%99am%ef%bc%9a%e8%bf%87%e7%94%b5%e4%bd%8d%e4%bd%8e%e8%87%b3280-mv%ef%bc%81%e6%96%b0%e5%9e%8bni-mof%e5%ae%9e%e7%8e%b0\/","title":{"rendered":"\u6731\u5b97\u9f99\/\u5f90\u653f\u6d9b\/\u738b\u5b50\u9f99AM\uff1a\u8fc7\u7535\u4f4d\u4f4e\u81f3280 mV\uff01\u65b0\u578bNi MOF\u5b9e\u73b0\u9ad8\u6548\u7535\u50ac\u5316\u6c34\u6c27\u5316"},"content":{"rendered":"

\u7531\u4e8e\u6790\u6c27\u53cd\u5e94(OER)\u52a8\u529b\u5b66\u7f13\u6162\uff0c\u7535\u50ac\u5316\u6c34\u5206\u89e3\u88c5\u7f6e\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u53d7\u5230\u9650\u5236\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u948c(Ru)\u548c\u94f1(Ir)\u57fa\u50ac\u5316\u5242(RuO2<\/sub>\u548cIrO2<\/sub>)\u7531\u4e8e\u5176\u4f18\u8d8a\u7684\u6c34\u6c27\u5316\u6d3b\u6027\u800c\u88ab\u8ba4\u4e3a\u662fOER\u7684\u57fa\u51c6\u50ac\u5316\u5242\u3002<\/p>\n

\u4f46\u662f\uff0cRu\u548cIr\u4ef7\u683c\u6602\u8d35\u4e14\u7a00\u7f3a\uff0c\u9650\u5236\u4e86\u5b83\u4eec\u5728\u5927\u89c4\u6a21\u8bbe\u5907\u4e2d\u7684\u4f7f\u7528\u3002\u6839\u636e\u6700\u8fd1\u7684\u7814\u7a76\uff0c\u57fa\u4e8e\u975e\u8d35\u91d1\u5c5e\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u5df2\u6210\u4e3a\u4e00\u79cd\u5e94\u7528\u5e7f\u6cdb\u7684OER\u7535\u50ac\u5316\u5242\u3002\u7531\u4e8e\u5176\u53ef\u53ca\u6027\u3001\u53ef\u8c03\u5b54\u9699\u7387\u548c\u5316\u5b66\u529f\u80fd\u4ee5\u53ca\u660e\u786e\u7684\u5468\u671f\u6846\u67b6\u7ed3\u6784\uff0c\u5728\u6784\u5efa\u9ad8\u6548\u6c34\u6c27\u5316\u50ac\u5316\u5242\u65b9\u9762\u5177\u6709\u5f88\u5927\u7684\u524d\u666f\u3002<\/p>\n

\"1\"<\/p>\n

\"2\"<\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u6731\u5b97\u9f99<\/strong>\u3001\u65b0\u52a0\u5761\u79d1\u6280\u7814\u7a76\u5c40(A*STAR)\u5f90\u653f\u6d9b<\/strong>\u548c\u66a8\u5357\u5927\u5b66\u738b\u5b50\u9f99<\/strong>\u7b49\u8bbe\u8ba1\u4e86\u4e00\u79cd\u4ee5\u786b\u9187\u5b98\u80fd\u5316\u76842,6-\u4e8c\u5def\u57fa\u82ef-1,4-\u4e8c\u7fa7\u9178(DMBD)\u4f5c\u4e3a\u8fde\u63a5\u5242\u7684Ni-MOF\u50ac\u5316\u5242(Ni(DMBD)\u2212MOF)\uff0c\u5176\u5177\u6709\u4f18\u5f02\u7684\u7535\u50ac\u5316OER\u6d3b\u6027\u3002<\/p>\n

\u8be5\u4e8c\u7ef4MOF\u5177\u6709\u91d1\u5c5e\u2212\u786b(M\u2212S)\u548c\u91d1\u5c5e\u2212\u6c27(M\u2212O)\u952e\uff0c\u5e76\u4e14\u5c42\u95f4\u7a7a\u95f4\u5305\u542b\u7b2c\u4e8c\u79cd\u7c7b\u578b\u7684\u91d1\u5c5e\u79bb\u5b50\u4e0e\u7fa7\u57faO\u4f9b\u4f53\u7ed3\u5408\uff0c\u5e76\u7531\u6c34\u914d\u4f53\u6865\u63a5\u3002\u8fd9\u79cd\u65b0\u7684MOF\u5e76\u4e0d\u662f\u50cf\u4e4b\u524d\u7684\u7814\u7a76\u90a3\u6837\u5c06Ni\u2212S\u50ac\u5316\u5242\u9897\u7c92\u6c89\u79ef\u5230MOF\u57fa\u8d28\u4e0a\uff0c\u800c\u662f\u5c06Ni\u2212S\u96c6\u6210\u5230\u914d\u4f4d\u94fe\u4e2d\uff0c\u4ee5\u529f\u80fd\u5316MOF\u6846\u67b6\u3002<\/p>\n

\"3\"<\/p>\n

\"9\"<\/p>\n

\u6b64\u5916\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0c\u6240\u5236\u5907\u7684Ni(DMBD)\u2212MOF\u5177\u6709\u91d1\u5c5e\u7535\u5b50\u7ed3\u6784\uff0c\u8868\u660e\u96c6\u6210\u7684Ni\u2212S\u589e\u5f3a\u4e86\u7535\u5bfc\u7387\u3002<\/p>\n

\u57fa\u4e8e\u4e0a\u8ff0\u7ed3\u8bba\uff0c\u7814\u7a76\u4eba\u5458\u5728Ni(DMBD)\u2212MOF\u52a0\u5165Fe\u5143\u7d20\uff0c\u53cc\u91d1\u5c5eNiFe(DMBD)-MOF\u5728100 mA cm\u22122<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u8fc7\u7535\u4f4d\u4f4e\u81f3280 mV\uff1b\u5728\u4ee5NiFe(DMBD)-MOF\/NF\u4e3a\u9633\u6781\u548cPt\/C\/NF\u4e3a\u9634\u6781\u7684\u6c34\u7535\u89e3\u69fd\u4e2d\uff0c\u4ec5\u97001.50 V\u7684\u7535\u6c60\u7535\u538b\u5c31\u80fd\u4ea7\u751f10 mA cm\u22122<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

\u603b\u7684\u6765\u8bf4\uff0c\u672c\u7814\u7a76\u5c55\u793a\u4e86\u4e00\u79cd\u9ad8\u6548\u7a33\u5b9a\u7684MOF OER\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u4e3a\u5229\u7528\u5206\u5b50\u8bbe\u8ba1\u548c\u6676\u4f53\u5de5\u7a0b\u5b9e\u73b0\u660e\u786e\u5b9a\u4e49\u7684\u6676\u4f53\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u6709\u6548\u7b56\u7565\u3002<\/p>\n

Molecular Engineering Metal-Organic Frameworks as Efficient Electrochemical Catalysis for Water Oxidation. Advanced Materials, 2023. DOI: 10.1002\/adma.202300945<\/p>\n

 <\/p>\n

\n
\n
\n
<\/section>\n<\/section>\n<\/section>\n<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u7531\u4e8e\u6790\u6c27\u53cd\u5e94(OER)\u52a8\u529b\u5b66\u7f13\u6162\uff0c\u7535\u50ac\u5316\u6c34\u5206\u89e3\u88c5\u7f6e\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u53d7\u5230\u9650\u5236\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u948c(Ru)\u548c\u94f1(Ir)\u57fa\u50ac […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48244","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48244","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48244"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48244\/revisions"}],"predecessor-version":[{"id":48245,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48244\/revisions\/48245"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48244"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48244"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48244"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}