{"id":48214,"date":"2023-06-12T09:03:56","date_gmt":"2023-06-12T01:03:56","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48214"},"modified":"2023-05-28T09:06:42","modified_gmt":"2023-05-28T01:06:42","slug":"angew-chem-%ef%bc%9a%e8%b0%83%e6%95%b4%e9%87%91%e5%b1%9e%e6%b4%bb%e6%80%a7%e4%b8%ad%e5%bf%83%e9%85%8d%e4%bd%8d%e4%bb%a5%e6%94%b9%e5%8f%98%e6%b4%bb%e6%80%a7%e4%b8%ad%e5%bf%83%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e8%b0%83%e6%95%b4%e9%87%91%e5%b1%9e%e6%b4%bb%e6%80%a7%e4%b8%ad%e5%bf%83%e9%85%8d%e4%bd%8d%e4%bb%a5%e6%94%b9%e5%8f%98%e6%b4%bb%e6%80%a7%e4%b8%ad%e5%bf%83%e7%9a%84\/","title":{"rendered":"Angew. Chem. \uff1a\u8c03\u6574\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\u914d\u4f4d\u4ee5\u6539\u53d8\u6d3b\u6027\u4e2d\u5fc3\u7684\u201c\u8dc3\u8fc1\u201d\u884c\u4e3a"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u539f\u4f4dHERFD-XANES\u6d4b\u8bd5\uff0c\u7814\u7a76\u8005\u89c2\u6d4b\u5230\u4e86\u7535\u50ac\u5316\u6c27\u8fd8\u539f\u8fc7\u7a0b\u4e2dCo-Nx\u6d3b\u6027\u4f4d\u70b9\u4e2d\u7684Co\u4f1a\u53d1\u751f\u201c\u8dc3\u8fc1\u201d\u73b0\u8c61\u3002\u5728\u7ed3\u5408\u4e86\u7535\u5316\u5b66\u6d4b\u8bd5\u7684\u7ed3\u679c\u4e4b\u540e\uff0c\u7814\u7a76\u8005\u53d1\u73b0Co\u4e2d\u5fc3\u7684\u201c\u8dc3\u8fc1\u201d\u5e45\u5ea6\u4f1a\u5bf9\u6c27\u8fd8\u539f\u9009\u62e9\u6027\u6709\u91cd\u5927\u5f71\u54cd\u3002\u901a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\uff0c\u7814\u7a76\u8005\u63a8\u6d4bCo\u6d3b\u6027\u4e2d\u5fc3\u5468\u56f4\u6c2e\u539f\u5b50\u7684\u914d\u4f4d\u53ef\u80fd\u4f1a\u5bf9\u5176\u539f\u4f4d\u72b6\u6001\u4e0b\u7684\u201c\u8dc3\u8fc1\u201d\u884c\u4e3a\u6709\u51b3\u5b9a\u4f5c\u7528\u3002<\/p>\n<p>\u5f97\u76ca\u4e8e\u5176\u8f83\u9ad8\u7684\u5de5\u4f5c\u7535\u4f4d\uff0c\u7535\u50ac\u5316\u6c27\u8fd8\u539f\u53cd\u5e94\u4e0d\u4ec5\u53ef\u4ee5\u7528\u4f5c\u71c3\u6599\u7535\u6c60\u7684\u9634\u6781\u53cd\u5e94\uff0c\u8fd8\u53ef\u4ee5\u7528\u6765\u5236\u5907\u8fc7\u6c27\u5316\u6c22\u3002\u7136\u800c\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u9009\u62e9\u6027\u4e00\u76f4\u662f\u4e00\u4e2a\u4ee4\u4eba\u68d8\u624b\u7684\u95ee\u9898\uff1a\u4e00\u65b9\u9762\uff0c\u5728\u56db\u7535\u5b50\u53cd\u5e94\u7684\u5e94\u7528\u4e2d\uff0c\u7531\u4e8c\u7535\u5b50\u8def\u5f84\u4ea7\u751f\u7684\u5c11\u91cf\u8fc7\u6c27\u5316\u6c22\u53ef\u80fd\u4f1a\u901a\u8fc7\u82ac\u987f\u53cd\u5e94\u7834\u574f\u79bb\u5b50\u4ea4\u6362\u819c\uff0c\u5f71\u54cd\u5668\u4ef6\u7a33\u5b9a\u6027\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u5728\u4e8c\u7535\u5b50\u8def\u5f84\u5236\u5907\u7eff\u8272\u8fc7\u6c27\u5316\u6c22\u5e94\u7528\u4e2d\uff0c\u56db\u7535\u5b50\u53cd\u5e94\u7684\u5b58\u5728\u4f1a\u964d\u4f4e\u5236\u5907\u7684\u80fd\u91cf\u5229\u7528\u6548\u7387\uff0c\u589e\u52a0\u6210\u672c\u3002\u4e3a\u4e86\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\uff0c\u9700\u8981\u7814\u7a76\u8005\u4eec\u5728\u539f\u5b50\u7ea7\u522b\u7ef4\u5ea6\u4e0a\u63a2\u7a76\u6c27\u8fd8\u539f\u9009\u62e9\u6027\u7684\u5f71\u54cd\u56e0\u7d20\u3002<\/p>\n<p>\u672c\u6587\u53d1\u73b0\u901a\u8fc7\u8c03\u6574\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\u5468\u56f4\u6c2e\u539f\u5b50\u7684\u914d\u4f4d\u60c5\u51b5\uff0c\u53ef\u4ee5\u6539\u53d8\u6d3b\u6027\u4e2d\u5fc3\u5728\u539f\u4f4d\u6761\u4ef6\u4e0b\u53d1\u751f\u7684\u201c\u8dc3\u8fc1\u201d\u884c\u4e3a\uff0c\u7ee7\u800c\u53ef\u4ee5\u5927\u5e45\u5ea6\u63d0\u5347\u50ac\u5316\u5242\u7684\u6027\u80fd\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230516\/1684203688380396.png\" alt=\"1\" \/><\/section>\n<section>\u56fe1\u7535\u50ac\u5316\u4e8c\u7535\u5b50\u6c27\u8fd8\u539f\u6570\u636e\u5206\u6790<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u5bf9\u8fc7\u5f80\u7535\u50ac\u5316\u4e8c\u7535\u5b50\u6c27\u8fd8\u539f\u9886\u57df\u7684\u7edf\u8ba1\u6570\u636e\u5206\u6790\uff0c\u4f5c\u8005\u53d1\u73b0\u65e5\u524d\u6700\u53d7\u6b22\u8fce\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u601d\u8def\u662f\u57fa\u4e8eO<sub>2<\/sub>* hydrogenation\u548cOOH* desorption\u8fd9\u4e24\u6b65\u7684Sabatier Volcano Plot \uff08\u4ee5OOH*\u7684\u81ea\u7531\u80fd\u4e3adescriptor\uff09\u8fd9\u4e2a\u6982\u5ff5\u800c\u5efa\u7acb\u7684\u3002\u7136\u800c\u5c3d\u7ba1\u5f88\u591a\u7814\u7a76\u90fd\u58f0\u79f0\u81ea\u5df1\u7684\u50ac\u5316\u5242\u7b26\u5408Sabatier Principle\uff0c\u4f5c\u8005\u53d1\u73b0\u76ee\u524d\u6ca1\u6709\u50ac\u5316\u5242\u53ef\u4ee5\u5728\u5927\u7535\u6d41\u60c5\u51b5\u4e0b\uff081 mA cm<sup>-2<\/sup>\uff0c\u65cb\u8f6c\u73af\u76d8\u7535\u6781\u6d4b\u8bd5\u6761\u4ef6\u4e0b\uff09\u63a5\u8fd1\u4e8c\u7535\u5b50\u6c27\u8fd8\u539f\u7684\u7406\u8bba\u50ac\u5316\u7535\u4f4d\u3002\u4f5c\u8005\u8ba4\u4e3a\u8fd9\u662f\u7531\u4e8eSabatier Volcano Plot\u601d\u8def\u53ea\u8003\u8651\u4e86\u4e8c\u7535\u5b50\u8def\u5f84\u7684\u4f18\u5316\uff08\u5373\u8d77\u59cb\u7535\u4f4d\u7684\u4f18\u5316\uff09\uff0c\u800c\u5e76\u6ca1\u6709\u8003\u8651\u5230\u56db\u7535\u5b50\u8def\u5f84\u5bf9\u4e8c\u7535\u5b50\u8def\u5f84\u7684\u5f71\u54cd\u3002\u6362\u8a00\u4e4b\uff0c\u7531\u4e8e\u6c27\u8fd8\u539f\u53cd\u5e94\u662f\u4e00\u4e2a\u7531\u4f20\u8d28\u6240\u7ea6\u675f\u7684\u53cd\u5e94\uff0c\u5355\u4f4d\u65f6\u95f4\u5185\u80fd\u88ab\u8fd8\u539f\u7684\u6c27\u6c14\u662f\u6709\u9650\u7684\uff1b\u5982\u679c\u6709\u4e00\u90e8\u5206\u6c27\u6c14\u53d1\u751f\u7684\u662f\u56db\u7535\u5b50\u53cd\u5e94\uff0c\u7eb5\u4f7f\u4e8c\u7535\u5b50\u8def\u5f84\u7684\u53cd\u5e94\u70ed\u529b\u5b66\uff08\u5373\u8d77\u59cb\u7535\u4f4d\uff09\u751a\u81f3\u53cd\u5e94\u52a8\u529b\u5b66\u5df2\u8fbe\u81ea\u8eab\u7684\u6700\u4f18\u72b6\u6001\uff0c\u8fc7\u6c27\u5316\u6c22\u7684\u4ea7\u751f\u901f\u7387\u4e5f\u65e0\u6cd5\u8fbe\u5230\u6700\u4f18\uff1b\u6700\u7ec8\u5bfc\u81f4\u4e86\u5728\u5927\u7535\u6d41\u60c5\u51b5\u4e0b\u50ac\u5316\u5242\u7684\u6d3b\u6027\u8fdc\u8fdc\u4e0d\u5982\u7406\u8bba\u503c\u3002\u4f5c\u8005\u8ba4\u4e3a\u5982\u679c\u53ef\u4ee5\u901a\u8fc7\u727a\u7272\u8d77\u59cb\u7535\u4f4d\uff08\u5373OOH*\u7684\u81ea\u7531\u80fd\u504f\u79bb\u706b\u5c71\u56fe\u7684\u9876\u7aef\uff09\u6765\u4f7f\u5f97\u4e8c\u7535\u5b50\u8def\u5f84\u7684\u9009\u62e9\u6027\u5f97\u4ee5\u63d0\u9ad8\uff0c\u8fd9\u6837\u5728\u5927\u7535\u6d41\u60c5\u51b5\u4e0b\u8fc7\u6c27\u5316\u6c22\u4ea7\u7387\u53ef\u80fd\u4f1a\u6bd4\u7b26\u5408\u706b\u5c71\u56fe\u7406\u8bba\u7684\u50ac\u5316\u5242\u7684\u4ea7\u7387\u8981\u9ad8\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230516\/1684203699853558.png\" alt=\"2\" \/><\/section>\n<section>\u56fe2\u00a0\u4e0d\u540c\u7684Co-Nx\u50ac\u5316\u5242\u7684\u8868\u5f81<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u9a8c\u8bc1\u4e0a\u8ff0\u731c\u60f3\u7684\u53ef\u884c\u6027\uff0c\u4f5c\u8005\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4e0d\u540c\u914d\u4f4d\u73af\u5883\u7684Co-Nx\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u5206\u522b\u4e3aCoN<sub>4+4<\/sub>@ACNT\uff0cCoN<sub>4<\/sub>@ACNT\u548cCoN<sub>2+x<\/sub>@ACNT\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230516\/1684203709364848.png\" alt=\"5\" \/><\/section>\n<section>\u56fe3\u00a0\u7535\u5316\u5b66\u8868\u5f81<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u53d1\u73b0\u5c3d\u7ba1\u8fd9\u4e09\u4e2a\u50ac\u5316\u5242\u7684\u8d77\u59cb\u7535\u4f4d\u76f8\u4f3c\uff0c\u4f46\u662f\u4e0d\u540c\u7684\u6c2e\u914d\u4f4d\u73af\u5883\u4f1a\u4f7f\u5f97\u50ac\u5316\u5242\u5177\u6709\u5b8c\u5168\u4e0d\u540c\u7684\u6c27\u8fd8\u539f\u9009\u62e9\u6027\u3002\u5176\u4e2dCoN<sub>4+4<\/sub>@ACNT\u4e0d\u4ec5\u4e8c\u7535\u5b50\u8def\u5f84\u9009\u62e9\u6027\u63a5\u8fd1100%\uff0c\u8fd8\u53ef\u4ee5\u57280.82 V vs.\u00a0RHE\u7535\u4f4d\u4e0b\u5c31\u53ef\u4ee5\u8fbe\u52301\u00a0mA\u00a0cm<sup>-2<\/sup>\u7684\u8fc7\u6c27\u5316\u6c22\u751f\u4ea7\u7535\u6d41\uff1b\u800cCoN<sub>4<\/sub>@ACNT\u663e\u793a\u51fa\u6df7\u5408\u7684\u9009\u62e9\u6027\uff1bCoN<sub>2+x<\/sub>@ACNT\u5219\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u56db\u7535\u5b50\u8def\u5f84\u9009\u62e9\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section><img decoding=\"async\" title=\"6\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230516\/1684203722646085.png\" alt=\"6\" \/><\/section>\n<\/section>\n<section>\u56fe4\u00a0\u539f\u4f4dHERFD-XANES\u8868\u5f81<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u89e3\u91ca\u50ac\u5316\u5242\u622a\u7136\u4e0d\u540c\u7684\u9009\u62e9\u6027\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u539f\u4f4d\u5149\u8c31\u6d4b\u8bd5\u3002\u5176\u4e2dpre-edge peak\u5bf9\u5e94\u7740\u50ac\u5316\u5242\u5438\u9644\u7684\u4e2d\u95f4\u4f53\uff08\u6bd4\u5982O<sub>2<\/sub>*\uff09\uff0cedge peak\u5219\u662f\u53ef\u4ee5\u53cd\u6620\u51fa\u50ac\u5316\u5242\u5bf9\u79f0\u6027\u7684\u53d8\u5316\u3002\u4f5c\u8005\u53d1\u73b0\u5bf9\u4e8eCoN<sub>4<\/sub>@ACNT\u8fd9\u4e2a\u6837\u54c1\uff0c\u52a0\u5927\u8fc7\u7535\u52bf\u4f1a\u589e\u52a0\u50ac\u5316\u5242\u7684\u4e0d\u5bf9\u79f0\u6027\uff08\u8fd9\u662f\u7531\u4e8eCo\u4e2d\u5fc3\u504f\u79bbCo-Nx\u5e73\u9762\u6240\u5f15\u8d77\u7684\uff09\u548c\u6539\u5584O<sub>2<\/sub>* hydrogenation\u8fd9\u4e00\u6b65\u7684\u901f\u7387\uff0c\u800c\u50ac\u5316\u5242\u6b64\u65f6\u4e5f\u66f4\u52a0\u503e\u5411\u4e8e\u4e8c\u7535\u5b50\u8def\u5f84\u3002\u901a\u8fc7CoN<sub>4<\/sub>@ACNT\u548cCoN<sub>4+4<\/sub>@ACNT\u7684\u5bf9\u6bd4\uff0c\u4f5c\u8005\u53d1\u73b0CoN<sub>4+4<\/sub>@ACNT\u7684Co\u4e2d\u5fc3\u66f4\u5bb9\u6613\u53d1\u751f\u504f\u79bb\u73b0\u8c61\uff08\u540c\u65f6\u5176\u4e5f\u5177\u6709\u66f4\u597d\u7684O<sub>2<\/sub>* hydrogenation\u901f\u7387\uff09\uff0c\u8fd9\u4e5f\u548c\u5b83\u66f4\u597d\u7684\u4e8c\u7535\u5b50\u9009\u62e9\u6027\u76f8\u5bf9\u5e94\u3002\u6545\u4f5c\u8005\u8ba4\u4e3a\u5f53\u50ac\u5316\u5242\u53d1\u751f\u66f4\u5927\u5e45\u5ea6\u7684\u91d1\u5c5e\u4e2d\u5fc3\u201c\u8dc3\u8fc1\u201d\u73b0\u8c61\u65f6\uff0c\u5176\u4f1a\u5c55\u73b0\u51fa\u66f4\u597d\u7684O<sub>2<\/sub>* hydrogenation\u8868\u73b0\uff0c\u4ece\u800c\u63d0\u9ad8\u4e8c\u7535\u5b50\u8def\u5f84\u9009\u62e9\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><img decoding=\"async\" title=\"7\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230516\/1684203736302179.png\" alt=\"7\" \/><\/section>\n<\/section>\n<section>\n<section><\/section>\n<p><img decoding=\"async\" title=\"7\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230516\/1684203777999138.png\" alt=\"7\" \/>\u56fe4\u00a0\u56db\u7535\u5b50\u8def\u5f84\u9009\u62e9\u6027\u7684\u63d0\u9ad8<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4f18\u5316CoN<sub>2+x<\/sub>@ACNT\u7684\u56db\u7535\u5b50\u8def\u5f84\u9009\u62e9\u6027\uff0c\u4f5c\u8005\u53d1\u73b0\u5e76\u5229\u7528\u4e86\u7531\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u7684redox behavior\u5f15\u8d77\u7684\u201celectron dislocation\u201d\u73b0\u8c61\u3002<\/p>\n<p>\u603b\u7ed3\u4e0e\u5c55\u671b\uff1a1.\u7531\u4e8e\u539f\u4f4d\u5149\u8c31\u6d4b\u8bd5\u662f\u57282021\u5e74\u8fdb\u884c\u7684\uff0c\u53d7\u9650\u4e8e\u793e\u4ea4\u758f\u79bb\u653f\u7b56\u5bf9\u4e8e\u5b9e\u9a8c\u5ba4\u5b89\u5168\u7684\u9650\u5236\uff0c\u5b9e\u9a8c\u4f7f\u7528\u7684\u662f\u7a7a\u6c14\u800c\u975e\u6c27\u6c14\uff0c\u8fd9\u4e5f\u5bfc\u81f4\u4e86\u539f\u4f4d\u5149\u8c31\u6d4b\u8bd5\u4e2d\u4fe1\u53f7\u7684\u53d8\u5316\u8f83\u5f31\uff0c\u4f5c\u8005\u8ba4\u4e3a\u672a\u6765\u6709\u6761\u4ef6\u7684\u60c5\u51b5\u4e0b\u5e94\u8be5\u5728\u6c27\u6c14\u6761\u4ef6\u4e0b\u8fdb\u884c\u6d4b\u8bd5\u30022.HERFD-XANES\u6d4b\u8bd5\u76f8\u5bf9\u4e8e\u4f20\u7edf\u7684XANES\u6d4b\u8bd5\uff0c\u5177\u6709\u66f4\u597d\u7684energy resolution\uff0c\u4f46\u540c\u65f6\u5176\u4fe1\u53f7\u5f3a\u5ea6\u4e5f\u8fdc\u8fdc\u66f4\u5f31\uff0c\u52a0\u4e0a\u672c\u6b21\u7814\u7a76\u7684\u50ac\u5316\u5242\u4e3a\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u8fd9\u4e5f\u662f\u539f\u4f4d\u5149\u8c31\u6d4b\u8bd5\u4fe1\u53f7\u53d8\u5316\u8f83\u5c0f\u7684\u53e6\u4e00\u4e2a\u53ef\u80fd\u56e0\u7d20\u30023.\u4f5c\u8005\u89c2\u6d4b\u5230\u539f\u4f4d\u6761\u4ef6\u4e0b\u50ac\u5316\u5242\u91d1\u5c5e\u4e2d\u5fc3\u7684\u201c\u8dc3\u8fc1\u201d\u73b0\u8c61\uff0c\u8be5\u73b0\u8c61\u6539\u53d8\u4e86\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u751f\u6210\u901f\u7387\u3002\u4f5c\u8005\u8ba4\u4e3a\u201c\u8dc3\u8fc1\u201d\u662f\u7531\u4e8e\u65bd\u52a0\u7684\u7535\u538b\u6240\u5f15\u8d77\u7684\u3002\u4f46\u662f\u4e5f\u4e0d\u80fd\u6392\u9664\u65bd\u52a0\u7535\u538b\u540e\u4ea7\u751f\u4e86\u4e2d\u95f4\u4f53\uff0c\u4e2d\u95f4\u4f53\u5438\u9644\u5728\u91d1\u5c5e\u4f4d\u70b9\u4e0a\uff0c\u5f15\u8d77\u4e86\u201c\u8dc3\u8fc1\u201d\u73b0\u8c61\u3002\u6545\u7a76\u7adf\u662f\u50ac\u5316\u5242\u201c\u8dc3\u8fc1\u201d\u73b0\u8c61\u5bfc\u81f4\u4e86\u4e2d\u95f4\u4f53\u7684\u751f\u6210\u901f\u7387\u7684\u6539\u53d8\uff0c\u8fd8\u662f\u4e2d\u95f4\u4f53\u7684\u751f\u6210\u5bfc\u81f4\u50ac\u5316\u5242\u91d1\u5c5e\u4e2d\u5fc3\u201c\u6da6\u201d\u4e86\uff0c\u9700\u8981\u672a\u6765\u5728\u60f0\u6027\u6c14\u4f53\u6761\u4ef6\u4e0b\u8fdb\u884c\u5bf9\u6bd4\u5b9e\u9a8c\u30024.\u672a\u6765\u9700\u8981\u66f4\u8be6\u7ec6\u7684\u7406\u8bba\u8ba1\u7b97\u6765\u89e3\u91ca\u4e3a\u4f55\u5bf9\u4e8eCo-Nx\u50ac\u5316\u5242\uff0c\u66f4\u597d\u7684O<sub>2<\/sub>* hydrogenation\u901f\u7387\u4f1a\u5bfc\u81f4\u66f4\u9ad8\u7684\u4e8c\u7535\u5b50\u9009\u62e9\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Approaching Theoretical Performances of Electrocatalytic Hydrogen Peroxide Generation by Cobalt-Nitrogen Moieties<\/p>\n<p>Runjia Lin,\u00a0Liqun Kang,\u00a0Karolina Lisowska,\u00a0Weiying He,\u00a0Siyu Zhao,\u00a0Shusaku Hayama,\u00a0Graham J. Hutchings,\u00a0Dan J. L. Brett,\u00a0Furio Cor\u00e0,\u00a0Ivan P. Parkin,\u00a0Guanjie He<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202301433<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u901a\u8fc7\u539f\u4f4dHERFD-XANES\u6d4b\u8bd5\uff0c\u7814\u7a76\u8005\u89c2\u6d4b\u5230\u4e86\u7535\u50ac\u5316\u6c27\u8fd8\u539f\u8fc7\u7a0b\u4e2dCo-Nx\u6d3b\u6027\u4f4d\u70b9\u4e2d\u7684Co\u4f1a\u53d1\u751f\u201c\u8dc3\u8fc1\u201d\u73b0 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48214","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48214","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48214"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48214\/revisions"}],"predecessor-version":[{"id":48215,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48214\/revisions\/48215"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48214"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48214"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48214"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}