{"id":48158,"date":"2023-06-06T08:26:27","date_gmt":"2023-06-06T00:26:27","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48158"},"modified":"2023-05-22T10:29:55","modified_gmt":"2023-05-22T02:29:55","slug":"angew-chem-%ef%bc%9a%e6%b0%9f%e5%a1%ab%e5%85%85%e6%b0%a7%e7%a9%ba%e4%bd%8d%e6%bf%80%e6%b4%bb%e6%99%b6%e6%a0%bc%e6%b0%a7%e6%b4%bb%e6%80%a7%e5%ae%9e%e7%8e%b0oer%e5%8f%8d%e5%ba%94%e6%9c%ba%e5%88%b6","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%b0%9f%e5%a1%ab%e5%85%85%e6%b0%a7%e7%a9%ba%e4%bd%8d%e6%bf%80%e6%b4%bb%e6%99%b6%e6%a0%bc%e6%b0%a7%e6%b4%bb%e6%80%a7%e5%ae%9e%e7%8e%b0oer%e5%8f%8d%e5%ba%94%e6%9c%ba%e5%88%b6\/","title":{"rendered":"Angew. Chem. \uff1a\u6c1f\u586b\u5145\u6c27\u7a7a\u4f4d\u6fc0\u6d3b\u6676\u683c\u6c27\u6d3b\u6027\u5b9e\u73b0OER\u53cd\u5e94\u673a\u5236\u8c03\u63a7"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u6c34\u6c27\u5316\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u662f\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u3001\u7535\u89e3\u6c34\u5236\u6c22\u3001\u71c3\u6599\u7535\u6c60\u7b49\u65b0\u80fd\u6e90\u6280\u672f\u7684\u5173\u952e\u53cd\u5e94\u4e4b\u4e00\u3002\u5176\u7f13\u6162\u7684\u56db\u7535\u5b50-\u8d28\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u662f\u5236\u7ea6\u5176\u6548\u7387\u7684\u5173\u952e\u3002\u5982\u4f55\u63d0\u5347OER\u7535\u50ac\u5316\u6d3b\u6027\u662f\u5f53\u524d\u7814\u7a76\u7684\u70ed\u70b9\u3002\u76ee\u524d\u5e7f\u6cdb\u63a5\u53d7\u7684\u7535\u50ac\u5316OER\u53cd\u5e94\u673a\u5236\u4e3b\u8981\u6709\u4e24\u79cd\uff0c\u4e00\u662f\u4ee5\u91d1\u5c5e\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\u7684\u53cd\u5e94\u7269\u5438\u8131\u9644\uff08\u5373*OH \u2192 *O \u2192 *OOH \u2192 *O<sub>2<\/sub>\u8fc7\u7a0b\uff09\u673a\u5236\uff08Adsorbate evolution mechanism, AEM\uff09\u3002\u4e8c\u662f\u50ac\u5316\u5242\u81ea\u8eab\u6676\u683c\u6c27\u5728OER\u7535\u52bf\u4e0b\u7684\u6c27\u5316\u8fd8\u539f\u548c\u8fc1\u79fb\uff08Lattice oxygen oxidation mechanism, LOM\uff09\u3002\u5bf9\u4e8eAEM\u8fc7\u7a0b\uff08\u5373\u91d1\u5c5e\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\uff09\uff0c\u6c27-\u6c27\u6210\u952e\u975e\u5e38\u96be\uff0c\u800cLOM\u8fc7\u7a0b\u4e2d\u7684\u6676\u683c\u6c27\u6c27\u5316\u8fd8\u539f\u80fd\u591f\u76f4\u63a5\u751f\u6210O\u2013O\u5316\u5b66\u952e\uff0c\u7a81\u7834AEM\u7684\u9650\u5236\u3002\u4f46LOM\u8fc7\u7a0b\u4e2d\u6676\u683c\u6c27\u6c27\u5316\u5f15\u8d77\u7684\u8868\u9762\u91cd\u6784\u4f1a\u5f71\u54cd\u50ac\u5316\u5242\u7a33\u5b9a\u6027\uff0c\u800cAEM\u8fc7\u7a0b\u5219\u901a\u5e38\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u5b9e\u73b0AEM\u548cLOM\u8fc7\u7a0b\u7684\u8c03\u63a7\u80fd\u534f\u540c\u4f18\u5316\u50ac\u5316\u5242\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u4f46\u57fa\u4e8e\u50ac\u5316\u5242\u56fa\u6709\u6027\u80fd\u5e76\u5b9e\u73b0\u50ac\u5316\u8def\u5f84\u8c03\u63a7\u4ecd\u7136\u9762\u4e34\u6311\u6218\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u5e7f\u5dde\u5927\u5b66\u5218\u5146\u6e05\u6559\u6388\u56e2\u961f\uff0c\u4ee5ZnCo<sub>2<\/sub>O<sub>4<\/sub>\u5c16\u6676\u77f3\u4e3a\u7814\u7a76\u5bf9\u8c61\uff0c\u5c06F\u79bb\u5b50\u586b\u5145\u8fdbZnCo<sub>2<\/sub>O<sub>4<\/sub>\u7684\u6c27\u7a7a\u4f4d\u4e2d\uff0c\u5efa\u7acb\u4e86\u50ac\u5316\u5242\u7535\u5b50\u7ed3\u6784\u4e0eOER\u50ac\u5316\u673a\u5236\u4e4b\u95f4\u7684\u8054\u7cfb\u3002\u5176\u4e2d\uff0cF\u79bb\u5b50\u586b\u5145\u63d0\u9ad8\u4e86O 2p\u4e2d\u5fc3\uff0c\u6fc0\u6d3b\u4e86\u6676\u683cO\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\uff0c\u5b9e\u73b0\u7535\u50ac\u5316OER\u4eceAEM\u5230LOM\u8def\u5f84\u7684\u8f6c\u6362\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230511\/1683771991672074.jpg\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u672c\u5de5\u4f5c\u4e2d\uff0cZnCo<sub>2<\/sub>O<sub>4<\/sub>\u5c16\u6676\u77f3\u56db\u9762\u4f53\u4f4d\u4e3aOER\u60f0\u6027Zn\uff0c\u56e0\u6b64\u53ef\u4ee5\u66f4\u597d\u53bb\u7814\u7a76\u516b\u9762\u4f53\u4f4dCo\u6d3b\u6027\uff0c\u4f5c\u8005\u901a\u8fc7\u9884\u8fd8\u539f\u5904\u7406\u5f97\u5230\u5bcc\u542b\u6c27\u7a7a\u7a74\u7684ZnCo<sub>2<\/sub>O<sub>4<\/sub>\uff0c\u8fdb\u4e00\u6b65\u901a\u8fc7\u540e\u7eed\u70ed\u5904\u7406\u586b\u5145F\u79bb\u5b50\uff0c\u540c\u6b65\u8f90\u5c04\u7ed3\u679c\u663e\u793a\uff0cF\u79bb\u5b50\u586b\u5145\u540e\u7684Co\u2013O\u952e\u952e\u957f\u66f4\u77ed\uff0c\u610f\u5473\u7740F\u79bb\u5b50\u586b\u5145\u589e\u5f3a\u4e86Co\u2013O\u5171\u4ef7\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230511\/1683772001944882.png\" alt=\"8\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u7535\u5316\u5b66\u6d4b\u8bd5\u7ed3\u679c\u663e\u793aF\u79bb\u5b50\u586b\u5145\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u7535\u50ac\u5316OER\u7535\u52bf\u3002F\u586b\u5145ZnCo<sub>2<\/sub>O<sub>4<\/sub>\u50ac\u5316\u5242\u5bf9\u7535\u89e3\u6db2pH\u66f4\u4e3a\u654f\u611f\uff0c\u56e0\u4e3aLOM\u50ac\u5316\u8def\u5f84\u7684\u9650\u901f\u6b65\u9aa4\u901a\u5e38\u4e3a\u7f9f\u57fa\u7684\u53bb\u8d28\u5b50\u5316\u3002\u4f5c\u8005\u5728\u7535\u50ac\u5316\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u52a0\u5165\u56db\u7532\u57fa\u94f5\u9633\u79bb\u5b50\uff08TMA<sup>+<\/sup>\uff09\uff0c\u8bc1\u5b9e\u4e86LOM\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u4f1a\u4ea7\u751f\u8fc7\u6c27\u7c7b\uff08O<sub>2<\/sub><sup>2<\/sup>\uff09\u548c\u8d85\u6c27\u7c7b\uff08O<sub>2<\/sub><sup>&#8211;<\/sup>\uff09\u7269\u8d28\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"9\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230511\/1683772011950133.jpg\" alt=\"9\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8fdb\u4e00\u6b65\u6a21\u62df\u8ba1\u7b97\u4e5f\u8868\u660eF\u586b\u5145\u53ef\u4ee5\u4fc3\u4f7fZnCo<sub>2<\/sub>O<sub>4<\/sub>\u6790\u6c27\u53cd\u5e94\u8def\u5f84\u4eceAEM\u5411LOM\u8f6c\u6362\uff0cF\u586b\u5145\u5f15\u8d77O-2p band\u53d1\u751f\u4e0a\u79fb\uff0c\u53d7\u5230\u6c27\u5316\u7684\u6676\u683c\u6c27\u4f1a\u53c2\u4e0e\u6c27\u6c14\u4ea7\u7269\u7684\u751f\u6210\u3002\u6b64\u5916\uff0cF\u79bb\u5b50\u7684\u5f3a\u7535\u8d1f\u6027\u53ef\u4ee5\u6709\u6548\u5e73\u8861\u53bb\u8d28\u5b50\u5316\u8fc7\u7a0b\uff0c\u63d0\u5347\u50ac\u5316\u5242\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u901a\u8fc7\u5bf9\u50ac\u5316\u5242\u7535\u5b50\u7ed3\u6784\u8c03\u63a7\u5b9e\u73b0\u4e86\u6790\u6c27\u53cd\u5e94\u8def\u5f84\u7684\u8c03\u63a7\uff0c\u4e3a\u8bbe\u8ba1\u9ad8\u6548\u6790\u6c27\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Activating Lattice Oxygen in Spinel ZnCo<sub>2<\/sub>O<sub>4<\/sub>\u00a0through Filling Oxygen Vacancies with Fluorine for Electrocatalytic Oxygen Evolution<\/p>\n<p>Kang Xiao,\u00a0Yifan Wang,\u00a0Peiyuan Wu,\u00a0Liping Hou,\u00a0Prof. Zhao-Qing Liu<\/p>\n<p>\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5e7f\u5dde\u5927\u5b66\u8096\u6297\u526f\u6559\u6388\u548c\u7855\u58eb\u7814\u7a76\u751f\u738b\u4f9d\u9492<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202301408<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6c34\u6c27\u5316\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u662f\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u3001\u7535\u89e3\u6c34\u5236\u6c22\u3001\u71c3\u6599\u7535\u6c60\u7b49\u65b0\u80fd\u6e90\u6280\u672f\u7684\u5173\u952e\u53cd\u5e94\u4e4b\u4e00\u3002\u5176\u7f13\u6162\u7684\u56db\u7535\u5b50-\u8d28\u5b50\u8f6c [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48158","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48158","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48158"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48158\/revisions"}],"predecessor-version":[{"id":48159,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48158\/revisions\/48159"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48158"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48158"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48158"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}