{"id":47982,"date":"2023-05-17T08:36:24","date_gmt":"2023-05-17T00:36:24","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47982"},"modified":"2023-05-02T08:37:32","modified_gmt":"2023-05-02T00:37:32","slug":"angew-chem-%ef%bc%9a%e5%85%89%e9%95%8d%e5%82%ac%e5%8c%96csp-csp3%e4%b8%8d%e5%af%b9%e7%a7%b0%e8%bf%98%e5%8e%9f%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94%e5%88%b6%e5%a4%87%e6%89%8b%e6%80%a7%ce%b1","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%85%89%e9%95%8d%e5%82%ac%e5%8c%96csp-csp3%e4%b8%8d%e5%af%b9%e7%a7%b0%e8%bf%98%e5%8e%9f%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94%e5%88%b6%e5%a4%87%e6%89%8b%e6%80%a7%ce%b1\/","title":{"rendered":"Angew. Chem. \uff1a\u5149\u954d\u50ac\u5316C(sp)-C(sp3)\u4e0d\u5bf9\u79f0\u8fd8\u539f\u5076\u8054\u53cd\u5e94\u5236\u5907\u624b\u6027\u03b1-\u7094\u57fa\u81a6\u9178\u916f\u5316\u5408\u7269"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u624b\u6027\u81a6\u5316\u5408\u7269\u5728\u5408\u6210\u5316\u5b66\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u5229\u7528\u5076\u8054\u7b56\u7565\u53ef\u4e3a\u5176\u5408\u6210\u63d0\u4f9b\u76f4\u63a5\u3001\u4fbf\u5229\u3001\u6a21\u5757\u5316\u7684\u65b9\u6cd5\u3002\u5c3d\u7ba1\u03b1-\u82b3\u57fa\u3001\u70ef\u57fa\u3001\u70f7\u57fa\u81a6\u5316\u5408\u7269\u90fd\u5df2\u7ecf\u6709\u4e86\u76f8\u5173\u62a5\u9053\uff0c\u4f46\u662f\u624b\u6027\u03b1-\u7094\u57fa\u81a6\u9178\u916f\u5c1a\u7f3a\u4e4f\u9ad8\u6548\u5408\u6210\u9014\u5f84\u3002\u5728\u524d\u671f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u540c\u6d4e\u5927\u5b66\u5f90\u6d9b\u8bfe\u9898\u7ec4\u53d1\u5c55\u4e86\u4e00\u79cd\u5149\u954d\u50ac\u5316\u5408\u6210\u624b\u6027\u03b1-\u7094\u57fa\u81a6\u9178\u916f\u7684\u65b0\u65b9\u6cd5\uff0c\u4e5f\u662f\u9996\u6b21\u5c06\u5149\u954d\u8fd8\u539f\u4e0d\u5bf9\u79f0\u5076\u8054\u4f53\u7cfb\u5e94\u7528\u4e8eC(sp)-C(sp<sup>3<\/sup>)\u6210\u952e\uff0c\u53cd\u5e94\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u666e\u9002\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230418\/1681784841149117.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u6eb4\u4ee3\u7094\u70c3\u5e95\u7269\u4ee5\u53ca\u03b1-\u6eb4\u4ee3\u78f7\u9178\u916f\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u53cd\u5e94\u5bf9\u4e8e\u5404\u79cd\u53d6\u4ee3\u7684\u7094\u70c3\uff0c\u4ee5\u53ca\u5404\u79cd\u7c7b\u578b\u7684\u03b1-\u6eb4\u81a6\u9178\u916f\u90fd\u80fd\u5f97\u5230\u9ad8\u7684\u6536\u7387\u548c\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230418\/1681784850450085.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u8bf4\u660e\u8be5\u65b9\u6cd5\u7684\u5e94\u7528\u6027\uff0c\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u4e86\u514b\u7ea7\u53cd\u5e94\uff0c\u540c\u65f6\u5bf9\u4ea7\u7269\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u7684\u8f6c\u5316\uff0c\u4ea7\u7269\u7684\u5bf9\u6620\u9009\u62e9\u6027\u80fd\u591f\u5f97\u5230\u8f83\u597d\u7684\u4fdd\u6301\u3002\u4e0d\u8fc7\u5728\u751f\u6210\u8054\u70ef\u7684\u53cd\u5e94\u4e2d\uff0c\u6ca1\u6709\u89c2\u6d4b\u5230\u624b\u6027\u4f20\u9012\u7684\u8fc7\u7a0b\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230418\/1681784859274494.png\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6700\u540e\u4f5c\u8005\u5bf9\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u7814\u7a76\uff0c\u8bc1\u5b9e\u4e86\u81ea\u7531\u57fa\u53cd\u5e94\u7684\u673a\u7406\uff0c\u540c\u65f6\u63d0\u51fa\u4e86\u4e00\u4e2a\u5408\u7406\u7684\u53cd\u5e94\u5faa\u73af\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230418\/1681784870204217.png\" alt=\"5\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u5f90\u6d9b\u8bfe\u9898\u7ec4\u5229\u7528\u5149\u954d\u4e0d\u5bf9\u79f0\u8fd8\u539f\u5076\u8054\u4f53\u7cfb\u6210\u529f\u5730\u5b9e\u73b0\u4e86\u03b1-\u6eb4\u4ee3\u78f7\u9178\u916f\u548c\u7094\u57fa\u6eb4\u5316\u7269\u7684\u624b\u6027\u5076\u8054\uff0c\u4e3a\u5408\u6210\u03b1-\u7094\u57fa\u78f7\u9178\u916f\u7c7b\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u4e00\u6761\u9ad8\u6548\u3001\u6a21\u5757\u5316\u7684\u5de5\u4f5c\u3002\u5229\u7528\u4f20\u7edf\u91d1\u5c5e\u8fd8\u539f\u5242\u5747\u4e0d\u80fd\u5f88\u597d\u5730\u5b9e\u73b0\u8be5\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u8fdb\u4e00\u6b65\u8bf4\u660e\u4e86\u8be5\u4f53\u7cfb\u5728\u8be5\u53cd\u5e94\u4e2d\u7684\u4f18\u52bf\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Enantioconvergent Reductive C(sp)\u2212C(sp<sup>3<\/sup>) Cross-Coupling to Access Chiral \u03b1-Alkynyl Phosphonates Under Dual Nickel\/Photoredox Catalysis<\/p>\n<p>Hepan Wang,\u00a0Xiaoqiang Wu,\u00a0Prof.\u2005Dr. Tao XU<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202218299<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u624b\u6027\u81a6\u5316\u5408\u7269\u5728\u5408\u6210\u5316\u5b66\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u5229\u7528\u5076\u8054\u7b56\u7565\u53ef\u4e3a\u5176\u5408\u6210\u63d0\u4f9b\u76f4\u63a5\u3001\u4fbf\u5229\u3001\u6a21\u5757\u5316\u7684\u65b9\u6cd5\u3002\u5c3d\u7ba1\u03b1-\u82b3\u57fa\u3001\u70ef\u57fa\u3001\u70f7 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47982","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47982","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47982"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47982\/revisions"}],"predecessor-version":[{"id":47983,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47982\/revisions\/47983"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47982"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47982"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47982"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}