{"id":47906,"date":"2023-05-10T08:11:36","date_gmt":"2023-05-10T00:11:36","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47906"},"modified":"2023-04-24T10:12:50","modified_gmt":"2023-04-24T02:12:50","slug":"angew-chem-%ef%bc%9a%e9%93%ac%e4%bb%8b%e5%af%bc%e7%9a%84%e8%8b%af%e7%8e%af12-%e8%bf%98%e5%8e%9f%e5%92%8c%e5%8c%ba%e5%9f%9f%e5%8f%91%e6%95%a3%e6%80%a7%e8%bf%98%e5%8e%9f%e6%b0%98%e5%8c%96%e5%8f%8d","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e9%93%ac%e4%bb%8b%e5%af%bc%e7%9a%84%e8%8b%af%e7%8e%af12-%e8%bf%98%e5%8e%9f%e5%92%8c%e5%8c%ba%e5%9f%9f%e5%8f%91%e6%95%a3%e6%80%a7%e8%bf%98%e5%8e%9f%e6%b0%98%e5%8c%96%e5%8f%8d\/","title":{"rendered":"Angew. Chem. \uff1a\u94ec\u4ecb\u5bfc\u7684\u82ef\u73af1,2-\u8fd8\u539f\u548c\u533a\u57df\u53d1\u6563\u6027\u8fd8\u539f\u6c18\u5316\u53cd\u5e94"},"content":{"rendered":"<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230411\/1681181404638205.png\" alt=\"1\" \/><\/section>\n<p>&nbsp;<\/p>\n<section>\n<section>\n<section>\n<section>\n<section>\u82b3\u70c3\u8fd8\u539f\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u6700\u91cd\u8981\u7684\u53cd\u5e94\u4e4b\u4e00\u3002\u76f8\u6bd4\u4e8e\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u7684\u82ef\u73af\u5168\u6c22\u5316\u8fd8\u539f\u548c1,4-\u8fd8\u539f\uff08Birch\u8fd8\u539f\uff09\uff0c\u82ef\u73af\u76841,2-\u8fd8\u539f\u53cd\u5e94\u5f88\u5c11\u88ab\u62a5\u9053\u3002\u5176\u4e2d\uff0c\u80fd\u8010\u53d7\u8fd8\u539f\u654f\u611f\u5b98\u80fd\u56e2\u7684\u5316\u5b66\u9009\u62e9\u6027\u7684\u82ef\u73af1,2-\u8fd8\u539f\u53cd\u5e94\u81f3\u4eca\u8fd8\u6ca1\u6709\u88ab\u7814\u7a76\u63a2\u8ba8\u8fc7\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u968f\u7740\u6c18\u4ee3\u53cd\u5e94\u5728\u836f\u7269\u5408\u6210\u4e2d\u7684\u6301\u7eed\u5e94\u7528\uff0c\u53d1\u5c55\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u7684\u8fd8\u539f\u6c18\u5316\u53cd\u5e94\u4e5f\u8d8a\u6765\u8d8a\u53d7\u5230\u79d1\u5b66\u5bb6\u4eec\u7684\u91cd\u89c6\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u674e\u4f1f\u8bfe\u9898\u7ec4\uff0c\u57fa\u4e8e\u94ec\u91d1\u5c5e\u03b7<sup>6<\/sup>-\u914d\u4f4d\u6d3b\u5316\u60f0\u6027\u82ef\u73af\u03c0\u952e\u7b56\u7565\uff0c\u4f7f\u7528\u5546\u4e1a\u6613\u5f97\u7684\u7845\u70f7\u8fd8\u539f\u5242\u548c\u4e09\u6c1f\u4e59\u9178\uff0c\u5b9e\u73b0\u4e86\u5316\u5b66\u9009\u62e9\u6027\u7684\u82b3\u70c31,2-\u8fd8\u539f\u53cd\u5e94, \u5373\u4f18\u5148\u8fd8\u539f\u672c\u6765\u60f0\u6027\u7684\u82ef\u73af\u03c0\u952e\uff0c\u540c\u65f6\u4fdd\u7559\u5404\u79cd\u8fd8\u539f\u654f\u611f\u5b98\u80fd\u56e2\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230411\/1681181412400444.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6b64\u5916\uff0c\u901a\u8fc7\u6539\u53d8\u76f8\u5e94\u7684\u6c18\u4ee3\/\u975e\u6c18\u4ee3\u7845\u70f7\u4e0e\u9178\u7684\u53cd\u5e94\u7ec4\u5408\uff0c\u8bfe\u9898\u7ec4\u8fdb\u4e00\u6b65\u53d1\u5c55\u4e86\u533a\u57df\u53d1\u6563\u6027\u7684\u82ef\u73af\u8fd8\u539f\u6c18\u5316\u53cd\u5e94\uff0c\u5373\u53ef\u4ee5\u7cbe\u786e\u5730\u63a7\u5236\u6c18\u4ee3\u7684\u4f4d\u7f6e\u548c\u6c18\u539f\u5b50\u5f15\u5165\u6570\u91cf\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230411\/1681181422848051.png\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u63a7\u5236\u5b9e\u9a8c\uff0c\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u6355\u6349\u548c\u8f6c\u5316\uff0c\u4ee5\u53ca\u5bf9\u53cd\u5f0f\u8fd8\u539f\u6c18\u4ee3\u4ea7\u7269\u7684\u7ed3\u6784\u9274\u5b9a\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u53ef\u80fd\u76841,2-\u53cd\u5f0f\u8fd8\u539f\u673a\u7406\u3002\u6700\u540e\uff0c\u4f5c\u8005\u5229\u7528\u8fd9\u79cd\u64cd\u4f5c\u7b80\u4fbf\u7684\u82b3\u70c31,2-\u8fd8\u539f\u53cd\u5e94\uff0c\u5feb\u901f\u5b8c\u6210\u4e86\u00a0(\u00b1)-\u52a0\u5170\u4ed6\u654f\uff08galanthamine\uff09\u548c (\u00b1)-\u529b\u53ef\u62c9\u654f\uff08lycoramine\uff09\u7684\u5f62\u5f0f\u5168\u5408\u6210\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230411\/1681181434794820.png\" alt=\"7\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8be5\u5de5\u4f5c\u4e3a\u89e3\u51b3\u82ef\u73af1,2-\u8fd8\u539f\u53cd\u5e94\u4e2d\u7684\u5316\u5b66\u9009\u62e9\u6027\u95ee\u9898\u548c\u533a\u57df\u9009\u62e9\u6027\u95ee\u9898\uff0c\u4ee5\u53ca\u82ef\u73af\u7684\u533a\u57df\u53d1\u6563\u6027\u8fd8\u539f\u6c18\u4ee3\u95ee\u9898\u63d0\u4f9b\u4e86\u7b80\u4fbf\u53ef\u884c\u65b9\u6848\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Chemoselective 1,2-Reduction and Regiodivergent Deuteration of Chromium-Bound Arenes<\/p>\n<p>Jia-Yi Qiu,\u00a0Wei-Long Zeng,\u00a0Hui Xie,\u00a0Ming-Yang Wang,\u00a0Prof.\u2005Dr. Wei Li<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202218961<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u82b3\u70c3\u8fd8\u539f\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u6700\u91cd\u8981\u7684\u53cd\u5e94\u4e4b\u4e00\u3002\u76f8\u6bd4\u4e8e\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u7684\u82ef\u73af\u5168\u6c22\u5316\u8fd8\u539f\u548c1,4-\u8fd8\u539f\uff08Bi [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47906","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47906","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47906"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47906\/revisions"}],"predecessor-version":[{"id":47907,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47906\/revisions\/47907"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47906"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47906"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47906"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}