{"id":47898,"date":"2023-05-09T08:23:41","date_gmt":"2023-05-09T00:23:41","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47898"},"modified":"2023-04-23T10:24:24","modified_gmt":"2023-04-23T02:24:24","slug":"chem-eur-j-%ef%bc%9a%e5%88%ba%e6%bf%80%e5%93%8d%e5%ba%94%e5%9e%8b%e5%a4%9a%e5%8a%9f%e8%83%bd%e6%b0%b4%e6%ba%b6%e6%80%a7%e9%87%91%e5%b1%9e%e5%8d%a1%e5%ae%be%e7%ac%bc","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/chem-eur-j-%ef%bc%9a%e5%88%ba%e6%bf%80%e5%93%8d%e5%ba%94%e5%9e%8b%e5%a4%9a%e5%8a%9f%e8%83%bd%e6%b0%b4%e6%ba%b6%e6%80%a7%e9%87%91%e5%b1%9e%e5%8d%a1%e5%ae%be%e7%ac%bc\/","title":{"rendered":"Chem. Eur. J.\uff1a\u523a\u6fc0\u54cd\u5e94\u578b\u591a\u529f\u80fd\u6c34\u6eb6\u6027\u91d1\u5c5e\u5361\u5bbe\u7b3c"},"content":{"rendered":"<p>\u897f\u5317\u5927\u5b66\u97e9\u82f1\u950b\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u7c7b\u65b0\u578b\u6c34\u6eb6\u6027\u91d1\u5c5e\u5361\u5bbe\u53d1\u5149\u6750\u6599\uff0c\u901a\u8fc7\u6eb6\u5242\u8c03\u63a7\u5b9e\u73b0\u4e86\u91d1\u5c5e\u5361\u5bbe\u7b3c\u7684\u7ed3\u6784\u8f6c\u5316\u3002\u8be5\u7c7b\u5316\u5408\u7269\u826f\u597d\u7684\u6eb6\u89e3\u5ea6\u53ca\u72ec\u7279\u7684\u53d1\u5149\u6027\u80fd\u4f7f\u5176\u53ef\u5e94\u7528\u4e8e\u6c28\u57fa\u9178\u4f20\u611f\u548c\u8367\u5149\u6210\u50cf\u7b49\u65b9\u9762\u3002<\/p>\n<p>\u5929\u7136\u751f\u7269\u5206\u5b50\u53ef\u4ee5\u901a\u8fc7\u9002\u5f53\u7684\u6539\u53d8\u5176\u5206\u5b50\u6784\u8c61\u4ece\u800c\u5bf9\u5916\u90e8\u6216\u5185\u90e8\u523a\u6fc0\u505a\u51fa\u53cd\u5e94\u3002\u529f\u80fd\u6027\u8d85\u5206\u5b50\u7ec4\u88c5\u4f53\u5177\u6709\u7c7b\u4f3c\u7684\u523a\u6fc0\u54cd\u5e94\u5355\u5143\uff0c\u8fd1\u5e74\u6765\u5e7f\u6cdb\u5e94\u7528\u4e8e\u836f\u7269\u4f20\u9012\u3001\u4f20\u611f\u5668\u3001\u5149\u5b66\u667a\u80fd\u6750\u6599\u7b49\u9886\u57df\u3002\u57fa\u4e8e\u91d1\u5c5e\u914d\u4f4d\u952e\u7684\u52a8\u6001\u53ef\u9006\u7279\u6027\uff0c\u91d1\u5c5e\u914d\u5408\u7269\u88ab\u5e94\u7528\u4e8e\u7814\u7a76\u7531\u591a\u79cd\u523a\u6fc0\u5f15\u53d1\u7684\u8d85\u5206\u5b50\u7ed3\u6784\u8f6c\u6362\u3002\u76f8\u6bd4\u4e8eWerner\u578b\u91d1\u5c5e\u4e2d\u5fc3\u914d\u4f4d\u7b3c\u7684\u7ed3\u6784\u8f6c\u6362\uff0c\u4f7f\u7528\u6eb6\u5242\uff0c\u5c24\u5176\u662f\u6c34\u89e6\u53d1\u6c2e\u6742\u73af\u5361\u5bbe\u6709\u673a\u91d1\u5c5e\u4f53\u7cfb\u7684\u7ed3\u6784\u8f6c\u6362\u9c9c\u6709\u62a5\u9053\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u97e9\u82f1\u950b\u8bfe\u9898\u7ec4\u5c06\u56db\u82ef\u4e59\u70ef\u4f5c\u4e3a\u57fa\u672c\u9aa8\u67b6\u4e0e\u6c2e\u6742\u73af\u5361\u5bbe\u5355\u5143\u76f8\u7ed3\u5408\uff0c\u5728\u8c03\u63a7\u6709\u673a\u91d1\u5c5e\u7ec4\u88c5\u4f53\u7684\u6784\u7b51\u53ca\u53d1\u5149\u65b9\u9762\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\u5e76\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u6210\u679c\uff08<em>Angew. Chem. Int. Ed<\/em>.\u00a0<strong>2020<\/strong>,\u00a0<em>59<\/em>, 10073\uff1b<em>CCS Chem.<\/em>\u00a0<strong>2022<\/strong>,\u00a0<em>4<\/em>, 732\u2212743\uff1b<em>Sci. China Chem<\/em>.\u00a0<strong>2021<\/strong>,\u00a0<em>64<\/em>, 1709\uff1b<em>\u00a0Chem. Eur. J.<\/em>\u00a0<strong>2019<\/strong>,\u00a0<em>25<\/em>, 9764\uff09\u3002<\/p>\n<p><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230410\/1681094888573000.png\" alt=\"1\" \/><\/p>\n<p>\u5728\u8be5\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u4ece\u78fa\u9178\u6839\u4fee\u9970\u7684\u56db-(1,2,4-\u4e09\u6c2e\u5511)\u56db\u82ef\u4e59\u70ef\u914d\u4f53\u51fa\u53d1\uff0c\u6784\u7b51\u4e86\u4e24\u79cd\u5177\u6709\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u7684\u91d1\u5c5e\u5361\u5bbe\u7b3c\u3002\u4e24\u79cd\u7ec4\u88c5\u4f53\u7684\u5f62\u6210\u53ef\u4ee5\u901a\u8fc7\u6eb6\u5242\u63a7\u5236\u5b9e\u73b0\uff1a\u4ee5\u6c34\u4f5c\u4e3a\u53cd\u5e94\u6eb6\u5242\u5f97\u5230\u6c34\u6eb6\u6027\u91d1\u5c5e\u5361\u5bbe\u7b3cAg<sub>8<\/sub>L<sub>4<\/sub>\uff0c\u5f53\u53cd\u5e94\u6eb6\u5242\u66f4\u6362\u4e3a\u7532\u9187\u65f6\u5219\u5f97\u5230\u56db\u6838\u91d1\u5c5e\u5361\u5bbe\u7b3cAg<sub>4<\/sub>L<sub>2<\/sub>\u3002\u76f8\u5bf9\u4e8e\u6c2e\u6742\u73af\u5361\u5bbe\u524d\u9a71\u4f53\uff0c\u5728\u91d1\u5c5e\u5316\u5f62\u6210\u6709\u673a\u91d1\u5c5e\u7ec4\u88c5\u4f53\u540e\u8367\u5149\u5f00\u542f\uff0c\u6c34\u6eb6\u6027\u91d1\u5c5e\u5361\u5bbe\u7b3cAg<sub>8<\/sub>L<sub>4<\/sub>\u7684\u6700\u5927\u53d1\u5c04\u6ce2\u957f\u4e3a456 nm\uff0c\u56db\u6838\u91d1\u5c5e\u5361\u5bbe\u7b3cAg<sub>4<\/sub>L<sub>2<\/sub>\u7684\u6700\u5927\u53d1\u5c04\u6ce2\u957f\u5219\u4e3a502 nm\u3002\u540c\u65f6\uff0c\u6eb6\u5242\u7684\u6539\u53d8\u53ef\u4ee5\u4fc3\u8fdb\u4e24\u7c7b\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u95f4\u7684\u8f6c\u53d8\uff0c\u5e76\u53ef\u4ee5\u901a\u8fc7\u8367\u5149\u5149\u8c31\u4ee5\u53ca\u91cf\u5b50\u4ea7\u7387\u7684\u53d8\u5316\u8ffd\u8e2a\u8d85\u5206\u5b50\u7ec4\u88c5\u4f53\u7ed3\u6784\u7684\u8f6c\u6362\u8fc7\u7a0b\u3002\u503c\u5f97\u63d0\u51fa\u7684\u662f\uff0c\u4e24\u79cd\u91d1\u5c5e\u5361\u5bbe\u7b3c\u901a\u8fc7\u6eb6\u5242\u8bf1\u5bfc\u53ef\u4ee5\u5b9e\u73b0\u53ef\u9006\u7ed3\u6784\u8f6c\u6362\u3002\u6b64\u5916\uff0c\u5177\u6709\u70ed\u54cd\u5e94\u7684\u91d1\u5c5e\u5361\u5bbe\u7b3cAg<sub>8<\/sub>L<sub>4<\/sub>\u56e0\u5176\u5728\u6c34\u4e2d\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u5ea6\u548c\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u88ab\u7528\u4f5c\u542b\u786b\u9187\u6c28\u57fa\u9178\u7684\u4f20\u611f\u3002\u540c\u65f6\uff0c\u91d1\u5c5e\u5361\u5bbe\u7b3cAg<sub>8<\/sub>L<sub>4<\/sub>\u5728\u4f53\u5916\u8868\u73b0\u51fa\u826f\u597d\u7684\u6297\u83cc\u548c\u6297\u764c\u6d3b\u6027\uff0c\u5e76\u5728\u4e9a\u7ec6\u80de\u6210\u50cf\u65b9\u9762\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n<p>\u8be5\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7\u6eb6\u5242\u6548\u5e94\u5b9e\u73b0\u4e86\u91d1\u5c5e\u5361\u5bbe\u7b3c\u7ed3\u6784\u7684\u52a8\u6001\u8f6c\u6362\uff0c\u521d\u6b65\u7814\u7a76\u4e86\u8be5\u7c7b\u6c34\u6eb6\u6027\u91d1\u5c5e\u5361\u5bbe\u7b3c\u5728\u751f\u7269\u4f20\u611f\u4e0e\u4e9a\u7ec6\u80de\u6210\u50cf\u65b9\u9762\u7684\u5e94\u7528\uff0c\u4e3a\u8fdb\u4e00\u6b65\u63a2\u7d22\u751f\u7269\u533b\u5b66\u8f6c\u6362\u7cfb\u7edf\u7684\u529f\u80fd\u6027\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u897f\u5317\u5927\u5b66\u97e9\u82f1\u950b\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u7c7b\u65b0\u578b\u6c34\u6eb6\u6027\u91d1\u5c5e\u5361\u5bbe\u53d1\u5149\u6750\u6599\uff0c\u901a\u8fc7\u6eb6\u5242\u8c03\u63a7\u5b9e\u73b0\u4e86\u91d1\u5c5e\u5361\u5bbe\u7b3c\u7684\u7ed3\u6784\u8f6c\u5316\u3002\u8be5\u7c7b\u5316\u5408\u7269\u826f [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47898","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47898","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47898"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47898\/revisions"}],"predecessor-version":[{"id":47899,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47898\/revisions\/47899"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47898"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47898"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47898"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}