{"id":47830,"date":"2023-05-01T08:39:34","date_gmt":"2023-05-01T00:39:34","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47830"},"modified":"2023-04-16T08:40:45","modified_gmt":"2023-04-16T00:40:45","slug":"ihpc-%e5%90%89%e5%a4%a7jacs%ef%bc%9atcda-cofs%e5%8a%a9%e5%8a%9b%e5%85%89%e5%82%ac%e5%8c%96her","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/ihpc-%e5%90%89%e5%a4%a7jacs%ef%bc%9atcda-cofs%e5%8a%a9%e5%8a%9b%e5%85%89%e5%82%ac%e5%8c%96her\/","title":{"rendered":"IHPC\/\u5409\u5927JACS\uff1aTCDA-COFs\u52a9\u529b\u5149\u50ac\u5316HER"},"content":{"rendered":"
\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff082D COFs\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u5149\u50ac\u5316\u5e73\u53f0\uff0c\u5728\u592a\u9633\u80fd\u5236\u6c22\u8fc7\u7a0b\u4e2d\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\uff0c\u4f46\u5b83\u4eec\u4f4e\u6548\u7684\u592a\u9633\u80fd\u6355\u83b7\u548c\u5feb\u901f\u7684\u7535\u8377\u91cd\u7ec4\u963b\u788d\u4e86\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd\u7684\u63d0\u9ad8\u3002<\/section>\n

 <\/p>\n

\u57fa\u4e8e\u6b64\uff0c\u5409\u6797\u5927\u5b66\u5218\u6653\u660e\u6559\u6388\u548c\u590f\u8679\u6559\u6388\u3001\u65b0\u52a0\u5761\u9ad8\u6027\u80fd\u8ba1\u7b97\u7814\u7a76\u6240Gang Wu\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u591a\u7ec4\u5206\u5408\u6210\u7b56\u7565\uff0c\u5206\u522b\u901a\u8fc7sp2<\/sup>-\u78b3\u952e\u548c\u4e9a\u80fa\u952e\u5c06\u7f3a\u7535\u5b50\u7684\u4e09\u55ea\u548c\u5bcc\u7535\u5b50\u7684\u82ef\u5e76\u4e09\u567b\u5429\u57fa\u56e2\u5f15\u5165\u6846\u67b6\uff0c\u6784\u5efa\u4e86\u4e24\u79cd\u5149\u6d3b\u6027\u4e09\u7ec4\u5206\u4f9b\u4f53-\u03c0-\u53d7\u4f53\uff08TCDA\uff09\u6750\u6599\u3002\u5bf9\u6bd4\u53cc\u7ec4\u5206COFs\uff0c\u65b0\u578bTCDA-COFs\u5728\u53ef\u89c1\u5149\u7167\u660e\uff08420-780 nm\uff09\u4e0b\uff0c\u57281 wt % Pt\u7684\u5b58\u5728\u4e0b\uff0c\u5176\u6790\u6c22\u901f\u7387\u8fbe\u5230\u4e8670.8\u00b11.9 mmol g-1<\/sup>\u00a0h-1<\/sup>\uff0c\u5177\u6709\u826f\u597d\u7684\u53ef\u91cd\u7528\u6027\u3002<\/section>\n
\"1\"<\/section>\n
\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u4f5c\u8005\u7814\u7a76\u4e86\u7ec4\u6210\u3001\u8fde\u63a5\u548c\u5149\u50ac\u5316\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u5bf9\u6bd4sp2<\/sup>\u00a0c-COF\u7b49\u53cc\u7ec4\u4efdCOFs\u4e2d\u53ef\u4ee5\u53d1\u73b0HOMO\u548cLUMO\u4e4b\u95f4\u7684\u7a7a\u95f4\u5206\u79bb\uff0c\u8fd9\u79cd\u5206\u79bb\u5728\u4e09\u7ec4\u5206COF-JLUs\u4e2d\u7531\u4e8e\u5176\u957f\u6865\u63a5PDA\u548cPDAN\u5355\u5143\u800c\u66f4\u52a0\u7a81\u51fa\u3002<\/section>\n
\u540cBader\u7535\u8377\u5206\u6790\u8868\u660e\uff0c\u53d7\u4f53TFPT\u4e0a\u7684\u7535\u5b50\u4f20\u9012\u901a\u9053\u603b\u4f53\u4e0a\u5e26\u6b63\u7535\u8377\uff0cCOF-JLU35\u548cCOF-JLU36\u7684\u51c0\u7535\u8377\u5206\u522b\u4e3a+0.33\u548c+0.14\u3002\u5728\u6fc0\u5b50\u89e3\u79bb\u540e\uff0c\u7535\u5b50\u548c\u53d7\u4f53\u590d\u5408\u7269\u4e4b\u95f4\u7684\u5f3a\u5f15\u529b\u5bfc\u81f4\u66f4\u5feb\u7684\u7535\u5b50\u7a7a\u7a74\u5206\u79bb\u3002<\/section>\n
\"2\"<\/section>\n
\u6b64\u5916\uff0c\u9ad8\u6548\u7684\u03c0\u5171\u8f6d\u5141\u8bb8\u76f8\u90bb\u5806\u53e0\u5c42\u4e4b\u95f4\u66f4\u597d\u7684\u8f68\u9053\u91cd\u53e0\uff0c\u8fdb\u4e00\u6b65\u7a33\u5b9a\u4e86\u7535\u8377\u5206\u79bbCOF-JLU35\u548cCOF-JLU36\u7684\u5c42\u95f4\u5806\u79ef\uff0c\u5bfc\u81f4\u4e86\u660e\u663e\u7684\u7535\u5b50\u79bb\u57df\uff0c\u5176\u4ef7\u5e26\u5bbd\u5ea6\u548c\u5bfc\u5e26\u5bbd\u5ea6W\u5747\u57281 eV\u5de6\u53f3\uff0c\u8fdc\u8fdc\u5927\u4e8esp2<\/sup>\u00a0c-COF\u3002<\/section>\n
\u5728COF-JLU35\u548cCOF-JLU36\u4e2d\uff0c\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u8de8\u5e73\u9762\u6709\u6548\u8d28\u91cf\u4e0e\u81ea\u7531\u7535\u5b50\u63a5\u8fd1\uff0c\u8fdc\u5c0f\u4e8e\u5e73\u9762\u5185\u8d28\u91cf\uff0c\u8fd9\u79cd\u5404\u5411\u5f02\u6027\u4f7f\u7535\u5b50\u548c\u7a7a\u7a74\u5728\u5206\u79bb\u7684\u901a\u9053\u4e2d\u5e73\u884c\u4f20\u8f93\u3002<\/section>\n
\u56e0\u6b64\uff0c\u7406\u8bba\u7814\u7a76\u7ed3\u679c\u8868\u660e\u4e24\u79cdTCDA-COFs\u90fd\u5177\u6709\u826f\u597d\u7684\u5149\u50ac\u5316\u6027\u80fd\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u9ad8\u6548\u7684\u7535\u8377\u5206\u79bb\u548c\u4f20\u8f93\u7684\u6f5c\u529b\u3002<\/section>\n
\"9\"<\/section>\n
Three-Component Donor-\u03c0-Acceptor Covalent-Organic Frameworks for Boosting Photocatalytic Hydrogen Evolution.\u00a0J. Am. Chem. Soc.,\u00a0<\/em>2023<\/strong>, DOI: 10.1021\/jacs.2c11893.<\/section>\n
https:\/\/doi.org\/10.1021\/jacs.2c11893.<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff082D COFs\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u5149\u50ac\u5316\u5e73\u53f0\uff0c\u5728\u592a\u9633\u80fd\u5236\u6c22\u8fc7\u7a0b\u4e2d\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\uff0c\u4f46\u5b83\u4eec\u4f4e\u6548\u7684\u592a […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47830","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47830","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47830"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47830\/revisions"}],"predecessor-version":[{"id":47831,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47830\/revisions\/47831"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47830"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47830"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47830"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}