{"id":47760,"date":"2023-04-23T08:20:48","date_gmt":"2023-04-23T00:20:48","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47760"},"modified":"2023-04-08T08:21:58","modified_gmt":"2023-04-08T00:21:58","slug":"angew-chem-%ef%bc%9a%e9%80%9a%e8%bf%87%e5%85%b1%e4%bb%b7%e5%90%8e%e5%90%88%e6%88%90%e4%bf%ae%e9%a5%b0%e5%ae%9a%e5%88%b6%e5%8a%9f%e8%83%bd%e5%8c%96pdnl2n%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e7%ac%bc","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e9%80%9a%e8%bf%87%e5%85%b1%e4%bb%b7%e5%90%8e%e5%90%88%e6%88%90%e4%bf%ae%e9%a5%b0%e5%ae%9a%e5%88%b6%e5%8a%9f%e8%83%bd%e5%8c%96pdnl2n%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e7%ac%bc\/","title":{"rendered":"Angew. Chem. \uff1a\u901a\u8fc7\u5171\u4ef7\u540e\u5408\u6210\u4fee\u9970\u5b9a\u5236\u529f\u80fd\u5316PdnL2n\u91d1\u5c5e\u6709\u673a\u7b3c"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u91d1\u5c5e\u6709\u673a\u7b3c\uff08\u4e5f\u79f0\u4e3a\u914d\u4f4d\u7b3c\uff09\uff0c\u56e0\u5176\u5177\u6709\u53ef\u8c03\u8282\u7684\u51e0\u4f55\u5f62\u72b6\u3001\u5c3a\u5bf8\u4ee5\u53ca\u9650\u57df\u7a7a\u8154\u7b49\u7279\u70b9\uff0c\u4f7f\u8fd9\u7c7b\u8d85\u5206\u5b50\u6750\u6599\u5728\u50ac\u5316\u3001\u5206\u5b50\u8bc6\u522b\u3001\u836f\u7269\u8f93\u9001\u548c\u751f\u7269\u533b\u5b66\u7b49\u9886\u57df\u5177\u6709\u6f5c\u5728\u5e94\u7528\u3002\u529f\u80fd\u5316\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u6784\u7b51\u901a\u5e38\u9700\u8981\u9884\u5148\u5408\u6210\u63a5\u679d\u6709\u7279\u5b9a\u5b98\u80fd\u56e2\u7684\u6709\u673a\u914d\u4f53\uff0c\u8fd9\u5f80\u5f80\u9700\u8981\u5728\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u8fdb\u884c\u590d\u6742\u7e41\u7410\u7684\u6709\u673a\u5408\u6210\u64cd\u4f5c\uff0c\u6781\u5927\u5730\u9650\u5236\u4e86\u6784\u5efa\u6b64\u7c7b\u591a\u529f\u80fd\u8d85\u5206\u5b50\u6750\u6599\u7684\u5408\u6210\u6548\u7387\u4ee5\u53ca\u591a\u6837\u6027\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u79cd\u80fd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u9ad8\u6548\u4e14\u53ef\u4ee5\u5b9a\u5236\u529f\u80fd\u5316\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u7b56\u7565\u975e\u5e38\u91cd\u8981\u3002\u5408\u6210\u540e\u4fee\u9970\u662f\u4e00\u79cd\u83b7\u53d6\u5b9a\u5236\u529f\u80fd\u5316\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u6709\u6548\u7b56\u7565\uff0c\u4f46\u53d1\u5c55\u5177\u6709\u901a\u7528\u4e14\u9ad8\u6548\u7684\u65b9\u6cd5\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u66a8\u5357\u5927\u5b66\u5468\u5c0f\u5e73\u6559\u6388\u56e2\u961f\u53d1\u5c55\u4e86\u4e00\u79cd\u901a\u8fc7\u5916\u56f4\u84bd\u53d6\u4ee3\u57fa\u4e0e\u5e26\u6709\u9a6c\u6765\u9170\u4e9a\u80fa\u57fa\u56e2\u7684\u5404\u79cd\u529f\u80fd\u5206\u5b50\u4e4b\u95f4\u7684\u9ad8\u6548 Diels-Alder \u73af\u52a0\u6210\u53cd\u5e94\uff0c\u5bf9Pd<sub>n<\/sub>L<sub>2n<\/sub>\uff08n = 12\uff0c2\uff09\u578b\u91d1\u5c5e\u6709\u673a\u7b3c\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u540e\u5408\u6210\u4fee\u9970\u7814\u7a76\uff0c\u5e76\u4f7f\u5176\u83b7\u5f97\u591a\u79cd\u4e0d\u540c\u7684\u6027\u8d28\u548c\u529f\u80fd\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230328\/1679986554722397.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u9996\u5148\u901a\u8fc7\u914d\u4f4d\u9a71\u52a8\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6210\u529f\u6784\u7b51\u4e86\u542b\u6709\u53cd\u5e94\u6d3b\u6027\u84bd\u57fa\u56e2\u7684 Pd<sub>12<\/sub>L<sub>24<\/sub>\u578b\u91d1\u5c5e\u6709\u673a\u7b3c\u3002\u7136\u540e\u5229\u7528\u84bd\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\u57fa\u56e2\u53ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u901a\u8fc7[4+2] Diels-Alder\u73af\u52a0\u6210\u53cd\u5e94\u7684\u7279\u70b9\uff0c\u53ef\u5728\u8be5\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u5916\u56f4\u6709\u6548\u63a5\u679d\u591a\u79cd\u529f\u80fd\u57fa\u56e2\uff08\u4f8b\u5982BINOL\u57fa\u56e2\u3001\u56db\u82ef\u57fa\u4e59\u70ef\u57fa\u3001\u8298\u57fa\u7b49)\uff0c\u5e76\u4e14\u5177\u6709\u76f8\u5f53\u9ad8\u7684\u4ea7\u7387\uff08&gt; 90%\uff09\u3002\u5bf9\u4e8e\u540e\u5408\u6210\u4fee\u9970\u6240\u5f97\u5230\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\uff0c\u5176\u7269\u7406\u5316\u5b66\u6027\u8d28\u6216\u529f\u80fd\u5f97\u5230\u660e\u663e\u7684\u6539\u53d8\u3002\u5176\u4e2d\uff0cBINOL\u4fee\u9970\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u83b7\u5f97\u4e86\u624b\u6027\u6027\u8d28\uff0c\u5e76\u4e14\u5728\u7a00\u6eb6\u6db2\u4e2d\u4f1a\u901a\u8fc7\u805a\u96c6\u800c\u5c55\u73b0\u51fa\u4e0d\u5bfb\u5e38\u7684\u6d53\u5ea6\u4f9d\u8d56\u6027\u5706\u4e8c\u8272\u6027\uff1b\u56db\u82ef\u57fa\u4e59\u70ef\u57fa\u4fee\u9970\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u5219\u83b7\u5f97\u4e86\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u529f\u80fd\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230328\/1679986563509749.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e4b\u540e\uff0c\u4f5c\u8005\u901a\u8fc7\u5206\u6b65\u540e\u5408\u6210\u4fee\u9970\u65b9\u6cd5\uff0c\u5c06\u4e24\u79cd\u5177\u6709\u4e0d\u540c\u5149\u529f\u80fd\u7684\u57fa\u56e2\u540c\u65f6\u5f15\u5165\u5230\u540c\u4e00\u4e2a\u91d1\u5c5e\u6709\u673a\u7b3c\u4e2d\uff0c\u4f8b\u5982\u4fee\u9970\u624b\u6027BINOL\u57fa\u56e2\u548c\u975e\u624b\u6027\u8298\u53d1\u5149\u57fa\u56e2\u3002\u540e\u5408\u6210\u4fee\u9970\u6240\u5f97\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u53ef\u4ee5\u901a\u8fc7\u5206\u5b50\u5185\u624b\u6027\u8bf1\u5bfc\u9014\u5f84\u5b9e\u73b0\u57fa\u4e8e\u975e\u624b\u6027\u8298\u53d1\u8272\u56e2\u7684\u5706\u504f\u632f\u53d1\u5149\u7279\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"9\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230328\/1679986585591632.png\" alt=\"9\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6b64\u5916\uff0c\u4ee5\u4e0a\u6709\u6548\u7684\u540e\u5408\u6210\u4fee\u9970\u65b9\u6cd5\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u6269\u5c55\u5230 Pd<sub>2<\/sub>L<sub>4<\/sub>\u578b\u91d1\u5c5e\u6709\u673a\u7b3c\u4f53\u7cfb\u4e2d\uff0c\u5e76\u4e14\u53ef\u4ee5\u83b7\u5f97\u63a5\u8fd1\u4e8e\u5b9a\u91cf\u4ea7\u7387\u7684\u529f\u80fd\u5316\u4ea7\u7269\u3002\u8be5\u9879\u5de5\u4f5c\u5c55\u793a\u4e86\u901a\u8fc7Diels-Alder\u73af\u52a0\u6210\u53cd\u5e94\u53ef\u4ee5\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u5b9e\u73b0\u7ed3\u6784\u590d\u6742\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u5b9a\u5236\u529f\u80fd\u5316\uff0c\u8fd9\u4e3a\u8bbe\u8ba1\u548c\u5408\u6210\u57fa\u4e8e\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u5148\u8fdb\u6750\u6599\u63d0\u4f9b\u4e86\u91cd\u8981\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Tailor-Made Pd<sub>n<\/sub>L<sub>2n<\/sub>\u00a0Metal-Organic Cages through Covalent Post-Synthetic Modification<\/p>\n<p>Dr. Dong Luo,\u00a0Zi-Jun Yuan,\u00a0Lin-Jie Ping,\u00a0Dr. Xiao-Wei Zhu,\u00a0Dr. Ji Zheng,\u00a0Chuang-Wei Zhou,\u00a0Xian-Chao Zhou,\u00a0Prof.\u2005Dr. Xiao-Ping Zhou,\u00a0Prof.\u2005Dr. Dan Li<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202216977<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u91d1\u5c5e\u6709\u673a\u7b3c\uff08\u4e5f\u79f0\u4e3a\u914d\u4f4d\u7b3c\uff09\uff0c\u56e0\u5176\u5177\u6709\u53ef\u8c03\u8282\u7684\u51e0\u4f55\u5f62\u72b6\u3001\u5c3a\u5bf8\u4ee5\u53ca\u9650\u57df\u7a7a\u8154\u7b49\u7279\u70b9\uff0c\u4f7f\u8fd9\u7c7b\u8d85\u5206\u5b50\u6750\u6599\u5728\u50ac\u5316\u3001\u5206\u5b50\u8bc6\u522b [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47760","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47760","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47760"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47760\/revisions"}],"predecessor-version":[{"id":47761,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47760\/revisions\/47761"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47760"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47760"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47760"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}