{"id":47652,"date":"2023-04-10T08:41:09","date_gmt":"2023-04-10T00:41:09","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47652"},"modified":"2023-03-26T08:42:33","modified_gmt":"2023-03-26T00:42:33","slug":"angew-chem-%ef%bc%9a%e5%bc%ba%e7%a3%81%e8%80%a6%e5%90%88%e7%a8%80%e5%9c%9f%e7%b0%87%e5%8d%95%e5%88%86%e5%ad%90%e7%a3%81%e4%bd%93%e7%9a%84%e6%96%b0%e5%9e%8b%e6%9e%84%e7%ad%91%e7%ad%96%e7%95%a5","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%bc%ba%e7%a3%81%e8%80%a6%e5%90%88%e7%a8%80%e5%9c%9f%e7%b0%87%e5%8d%95%e5%88%86%e5%ad%90%e7%a3%81%e4%bd%93%e7%9a%84%e6%96%b0%e5%9e%8b%e6%9e%84%e7%ad%91%e7%ad%96%e7%95%a5\/","title":{"rendered":"Angew. Chem. \uff1a\u5f3a\u78c1\u8026\u5408\u7a00\u571f\u7c07\u5355\u5206\u5b50\u78c1\u4f53\u7684\u65b0\u578b\u6784\u7b51\u7b56\u7565"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u533a\u522b\u4e8e\u4f20\u7edf\u78c1\u4f53\u7684\u957f\u7a0b\u78c1\u6709\u5e8f\u884c\u4e3a\uff0c\u5355\u5206\u5b50\u78c1\u4f53\uff08Single-molecule magnet, SMM\uff09\u662f\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u8bbe\u8ba1\u5f00\u53d1\u7684\u4e00\u7c7b\u5177\u6709\u78c1\u53cc\u7a33\u6001\u7684\u78c1\u6027\u5206\u5b50\u3002\u56e0\u5176\u5355\u4e2a\u5206\u5b50\u5728\u4e00\u5b9a\u6e29\u5ea6\uff08TB\uff09\u4e0b\u5c31\u80fd\u8868\u73b0\u51fa\u7c7b\u4f3c\u4f20\u7edf\u78c1\u4f53\u7684\u78c1\u5b66\u884c\u4e3a\uff0c\u4ece\u800c\u67b6\u8d77\u4e86\u5fae\u89c2\u81ea\u65cb\u4e0e\u5b8f\u89c2\u78c1\u4f53\u7684\u6865\u6881\uff0c\u5df2\u6210\u4e3a\u5316\u5b66\u3001\u7269\u7406\u548c\u6750\u6599\u7b49\u591a\u5b66\u79d1\u7684\u4ea4\u53c9\u7814\u7a76\u70ed\u70b9\u3002\u53e6\u5916\uff0c\u76ee\u524d\u78c1\u6027\u6750\u6599\u4f9d\u7136\u662f\u6700\u91cd\u8981\u7684\u4fe1\u606f\u5b58\u50a8\u4ecb\u8d28\uff0c\u4f46\u7531\u4e8e\u91cf\u5b50\u5c3a\u5bf8\u6548\u5e94\uff0c\u73b0\u5b58\u7684\u78c1\u5b58\u50a8\u8bbe\u5907\u5df2\u63a5\u8fd1\u5b58\u50a8\u5bc6\u5ea6\u6781\u9650\uff0c\u800c\u5206\u5b50\u5c3a\u5ea6\u7684\u5355\u5206\u5b50\u78c1\u4f53\u5728\u9ad8\u5bc6\u5ea6\u4fe1\u606f\u5b58\u50a8\u4e2d\u6709\u7740\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\u3002\u5f53\u524d\uff0c\u6b64\u7c7b\u6750\u6599\u7684\u78c1\u4f53\u6027\u8d28\u53ea\u6709\u5728\u4f4e\u6e29\u4e0b\u8868\u73b0\u51fa\u6765\uff08TB\u4f4e\uff09\uff0c\u4e25\u91cd\u5236\u7ea6\u4e86\u5176\u5411\u5e94\u7528\u53d1\u5c55\u3002<\/p>\n<p>\u9274\u4e8e\u91cd\u7a00\u571f\u5316\u5408\u7269\u5177\u6709\u6781\u5927\u7684\u78c1\u77e9\u548c\u78c1\u5404\u5411\u5f02\u6027\uff0c\u7a00\u571f\u5355\u5206\u5b50\u78c1\u4f53\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u5e0c\u671b\u5b9e\u73b0\u78c1\u4f53\u6027\u80fd\u7a81\u7834\u7684\u5173\u952e\u5206\u5b50\u78c1\u6027\u6750\u6599\u3002\u5176\u4e2d\uff0c\u5f3a\u8026\u5408\u591a\u6838\u7a00\u571f\u5355\u5206\u5b50\u78c1\u4f53\u8868\u73b0\u51fa\u4f18\u79c0\u7684\u78c1\u5b66\u6027\u80fd\uff0c\u5df2\u53d1\u5c55\u4e3a\u4e00\u4e2a\u524d\u6cbf\u7814\u7a76\u70ed\u70b9\u3002\u8003\u8651\u5230\u7a00\u571f\u79bb\u5b50\u51854f\u8f68\u9053\u53d7\u5230\u5916\u7535\u5b50\u5c42\u5c4f\u853d\uff0c\u8981\u5b9e\u73b0\u7a00\u571f\u79bb\u5b50\u4e4b\u95f4\u7684\u5f3a\u5173\u8054\u6027\u5177\u6709\u6781\u5927\u7684\u6311\u6218\u6027\u3002\u76ee\u524d\u8f83\u4e3a\u6210\u529f\u7684\u7b56\u7565\u662f\u901a\u8fc7\u81ea\u7531\u57fa\u6216\u91cd\u4e3b\u65cf\u79bb\u5b50\u6865\u8054\u7a00\u571f\u4e2d\u5fc3\uff0c\u6216\u662f\u76f4\u63a5\u5b9e\u73b0\u7a00\u571f\u79bb\u5b50\u4e4b\u95f4\u7684\u91d1\u5c5e-\u91d1\u5c5e\u6210\u952e\u3002\u4f46\u662f\uff0c\u6b64\u7c7b\u4f53\u7cfb\u591a\u96c6\u4e2d\u4e8e\u53cc\u91d1\u5c5e\u4e2d\u5fc3\u7684\u7a00\u571f\u5355\u5206\u5b50\u78c1\u4f53\uff0c\u800c\u66f4\u591a\u7a00\u571f\u91d1\u5c5e\u4e2d\u5fc3\u7684\u5f3a\u78c1\u8026\u5408\u4f53\u7cfb\u5219\u975e\u5e38\u7f55\u89c1\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u9655\u897f\u5e08\u8303\u5927\u5b66\u5f20\u9e4f\u526f\u6559\u6388\u53ca\u5408\u4f5c\u8005\uff0c\u5728\u81ea\u7531\u57fa\u6865\u8054\u7a00\u571f\u5355\u5206\u5b50\u78c1\u4f53\u4f53\u7cfb\u4e2d\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\uff0c\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u5bf9\u81ea\u7531\u57fa\u6865\u8054\u914d\u4f53\u7684\u9884\u7ec4\u88c5\u4f5c\u7528\uff0c\u5b9e\u73b0\u4e86\u5bf9\u56db\u4e2a\u7a00\u571f\u91d1\u5c5e\u4e2d\u5fc3\u8fdb\u884c\u5f3a\u78c1\u8026\u8054\u7684\u76ee\u7684\uff0c\u8fd9\u662f\u76ee\u524d\u542b\u6700\u591a\u91d1\u5c5e\u4e2d\u5fc3\u7684\u5f3a\u78c1\u8026\u5408\u7a00\u571f\u5355\u5206\u5b50\u78c1\u4f53\uff081-Ln\uff09\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"0\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230316\/1678934307656606.png\" alt=\"0\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u540c\u65f6\uff0c\u7531\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u53ca\u591a\u4e2a\u81ea\u7531\u57fa\u914d\u4f53\u7684\u5f15\u5165\uff0c\u6b64\u4f53\u7cfb\u5448\u73b0\u4e86\u826f\u597d\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\uff0c\u8fdb\u4e00\u6b65\u901a\u8fc7\u5316\u5b66\u8fd8\u539f\u65b9\u6cd5\u5bf91-Ln\u7684\u5355\u7535\u5b50\u8fd8\u539f\u4ea7\u7269\uff082-Ln\uff09\u8fdb\u884c\u4e86\u5206\u79bb\u63d0\u7eaf\uff0c\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u63ed\u793a\u4e86\u5176\u5177\u6709\u7c7b\u4f3c1-Ln\u7684\u5206\u5b50\u7ed3\u6784\uff0c\u800c\u5149\u8c31\u53ca\u78c1\u5b66\u8868\u5f81\u8868\u660e\u57282-Ln\u4e2d\u4e24\u4e2a\u6865\u8054\u914d\u4f53\u5177\u6709\u4e0d\u540c\u5316\u5408\u4ef7\uff0c\u800c\u8fd9\u79cd\u6df7\u5408\u4ef7\u914d\u4f53\u81f4\u4f7f2-Ln\u5177\u6709\u66f4\u597d\u7684\u78c1\u4f53\u6027\u8d28\u3002<\/p>\n<p>\u6700\u7ec8\uff0c\u5c3d\u7ba1\u6b64\u7c7b\u7a00\u571f\u5355\u5206\u5b50\u78c1\u4f53\u7684\u78c1\u5b66\u6027\u80fd\u6709\u5f85\u63d0\u9ad8\uff0c\u4f46\u8be5\u5de5\u4f5c\u4e3a\u5f3a\u78c1\u8026\u5408\u7a00\u571f\u7c07\u5355\u5206\u5b50\u78c1\u4f53\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u72ec\u5230\u7684\u6784\u7b51\u7b56\u7565\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Radical-Bridged Heterometallic Single-Molecule Magnets Incorporating Four Lanthanoceniums<\/p>\n<p>Dr. Peng Zhang,\u00a0Qian-Cheng Luo,\u00a0Dr. Zhenhua Zhu,\u00a0Wanrong He,\u00a0Nan Song,\u00a0Junting Lv,\u00a0Xuning Wang,\u00a0Prof. Quan-Guo Zhai,\u00a0Prof. Yan-Zhen Zheng,\u00a0Prof. Jinkui Tang<\/p>\n<p>\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u9655\u897f\u5e08\u8303\u5927\u5b66\u7684\u5f20\u9e4f\u526f\u6559\u6388\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202218540<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u533a\u522b\u4e8e\u4f20\u7edf\u78c1\u4f53\u7684\u957f\u7a0b\u78c1\u6709\u5e8f\u884c\u4e3a\uff0c\u5355\u5206\u5b50\u78c1\u4f53\uff08Single-molecule magnet, SMM\uff09\u662f\u5728\u5206\u5b50\u6c34 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47652","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47652","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47652"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47652\/revisions"}],"predecessor-version":[{"id":47653,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47652\/revisions\/47653"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47652"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47652"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47652"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}