{"id":47586,"date":"2023-04-02T09:00:03","date_gmt":"2023-04-02T01:00:03","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47586"},"modified":"2023-03-18T09:01:47","modified_gmt":"2023-03-18T01:01:47","slug":"%e6%bd%98%e9%94%8b-%e6%9d%8e%e8%88%9c%e5%ae%81acs-catalysis%ef%bc%9ani2p%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%a4%9a%e4%b8%ad%e5%bf%83%e5%8d%8f%e5%90%8c%e4%bd%9c%e7%94%a8%e7%94%a8%e4%ba%8e%e5%a2%9e","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e6%bd%98%e9%94%8b-%e6%9d%8e%e8%88%9c%e5%ae%81acs-catalysis%ef%bc%9ani2p%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%a4%9a%e4%b8%ad%e5%bf%83%e5%8d%8f%e5%90%8c%e4%bd%9c%e7%94%a8%e7%94%a8%e4%ba%8e%e5%a2%9e\/","title":{"rendered":"\u6f58\u950b\/\u674e\u821c\u5b81ACS Catalysis\uff1aNi2P\u50ac\u5316\u5242\u7684\u591a\u4e2d\u5fc3\u534f\u540c\u4f5c\u7528\u7528\u4e8e\u589e\u5f3a\u7535\u5316\u5b66CO2\u8fd8\u539f\u4e2d\u7684C-C\u5076\u8054"},"content":{"rendered":"

\u8fd1\u5e74\u6765\u4eba\u4eec\u5bf9\u53ef\u518d\u751f\u7535\u529b\u9a71\u52a8\u7684\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u7535\u8fd8\u539f\u7684\u5174\u8da3\u4e0e\u65e5\u4ff1\u589e\uff0c\u8fd9\u5c31\u8981\u6c42\u5728\u50ac\u5316\u5242\u8bbe\u8ba1\u4e2d\u91c7\u53d6\u6709\u6548\u7684\u7b56\u7565\u3002<\/p>\n

\u57fa\u4e8e\u6b64\uff0c\u5317\u4eac\u5927\u5b66\u6f58\u950b\u6559\u6388\uff0c\u674e\u821c\u5b81\u526f\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u5bf9\u5177\u6709\u4ee3\u8868\u6027\u7684Ni2<\/sub>P\u7535\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u7b2c\u4e00\u6027\u539f\u7406\u7814\u7a76\uff0c\u8be5\u50ac\u5316\u5242\u5177\u6709\u5bc6\u96c6\u5206\u5e03\u7684Ni3<\/sub>\u50ac\u5316\u4e2d\u5fc3\uff0c\u5728CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\uff08CO2<\/sub>RR\uff09\u4e2d\u8868\u73b0\u51fa\u8f83\u9ad8\u7684C-C\u5076\u8054\u9009\u62e9\u6027\u3002<\/p>\n

\"1\"<\/p>\n

DFT\u8ba1\u7b97\u8868\u660e\uff0c\u4e0d\u4ec5\u6bcf\u4e2aNi3<\/sub>\u4f4d\u70b9\u4e2d\u7684Ni\u539f\u5b50\u53ef\u4ee5\u534f\u540c\u5bb9\u7eb3\u53cd\u5e94\u4e2d\u95f4\u4f53\u4ee5\u83b7\u5f97\u66f4\u597d\u7684\u5076\u8054\u673a\u4f1a\uff0c\u800c\u4e14\u76f8\u90bb\u7684Ni3<\/sub>\u4f4d\u70b9\u4e5f\u53ef\u4ee5\u534f\u540c\u9a71\u52a8\u9ad8\u5438\u70ed\u6c22\u5316\u6b65\u9aa4\u5f62\u6210\u5173\u952e\u7684\u591a\u78b3\u7269\u79cd\u3002<\/p>\n

\u8fd9\u79cd\u80fd\u529b\u7684\u6838\u5fc3\u5728\u4e8e\u6c34\u7684\u6c22\u952e\u7f51\u7edc\u53c2\u4e0e\u5728\u76f8\u90bbNi3<\/sub>\u4f4d\u70b9\u4e4b\u95f4\u8f6c\u79fb\u8868\u9762\u8d28\u5b50\uff0c\u8fd9\u5efa\u7acb\u4e86\u4e00\u6761\u52a8\u529b\u5b66\u4e0a\u53ef\u884c\u7684\u8def\u5f84\u6765\u89c4\u907f\u7535\u5316\u5b66\u6b65\u9aa4\u4e2d\u7684\u70ed\u529b\u5b66\u635f\u5931\u3002<\/p>\n

\"2\"<\/p>\n

\u603b\u4e4b\uff0cNi2<\/sub>P\u7535\u50ac\u5316\u5242\u5bf9CO2<\/sub>RR\u4e2dC2+<\/sub>\u4ea7\u7269\u7684\u4f18\u8d8a\u9009\u62e9\u6027\u5f52\u56e0\u4e8e\u8868\u9762\u5bc6\u96c6\u5206\u5e03\u7684Ni3<\/sub>\u4f4d\u70b9\u7684\u591a\u4e2d\u5fc3\u534f\u540c\u4f5c\u7528\u3002\u8fd9\u79cd\u534f\u540c\u4f5c\u7528\u4f53\u73b0\u5728\u4e24\u4e2a\u5c42\u6b21\u4e0a\uff1a<\/p>\n

\u9996\u5148\uff0c\u6bcf\u4e2a\u5b64\u7acb\u7684Ni3<\/sub>\u50ac\u5316\u4e2d\u5fc3\u7684\u591a\u4e2a\u5438\u9644\u4f4d\u70b9\u53ef\u4ee5\u4e3aC1<\/sub>\u548cC2+<\/sub>\u7269\u79cd\u63d0\u4f9b\u5408\u9002\u7684\u7a7a\u95f4\uff0c\u6709\u52a9\u4e8e\u589e\u52a0C-C\u5076\u8054\u7684\u673a\u4f1a\u5e76\u51cf\u5c11\u6240\u9700\u7684\u80fd\u91cf\u3002<\/p>\n

\u7b2c\u4e8c\uff0c\u8868\u9762\u8d28\u5b50\u901a\u8fc7\u6c34\u8f85\u52a9\u8d28\u5b50\u8f6c\u79fb\uff08WAPT\uff09\u673a\u5236\u5728\u76f8\u90bb\u7684Ni3<\/sub>\u4f4d\u70b9\u4e4b\u95f4\u8f6c\u79fb\uff0c\u6709\u52a9\u4e8e\u5171\u5438\u9644\u6784\u578b\u4e2d*CO\u4e2d\u95f4\u4f53\u7684\u8fdb\u4e00\u6b65\u6c22\u5316\uff0c\u4ece\u800c\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u964d\u4f4eC-C\u5076\u8054\u7684\u6d3b\u5316\u80fd\u5792\u3002<\/p>\n

\"4\"<\/p>\n

Multi-Center Cooperativity Enables Facile C-C Coupling in Electrochemical CO2<\/sub>\u00a0Reduction on a Ni2<\/sub>P Catalyst.\u00a0ACS Catal.<\/em>,\u00a02023<\/strong>, DOI: 10.1021\/acscatal.2c05611.<\/p>\n

https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.2c05611.<\/p>\n","protected":false},"excerpt":{"rendered":"

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