{"id":47562,"date":"2023-03-30T08:02:31","date_gmt":"2023-03-30T00:02:31","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47562"},"modified":"2023-03-15T10:03:28","modified_gmt":"2023-03-15T02:03:28","slug":"angew-chem-%ef%bc%9a%e6%b0%a2%e9%94%ae%e7%bd%91%e7%bb%9c%e7%a8%b3%e5%ae%9a%e7%9a%84%e9%ab%98%e5%ae%b9%e9%87%8f%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e6%9c%89%e6%9c%ba%e6%ad%a3%e6%9e%81","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%b0%a2%e9%94%ae%e7%bd%91%e7%bb%9c%e7%a8%b3%e5%ae%9a%e7%9a%84%e9%ab%98%e5%ae%b9%e9%87%8f%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e6%9c%89%e6%9c%ba%e6%ad%a3%e6%9e%81\/","title":{"rendered":"Angew. Chem. \uff1a\u6c22\u952e\u7f51\u7edc\u7a33\u5b9a\u7684\u9ad8\u5bb9\u91cf\u9502\u79bb\u5b50\u7535\u6c60\u6709\u673a\u6b63\u6781\u6750\u6599"},"content":{"rendered":"
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\u9009\u62e9\u5408\u9002\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u5bf9\u6784\u5efa\u9ad8\u6027\u80fd\u7684\u9502\u79bb\u5b50\u7535\u6c60\u81f3\u5173\u91cd\u8981\u3002\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684\u65e0\u673a\u6b63\u6781\u6750\u6599\uff0c\u6709\u673a\u6750\u6599\u5177\u6709\u8d44\u6e90\u4e30\u5bcc\uff0c\u7eff\u8272\u53ef\u6301\u7eed\u7684\u4f18\u52bf\uff0c\u662f\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u6709\u5229\u5019\u9009\u8005\u3002<\/p>\n

\u7136\u800c\uff0c\u5982\u4f55\u89e3\u51b3\u7535\u6781\u6750\u6599\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u95ee\u9898\u4ecd\u9762\u4e34\u6311\u6218\u3002\u57fa\u4e8e\u6709\u673a\u6750\u6599\u6eb6\u89e3\u6027\u95ee\u9898\uff0c\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u9676\u5360\u826f\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u7b56\u7565\uff0c\u5373\u901a\u8fc7\u5728\u6709\u673a\u5c0f\u5206\u5b50\u7ed3\u6784\u4e2d\u6784\u7b51\u4e30\u5bcc\u7684\u6c22\u952e\u7f51\u7edc\uff0c\u6765\u6291\u5236\u6eb6\u89e3\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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\u901a\u8fc7\u5411\u8298-4\uff0c5\uff0c9\uff0c10-\u56db\u916e\uff08PTO\uff09\u76842\uff0c7\u53d6\u4ee3\u4f4d\u5f15\u5165\u6c28\u57fa\uff08-NH2<\/sub>\uff09\u5b98\u80fd\u56e2\u5408\u6210\u4e862\uff0c7-\u4e8c\u6c28-\u8298-4\uff0c5\uff0c9\uff0c10-\u56db\u916e\uff08PTO-NH2<\/sub>\uff09\u3002\u5f15\u5165\u7684\u6c28\u57fa\u57fa\u56e2\u4e0d\u4ec5\u53ef\u4ee5\u62d3\u5c55\u5171\u8f6d\u5e73\u9762\uff0c\u63d0\u5347\u7535\u5b50\u7535\u5bfc\u548cLi\u79bb\u5b50\u7684\u5d4c\u5165\u52a8\u529b\u5b66\uff0c\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u6c22\u952e\u4f9b\u4f53\u4e0ePTO\u5355\u5143\u7684\u7fb0\u57fa\u4f4d\u70b9\u5f62\u6210\u4e30\u5bcc\u7684\u6c22\u952e\u7f51\u7edc\u3002\u7ea2\u5916\u5149\u8c31\u8bc1\u5b9e\u4e86PTO-NH2<\/sub>\u5206\u5b50\u5185\u5b58\u5728\u4e24\u79cd\u73af\u5883\u7684\u7fb0\u57fa\u548c\u6c28\u57fa\u632f\u52a8\u5cf0\uff0c\u5373\u81ea\u7531\u6001\u548c\u534f\u540c\u6001\uff0cPTO-NH2<\/sub>\u5206\u5b50\u5185\u5b58\u5728\u7531C=O\u548cN-H\u5f62\u6210\u7684\u5206\u5b50\u95f4\u6c22\u952e\uff08C=O\u2026H-N\uff09\u53ca\u7531C=O\u548cAr-H\u5f62\u6210\u7684\u5206\u5b50\u5185\u6c22\u952e\uff08C=O\u2026H-Ar\uff09\u3002PTO-NH2<\/sub>\u6676\u4f53\u7ed3\u6784\u5b58\u5728\u660e\u663e\u7684\u03c0-\u03c0\u5806\u53e0\u6548\u5e94\uff0c\u5806\u53e0\u95f4\u8ddd\u4e3a3.16\u212b\u3002\u4e30\u5bcc\u7684\u6c22\u952e\u7f51\u7edc\u964d\u4f4e\u4e86PTO-NH2<\/sub>\u5206\u5b50\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\u539f\u4f4d\u7ea2\u5916\u548c\u539f\u4f4dXRD\u6d4b\u8bd5\u8bc1\u5b9e\u4e86PTO-NH2<\/sub>\u5206\u5b50\u5185\u5b58\u57281\/3\u7684\u81ea\u7531\u6001\u7fb0\u57fa\u548c2\/3\u7684\u534f\u540c\u6001\u7fb0\u57fa\u3002\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u53ef\u4ee5\u76d1\u6d4b\u5230PTO-NH2<\/sub>\u5206\u5b50\u5185\u6c22\u952e\u7f51\u7edc\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u53ef\u9006\u6f14\u53d8\u3002\u540c\u65f6\uff0c\u4e5f\u8bc1\u5b9e\u4e86\u6c22\u952e\u7f51\u7edc\u7684\u5b58\u5728\u53ef\u4ee5\u7a33\u5b9aPTO-NH2<\/sub>\u5206\u5b50\u7684\u4e24\u7535\u5b50\u4e2d\u95f4\u6001\uff0c\u5e76\u4f7f\u4e24\u7535\u5b50\u4e2d\u95f4\u6001\u5411\u56db\u7535\u5b50\u6001\u5e73\u7a33\u8fc7\u6e21\uff0c\u4ece\u800c\u6291\u5236PTO-NH2<\/sub>\u5206\u5b50\u7684\u6eb6\u89e3\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\u5f97\u76ca\u4e8e\u4e30\u5bcc\u7684\u6c22\u952e\u7f51\u7edc\u7ed3\u6784\uff0cPTO-NH2<\/sub>\u5206\u5b50\u76f8\u6bd4\u4e8ePTO\u5206\u5b50\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u6d3b\u6027\u4f4d\u70b9\u5229\u7528\u7387\uff08\uff0895% vs. 86%\uff09\uff0c\u66f4\u597d\u7684\u500d\u7387\u6027\u80fd\uff08292 mAh g-1<\/sup>\u00a0vs. 135 mAh g-1<\/sup>\u00a0at 1 A g-1<\/sup>\uff09\uff0c\u4ee5\u53ca\u66f4\u9ad8\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff0883% vs. 32% at 50 mA g-1<\/sup>\uff09\u3002\u53e6\u5916\uff0cPVDF\u7c98\u7ed3\u5242\u548cPTO-NH2<\/sub>\u5206\u5b50\u4e4b\u95f4\u5b58\u5728\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u4e5f\u4f1a\u8fdb\u4e00\u6b65\u6291\u5236PTO-NH2<\/sub>\u5206\u5b50\u7684\u6eb6\u89e3\u3002\u8be5\u5de5\u4f5c\u4e3a\u6291\u5236\u6709\u673a\u7535\u6781\u6750\u6599\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u9896\u7684\u6750\u6599\u8bbe\u8ba1\u7406\u5ff5\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\u8bba<\/strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n
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Hydrogen Bond Networks Stabilized High-Capacity Organic Cathode for Lithium-Ion Batteries<\/p>\n

Shibing Zheng,\u00a0Dongjie Shi,\u00a0Tianjiang Sun,\u00a0Letian Zhang,\u00a0Weijia Zhang,\u00a0Yixin Li,\u00a0Zhenbo Guo,\u00a0Zhanliang Tao,\u00a0Jun Chen<\/p>\n

\u5357\u5f00\u5927\u5b66\u535a\u58eb\u751f\u90d1\u4ed5\u5175\u3001\u5b59\u7530\u5c06\u548c\u7855\u58eb\u751f\u77f3\u51ac\u5a55\u4e3a\u672c\u6587\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

Angewandte Chemie International Edition<\/em><\/p>\n

DOI:\u00a010.1002\/anie.202217710<\/p>\n<\/section>\n<\/section>\n<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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