{"id":47550,"date":"2023-03-29T08:12:59","date_gmt":"2023-03-29T00:12:59","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47550"},"modified":"2023-03-14T10:13:48","modified_gmt":"2023-03-14T02:13:48","slug":"%e6%b5%99%e5%b7%a5%e5%a4%a7%e6%b2%88%e6%84%8fafm%ef%bc%9ati1-n3-ctf-10%e9%ab%98%e6%95%88%e5%8e%bb%e9%99%a4%e5%be%ae%e6%b1%a1%e6%9f%93%e7%89%a9","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e6%b5%99%e5%b7%a5%e5%a4%a7%e6%b2%88%e6%84%8fafm%ef%bc%9ati1-n3-ctf-10%e9%ab%98%e6%95%88%e5%8e%bb%e9%99%a4%e5%be%ae%e6%b1%a1%e6%9f%93%e7%89%a9\/","title":{"rendered":"\u200b\u6d59\u5de5\u5927\u6c88\u610fAFM\uff1aTi1-N3\/CTF-10\u9ad8\u6548\u53bb\u9664\u5fae\u6c61\u67d3\u7269"},"content":{"rendered":"<p>\u5355\u539f\u5b50\u6750\u6599\u5177\u6709\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u6700\u5927\u5316\u7684\u539f\u5b50\u5229\u7528\u7387\uff0c\u5728\u6709\u673a\u6c61\u67d3\u7269\uff08EOPs\uff09\u7684\u4fee\u590d\u4e2d\u663e\u793a\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u4f46\u63ed\u793a\u81ea\u65cb\u6001\u6c34\u5e73\u4e0a\u7684\u5185\u5728\u53cd\u5e94\u673a\u5236\u4ecd\u662f\u4e00\u9879\u8270\u5de8\u7684\u6311\u6218\u3002<\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u6d59\u6c5f\u5de5\u4e1a\u5927\u5b66\u6c88\u610f\u526f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u8d1f\u8f7d\u5355\u539f\u5b50\u949b\uff08Ti<sub>1<\/sub>\uff09\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08Ti<sub>1<\/sub>\/CTF\uff09\uff0c\u7528\u4e8e\u6d89\u53ca\u5438\u9644\u548c\u5149\u50ac\u5316\u534f\u540c\u4f5c\u7528\u7684\u4e24\u9636\u6bb5\u8fc7\u7a0b\uff0c\u5e76\u8bc1\u660e\u4e86\u7535\u5b50\u81ea\u65cb\u72b6\u6001\u5728\u8c03\u8282\u6750\u6599\u56fa\u6709\u6d3b\u6027\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<p>\u81ea\u65cb\u6781\u5316Ti<sub>1<\/sub>-N<sub>3<\/sub>\/CTF-10\u663e\u8457\u63d0\u9ad8\u4e862, 2, 4, 4\u2019-\u56db\u7f9f\u57fa\u4e8c\u82ef\u7532\u916e\uff08BP-2\uff09\u7684\u5438\u9644\u5bb9\u91cf\uff08453.285 \u00b5mol g<sup>\u22121<\/sup>\uff09\u548c\u964d\u89e3\u52a8\u529b\u5b66\uff082.263 h<sup>\u22121<\/sup>\uff0c\u6bd4CTF-0\u5feb17.0\u500d\uff09\uff0c\u5e76\u5728\u5e94\u7528\u4e8e\u5929\u7136\u6c34\u4e2d\u5177\u6709\u957f\u671f\u7a33\u5b9a\u6027\uff08\u5728\u4e03\u6b21\u5faa\u73af\u4e2d\u53bb\u966493.3%\u7684BP-2\uff09\u548c\u4f4e\u6210\u672c\uff084.45 kWh\u2219m<sup>\u22123<\/sup>\u7535\u80fd\/\u6b21\uff09\u3002<\/p>\n<p><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230306\/1678071214233264.jpg\" alt=\"1\" \/><\/p>\n<p>\u901a\u8fc7DFT\u8ba1\u7b97\u53d1\u73b0\uff0c\u5728Ti<sub>1<\/sub>-N<sub>3<\/sub>\/CTF-5\u548cTi<sub>1<\/sub>-N<sub>3<\/sub>\/CTF-10\u4e2d\uff0c\u81ea\u65cb\u6781\u5316\u7535\u5b50\u4e91\u5206\u5e03\u660e\u663e\u589e\u5f3a\uff0c\u800c\u5728CTF-0\u548cTiO<sub>2<\/sub>\/CTF-15\u4e2d\uff0c\u81ea\u65cb\u6781\u5316\u7535\u5b50\u4e91\u5206\u5e03\u6d88\u5931\uff0c\u8fd9\u4e24\u79cd\u4f53\u7cfb\u4e2d\u6ca1\u6709Ti<sub>1<\/sub>-N<sub>3<\/sub>\u57fa\u56e2\u3002<\/p>\n<p>\u6b64\u5916\uff0cDOS\u56fe\u8868\u660e\uff0c\u603b\u81ea\u65cb\u78c1\u77e9\uff08\u03bc<sub>eff<\/sub>\uff09\u7684\u4ea7\u751f\u6e90\u4e8eTi<sub>1<\/sub>-N<sub>3<\/sub>\u5355\u5143\u8bf1\u5bfc\u7684\u81ea\u65cb\u6781\u5316\u7535\u5b50\u7684\u518d\u5206\u914d\u3002Ti<sub>1<\/sub>-N<sub>3<\/sub>\/CTF-10\u4e2d\u7684N 2p\u8f68\u9053\u9010\u6e10\u53d8\u7a84\u5e76\u4e0eTi 3d\u8f68\u9053\u90e8\u5206\u91cd\u53e0\uff0c\u589e\u5f3a\u4e86Ti\u4e0eCTF\u9aa8\u67b6\u7684\u76f8\u4e92\u4f5c\u7528\u548c\u7a33\u5b9a\u6027\u3002Ti<sub>1<\/sub>-N<sub>3<\/sub>\/CTF-10\u548cTiO<sub>2<\/sub>\/CTF-15\u7684d-\u5e26\u4e2d\u5fc3<em>\u03b5<\/em><sub>d<\/sub>\u5206\u522b\u4e3a-0.78 eV\u548c-4.49 eV\uff0cTi<sub>1<\/sub>-N<sub>3<\/sub>\u57fa\u56e2\u7684\u5b58\u5728\u4f7f<em>\u03b5<\/em><sub>d<\/sub>\u8fbe\u5230\u8d39\u7c73\u80fd\u7ea7\uff0c\u589e\u5f3a\u4e86Ti\u7684\u5438\u9644\u4eb2\u548c\u6027\u3002<\/p>\n<p><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230306\/1678071220671446.jpg\" alt=\"2\" \/><\/p>\n<p>\u6b64\u5916\uff0c\u4f5c\u8005\u5206\u6790\u4e86\u81ea\u65cb\u6781\u5316CTFs\u5bf9\u6c61\u67d3\u7269\u7684\u5438\u9644\u884c\u4e3a\u3002BP-2\u5438\u9644\u4e3b\u8981\u4f4d\u4e8eCTFS\u7684\u82ef\u73af\u7ed3\u6784\u4e0a\uff0c\u03c0-\u03c0 EDA\u76f8\u4e92\u4f5c\u7528\u63d0\u4f9b\u4e86\u7a33\u5b9a\u7684\u5438\u9644\u529b\u3002Ti<sub>1<\/sub>-N<sub>3<\/sub>\u8bf1\u5bfc\u7684\u81ea\u65cb\u6781\u5316\u589e\u5f3a\u4e86\u539f\u5b50\u5206\u6563\u7684Ti\u7684\u7535\u8d1f\u6027\uff0c\u4ece\u800c\u5728\u6c61\u67d3\u7269\u548c\u6750\u6599\u4e4b\u95f4\u4ea7\u751f\u4e86\u8bf1\u5bfc\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n<p>\u603b\u4e4b\uff0cCTFs\u4e2d\u7684Ti<sub>1<\/sub>-N<sub>3<\/sub>\u4f4d\u70b9\u7a33\u5b9a\u4e86\u6c61\u67d3\u7269\u5206\u5b50\uff0c\u800c\u6c22\u952e\u8bf1\u5bfc\u7684\u03c0-\u03c0 EDA\u4e0e\u5076\u6781\u529b\u4e4b\u95f4\u7684\u201c\u63a8\u62c9\u201d\u76f8\u4e92\u4f5c\u7528\u8fdb\u4e00\u6b65\u589e\u5f3a\u4e86\u6c61\u67d3\u7269\u5728\u6750\u6599\u754c\u9762\u5904\u7684\u7ed3\u6784\u7578\u53d8\u3002<\/p>\n<p><img decoding=\"async\" title=\"5\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230306\/1678071229728679.jpg\" alt=\"5\" \/><\/p>\n<p>Unveiling Spin State-Dependent Micropollutant Removal using Single-Atom Covalent Triazine Framework.\u00a0<em>Adv. Funct. Mater.,\u00a0<\/em><strong>2023<\/strong>, DOI: 10.1002\/adfm.202210905.<\/p>\n<p>https:\/\/doi.org\/10.1002\/adfm.202210905.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5355\u539f\u5b50\u6750\u6599\u5177\u6709\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u6700\u5927\u5316\u7684\u539f\u5b50\u5229\u7528\u7387\uff0c\u5728\u6709\u673a\u6c61\u67d3\u7269\uff08EOPs\uff09\u7684\u4fee\u590d\u4e2d\u663e\u793a\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u4f46\u63ed\u793a [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47550","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47550","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47550"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47550\/revisions"}],"predecessor-version":[{"id":47551,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47550\/revisions\/47551"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47550"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47550"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47550"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}