{"id":47437,"date":"2023-03-17T08:46:47","date_gmt":"2023-03-17T00:46:47","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47437"},"modified":"2023-03-02T10:47:49","modified_gmt":"2023-03-02T02:47:49","slug":"%e5%bf%bb%e8%8e%b7%e9%ba%9f-%e7%8e%8b%e8%8f%b2-%e5%88%98%e8%be%89afm%ef%bc%9a%e9%80%9a%e8%bf%87%e7%a1%bc%e5%92%8c%e6%b0%ae%e5%8f%8c%e9%85%8d%e4%bd%8d%e8%b0%83%e8%8a%82%e5%8d%95%e5%8e%9f%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%bf%bb%e8%8e%b7%e9%ba%9f-%e7%8e%8b%e8%8f%b2-%e5%88%98%e8%be%89afm%ef%bc%9a%e9%80%9a%e8%bf%87%e7%a1%bc%e5%92%8c%e6%b0%ae%e5%8f%8c%e9%85%8d%e4%bd%8d%e8%b0%83%e8%8a%82%e5%8d%95%e5%8e%9f%e5%ad%90\/","title":{"rendered":"\u5ffb\u83b7\u9e9f\/\u738b\u83f2\/\u5218\u8f89AFM\uff1a\u901a\u8fc7\u787c\u548c\u6c2e\u53cc\u914d\u4f4d\u8c03\u8282\u5355\u539f\u5b50\u954d\u7684\u7535\u5b50\u7ed3\u6784\u4fc3\u8fdb\u6c27\u8fd8\u539f\u53cd\u5e94"},"content":{"rendered":"<section>\u78b3\u8f7d\u4f53\u4e0a\u542b\u6c2e\u914d\u4f4d\u76843D\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u7535\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u51c6\u786e\u5730\u8c03\u63a7\u5355\u539f\u5b50\u91d1\u5c5e\u4f4d\u70b9\u7684\u914d\u4f4d\u7ed3\u6784\u5e76\u786e\u5b9a\u51e0\u4f55\/\u7535\u5b50\u7ed3\u6784\u4e0eORR\u6d3b\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002<\/section>\n<p>&nbsp;<\/p>\n<section>\u57fa\u4e8e\u6b64\uff0c<strong>\u52a0\u5dde\u5927\u5b66\u5ffb\u83b7\u9e9f\u6559\u6388\uff0c\u6cb3\u5317\u5de5\u4e1a\u5927\u5b66\u738b\u83f2\u7814\u7a76\u5458\uff0c\u5218\u8f89\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u5177\u6709\u787c\u548c\u6c2e\u53cc\u914d\u4f4d\u7684\u78b3\u8d1f\u8f7d\u5355\u539f\u5b50\u954d\u50ac\u5316\u5242\uff08Ni-B\/N-C\uff09\uff0c\u76f8\u5bf9\u4e8e\u539f\u59cb\u7684Ni-N-C\u50ac\u5316\u5242\u5177\u6709\u66f4\u4f18\u5f02\u7684ORR\u6d3b\u6027\u3002<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230224\/1677206171422011.jpg\" alt=\"1\" \/><\/section>\n<section>\u672c\u6587\u901a\u8fc7DFT\u8ba1\u7b97\u4ece\u539f\u5b50\u6c34\u5e73\u4e0a\u63a2\u8ba8\u4e86Ni-B\/N-C\u7535\u50ac\u5316\u5242\u5177\u6709\u4f18\u5f02\u7684ORR\u6d3b\u6027\u7684\u539f\u56e0\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u5f15\u5165B\u540eNi\u4e2d\u5fc3\u7684\u7535\u8377\u5bc6\u5ea6\u589e\u52a0\uff0c\u800c\u0394<em>G<\/em><sub>O*<\/sub>\u968fNi\u4e2d\u5fc3Bader\u7535\u8377\u7684\u589e\u52a0\u800c\u51cf\u5c0f\u3002\u8fd9\u8868\u660eNi-B<sub>1<\/sub>N<sub>3<\/sub>\u4e0e\u5438\u9644O*\u7684\u7ed3\u5408\u6bd4Ni-N<sub>4<\/sub>\u66f4\u5f3a\uff0c\u53ef\u80fd\u5177\u6709\u66f4\u597d\u7684ORR\u50ac\u5316\u6d3b\u6027\u3002<img decoding=\"async\" title=\"4\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230224\/1677206180535274.jpg\" alt=\"4\" \/><\/section>\n<section>\u6295\u5f71\u6001\u5bc6\u5ea6\u56fe\uff08PDOS\uff09\u8868\u660e\uff0c\u03c3\u952e\u6765\u6e90\u4e8eNi 3dz<sup>2<\/sup>\u548cO 2pz\u8f68\u9053\u7684\u91cd\u53e0\u3002\u4e0eNi-N-C\u76f8\u6bd4\uff0cNi-B\/N-C\u5728\u8d39\u7c73\u80fd\u7ea7\u4ee5\u4e0b\u6709\u8f83\u5c11\u7684\u03c3*\u53cd\u952e\u7535\u5b50\u586b\u5145\uff0c\u8fd9\u610f\u5473\u7740Ni\u4e2d\u5fc3\u4e0e\u5438\u9644\u7684O\u4e4b\u95f4\u6709\u5f88\u5f3a\u7684\u8026\u5408\u3002Ni-B\/N-C\u4e2d\u8f83\u8d1f\u7684\u6676\u4f53\u8f68\u9053\u91cd\u53e0\u5e03\u5c45\u79ef\u5206\u503c\uff08ICOOP\uff09\u8868\u660eNi\u4e0eO\u4e4b\u95f4\u7684\u6210\u952e\u6bd4\u5728Ni-N-C\u4e2d\u66f4\u5f3a\u3002ORR\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe\u8868\u660e\uff0c\u5f15\u5165B\u540e\u8fc7\u7535\u4f4d\u4ece1.81\u964d\u4f4e\u52300.92 V\u3002\u56e0\u6b64\uff0cNi-B<sub>1<\/sub>N<sub>3<\/sub>\u7684\u5c40\u90e8\u914d\u4f4d\u73af\u5883\u6709\u5229\u4e8e\u63d0\u9ad8Ni-B\/N-C\u50ac\u5316\u5242\u7684ORR\u6d3b\u6027\u3002<\/section>\n<section>Modulating Electronic Structure of Atomically Dispersed Nickel Sites through Boron and Nitrogen Dual Coordination Boosts Oxygen Reduction.\u00a0<em>Adv. Funct. Mater.<\/em>,\u00a0<strong>2023<\/strong>, DOI: 10.1002\/adfm.202213863.<\/section>\n<section>https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202213863.<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u78b3\u8f7d\u4f53\u4e0a\u542b\u6c2e\u914d\u4f4d\u76843D\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u7535\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u51c6\u786e\u5730\u8c03\u63a7\u5355\u539f\u5b50 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47437","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47437","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47437"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47437\/revisions"}],"predecessor-version":[{"id":47438,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47437\/revisions\/47438"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47437"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47437"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47437"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}