{"id":47430,"date":"2023-03-16T08:24:58","date_gmt":"2023-03-16T00:24:58","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47430"},"modified":"2023-03-01T10:25:52","modified_gmt":"2023-03-01T02:25:52","slug":"angew-chem-%ef%bc%9a%e9%80%9a%e8%bf%87dz2%e8%bd%a8%e9%81%93%e9%a9%b1%e5%8a%a8%e7%9a%84%e7%94%b5%e8%8d%b7%e8%b0%83%e8%8a%82%e7%ad%96%e7%95%a5%e8%b0%83%e8%8a%82fen4%e4%bd%8d%e7%82%b9%e7%9a%84%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e9%80%9a%e8%bf%87dz2%e8%bd%a8%e9%81%93%e9%a9%b1%e5%8a%a8%e7%9a%84%e7%94%b5%e8%8d%b7%e8%b0%83%e8%8a%82%e7%ad%96%e7%95%a5%e8%b0%83%e8%8a%82fen4%e4%bd%8d%e7%82%b9%e7%9a%84%e7%94%b5\/","title":{"rendered":"Angew. Chem. 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decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230223\/1677120157512480.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>COP\u6750\u6599\u7684\u4f18\u52bf\u5728\u4e8e\u5206\u5b50\u7ed3\u6784\u4e2d\u5b9a\u4e49\u660e\u786e\u7684\u539f\u5b50\u7ed3\u6784\u6392\u5217\uff0c\u56e0\u6b64\u5b83\u4eec\u5177\u5907\u5de8\u5927\u7684\u4f18\u52bf\u548c\u53ef\u80fd\u6027\u53ef\u4ee5\u901a\u8fc7\u5206\u5b50\u7ed3\u6784\u8bbe\u8ba1\u3001\u88c5\u914d\u5e76\u4fee\u9970\u6d3b\u6027\u4f4d\u70b9\u5468\u56f4\u7684\u5c40\u57df\u914d\u4f4d\u73af\u5883\u3002COP\u9aa8\u67b6\u805a\u5408\u8fc7\u7a0b\u4e2d\u5178\u578b\u7684\u7f51\u72b6\u9650\u57df\u89c4\u5219\u80fd\u591f\u5c06\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u7cbe\u786e\u5730\u6392\u5e03\u7f16\u7ec7\u8fdbCOP\u6784\u7b51\u5355\u5143\u7684\u7f51\u7edc\u5185\u8154\u4e2d\u3002\u5728\u8fd9\u6837\u7684\u6392\u5217\u89c4\u5219\u4e0b\uff0cCOP\u6750\u6599\u81ea\u7136\u5730\u4fdd\u7559\u4e86FeN<sub>4<\/sub>\u4f4d\u70b9\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\u3002\u53d7\u76ca\u4e8eCOP\u7f51\u7edc\u7ed3\u6784\u4e2d\u9ad8\u7535\u5b50\u79bb\u57df\u6027\u7684\u5171\u8f6d\u4f53\u7cfb\u548c\u7a33\u56fa\u7684\u5171\u4ef7\u952e\u94fe\u63a5\uff0c\u5f97\u5230\u7684COP\u6750\u6599\u5c55\u73b0\u4e86\u826f\u597d\u7684\u7535\u5b50\u5bfc\u7535\u6027\u4ee5\u53ca\u6770\u51fa\u7684\u6c34\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd9\u5341\u5206\u6709\u52a9\u4e8eCOP\u6750\u6599\u5728\u9178\u3001\u78b1\u4ecb\u8d28\u4e2d\u7a33\u56fa\u5730\u5b58\u5728\u3002\u4f5c\u8005\u57fa\u4e8eCOP\u6750\u6599\u7ed3\u6784\u53ef\u8c03\u8282\u7684\u7279\u70b9\uff0c\u65b0\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u5168\u03c0\u5171\u8f6d\u7684\u672c\u5f81COP\u57fa\u6a21\u578b\u50ac\u5316\u5242\uff0c\u5b83\u4eec\u5206\u5b50\u7ed3\u6784\u4e2d\u5177\u5907\u6e05\u6670\u7684\u5c40\u90e8\u914d\u4f4d\u73af\u5883\uff1a\u5206\u5b50\u7ed3\u6784\u4e2d\u5929\u7136\u5730\u517c\u987e\u4e86FeN<sub>4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53ca\u5728\u8f74\u5411\u4fa7\u94fe\u65b9\u5411\u4f5c\u8005\u5b9a\u5411\u5730\u5f15\u5165\u4e86\u5177\u6709\u4e0d\u540c\u5438\/\u4f9b\u7535\u5b50\u6027\u8d28\u7684\u5b98\u80fd\u56e2\u7cbe\u5bc6\u5730\u4fee\u9970FeN<sub>4<\/sub>\u4f4d\u70b9\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230223\/1677120170426075.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>EXANES\u8c31\u56fe\u6d4b\u8bd5\u5206\u6790\u8bc1\u660e\u4e86\u5728\u4e00\u4e9b\u8f74\u5411\u4fa7\u94fe\u4fee\u9970\u7684COP\u4e2d\uff0c\u66f4\u591a\u7684\u6b63\u7535\u8377\u88ab\u8f74\u5411\u4fa7\u94fe\u5438\u7535\u5b50Cl\u5b98\u80fd\u56e2\u5468\u56f4\u7684Fe\u5355\u539f\u5b50\u6240\u643a\u5e26\u3002\u539f\u4f4dEXAFS\u52a8\u6001\u76d1\u6d4b\u4e86COP<sub>BTC<\/sub>@Cl-CNTs\u50ac\u5316\u5242\u5728\u6574\u4e2a\u6c27\u8fd8\u539f\u50ac\u5316\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u9ad8\u4ef7\u6001\u7684Fe<sup>H+<\/sup>N<sub>4<\/sub>\u4f4d\u70b9\u6784\u578b\u7ed3\u6784\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u8bc1\u5b9e\u4e86\u8f74\u5411\u4fa7\u94fe\u5b98\u80fd\u56e2\u6253\u7834\u4e86\u5e73\u9762FeN<sub>4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u7535\u8377\u7684\u5bf9\u79f0\u6027\uff0c\u5e76\u4e14\u4ece\u5e73\u9762\u5355\u94c1\u539f\u5b50\u4e2d\u5fc3\u63d0\u53d6\u51fa\u66f4\u591a\u7535\u5b50\u8fdb\u5165\u8f74\u5411\u7684\u5438\u7535\u5b50\u4fa7\u94fe\u57fa\u56e2\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230223\/1677120178490391.png\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u57fa\u4e8e\u5b9e\u9a8c\u4e0a\u7684\u65b0\u53d1\u73b0\uff0c\u4f5c\u8005\u521b\u65b0\u6027\u5730\u63d0\u51fa\u4e00\u79cd\u65b0\u7684\u63cf\u8ff0\u7b26\u03be\uff0c\u5b83\u88ab\u5b9a\u4e49\u4e3aFe\u539f\u5b50\u6295\u5f71\u52303dz<sup>2<\/sup>\u8f68\u9053\u7684\u80fd\u5e26\u4e2d\u5fc3\u3002\u901a\u8fc7\u8be5\u63cf\u8ff0\u7b26\uff0c\u4f5c\u8005\u5b9a\u91cf\u5730\u8bba\u8bc1\u4e86\u5438\u7535\u5b50\u4fa7\u94fe\u57fa\u56e2\u5bf9FeN<sub>4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u50ac\u5316\u6d3b\u6027\u7684\u706b\u5c71\u8c03\u8282\u673a\u5236\u3002\u5f53\u03be\u503c\u5206\u5e03\u4e8e -1.887 ~ -1.862 eV\u4e4b\u95f4\u65f6\uff0cCOP<sub>BTC<\/sub>@Cl-CNTs\u7535\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u8fbe\u5230\u6700\u4f73\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230223\/1677120190452631.png\" alt=\"6\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6700\u7ec8\uff0c\u5e94\u7528\u8be5\u975e\u70ed\u89e3\u7684COP<sub>BTC<\/sub>@Cl-CNTs\u4f5c\u4e3a\u9634\u6781\u50ac\u5316\u5242\u76f4\u63a5\u7ec4\u88c5PEMFCs\uff0c\u663e\u8457\u63d0\u5347\u4e86PEMFCs\u6700\u5927\u529f\u7387\u5bc6\u5ea6\uff0c\u6700\u7ec8\u8fbe\u5230231.5 mW cm<sup>-2<\/sup>\u7684\u5cf0\u503c\u529f\u7387\u3002\u4e0e\u6ca1\u6709\u529f\u80fd\u88c5\u9970\u7684COP<sub>BTC<\/sub>-CNTs\u76f8\u6bd4\uff0c\u8fd9\u662f\u4e00\u4e2a\u6570\u91cf\u7ea7\u7684\u6027\u80fd\u98de\u8dc3\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f20\u7edf\u70ed\u89e3\u5236\u5907\u7684M-N-C\u50ac\u5316\u5242\u9020\u6210\u7684\u6d3b\u6027\u4f4d\u70b9\u7ed3\u6784\u7684\u591a\u6837\u6027\u7ecf\u5e38\u96fe\u5316\u4e86\u6d3b\u6027\u4f4d\u70b9\u5468\u56f4\u7684\u5c40\u57df\u914d\u4f4d\u73af\u5883\u7684\u7814\u7a76\uff0c\u4ece\u800c\u5236\u7ea6\u4e86 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47430","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47430","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47430"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47430\/revisions"}],"predecessor-version":[{"id":47431,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47430\/revisions\/47431"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47430"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47430"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47430"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}