{"id":47329,"date":"2023-03-04T08:20:22","date_gmt":"2023-03-04T00:20:22","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47329"},"modified":"2023-02-17T10:21:14","modified_gmt":"2023-02-17T02:21:14","slug":"angew-chem-%ef%bc%9a3d%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e5%8e%9f%e5%ad%90%e4%b8%ad%e7%9a%84%e5%8f%8d%e5%b8%b8%e7%94%b5%e5%ad%90%e6%9e%84%e5%9e%8b","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a3d%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e5%8e%9f%e5%ad%90%e4%b8%ad%e7%9a%84%e5%8f%8d%e5%b8%b8%e7%94%b5%e5%ad%90%e6%9e%84%e5%9e%8b\/","title":{"rendered":"Angew. Chem. \uff1a3d\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u4e2d\u7684\u53cd\u5e38\u7535\u5b50\u6784\u578b"},"content":{"rendered":"
\n
\n
\n
\n
\u8fd1\u5e74\u6765\uff0c\u4ef7\u7535\u5b50\u5df2\u7ecf\u6210\u4e3a\u6750\u6599\u4f53\u7cfb\u4e2d\u65b0\u73b0\u8c61\u4e0e\u65b0\u6027\u8d28\u76f8\u5173\u7814\u7a76\u4e2d\u7684\u6838\u5fc3\u5173\u6ce8\u70b9\u4e4b\u4e00\u3002\u5df2\u6709\u7814\u7a76\u8868\u660e\uff0c\u8bf8\u591a\u7269\u7406\u4e0e\u5316\u5b66\u6027\u8d28\u5b9e\u8d28\u4e0a\u53d6\u51b3\u4e8e\u6750\u6599\u67d0\u4e00\u7279\u5b9a\u8f68\u9053\u7684\u4ef7\u7535\u5b50\uff0c\u4f8b\u5982Pb\u4e0eBi\u76f8\u5173\u6750\u6599\u7684\u94c1\u7535\u6027\u6e90\u4e8e\u51766s\u5b64\u5bf9\u7535\u5b50\uff0cf\u7535\u5b50\u5728\u8367\u5149\u6750\u6599\u7814\u7a76\u4e2d\u8d77\u7740\u51b3\u5b9a\u6027\u4f5c\u7528\uff0c\u800cd\u7535\u5b50\u5219\u5728\u5305\u62ec\u91d1\u5c5e-\u7edd\u7f18\u4f53\u76f8\u53d8\u3001\u5de8\u78c1\u7535\u963b\u6548\u5e94\u7b49\u8fc7\u6e21\u91d1\u5c5e\u6750\u6599\u6027\u8d28\u7814\u7a76\u4e2d\u5360\u4e3b\u5bfc\u4f4d\u7f6e\u3002<\/p>\n

\u5728\u5173\u4e8e3d\u8fc7\u6e21\u91d1\u5c5e\u6750\u6599\u7684\u7814\u7a76\u4e2d\uff0c\u7814\u7a76\u8005\u603b\u662f\u4e60\u60ef\u6027\u5c06\u76ee\u5149\u805a\u7126\u4e8e3d\u7535\u5b50\uff0c\u4f8b\u5982\u5173\u6ce8\u5176\u4e2d3d\u8f68\u9053\u7684\u80fd\u5e26\u4e2d\u5fc3\u4e0e\u50ac\u5316\u6027\u80fd\u7684\u5173\u8054\u3001\u4e0d\u540c\u7ed3\u6784\u53ca\u5176\u6f14\u5316\u4e2d\u8f68\u9053\u7684\u7b80\u5e76\u4e0e\u9000\u7b80\u5e76\u3001\u5404\u4e2a3d\u8f68\u9053\u4e0a\u7535\u5b50\u6570\u7684\u53d8\u5316\u53ca\u5176\u5bf9\u4e8e\u6750\u6599\u6027\u8d28\u7684\u5f71\u54cd\u3002\u7136\u800c\uff0c\u7279\u5b9a\u7684\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u4e0e\u6750\u6599\u7ed3\u6784\u4e2d\uff0c\u53ef\u80fd\u5b58\u5728\u4ef7\u7535\u5b50\u5360\u636e\u8f68\u9053\u7684\u4f18\u5148\u7ea7\u51fa\u73b0\u53d8\u5316\u7684\u73b0\u8c61\uff0c\u5373\u51fa\u73b0\u53cd\u5e38\u7535\u5b50\u6784\u578b\uff0c\u4f7f\u5f97\u975e3d\u8f68\u9053\u7684\u4ef7\u7535\u5b50\u6210\u4e3a\u6750\u6599\u6027\u8d28\u7684\u4e3b\u5bfc\u3002<\/p>\n

\u8003\u8651\u5230\u5b9e\u9645\u7814\u7a76\u4e2d\uff0c\u6750\u6599\u4f53\u7cfb\u5185\u5316\u5b66\u73af\u5883\u7684\u590d\u6742\u6027\uff0c\u4f20\u7edf\u7406\u8bba\u5bf9\u7279\u5b9a\u539f\u5b50\u7684\u7535\u5b50\u6784\u578b\u7684\u9884\u6d4b\u53ef\u80fd\u5e76\u4e0d\u51c6\u786e\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8e\u7535\u5b50\u6784\u578b\u7684\u5b9e\u9a8c\u6d4b\u5b9a\uff0c\u5c24\u5176\u5bf9\u4e8e\u90e8\u5206\u539f\u5b50\u7684\u7535\u5b50\u6784\u578b\u53ef\u80fd\u5b58\u5728\u4e89\u8bae\u7684\u6750\u6599\u800c\u8a00\uff0c\u662f\u5bf9\u5176\u7279\u6b8a\u6027\u8d28\uff0c\u4ee5\u53ca\u6027\u8d28-\u7535\u5b50\u5173\u8054\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76\u7684\u5fc5\u8981\u524d\u63d0\uff0c\u4e5f\u5c06\u6210\u4e3a\u7814\u7a76\u8005\u672a\u6765\u8fdb\u4e00\u6b65\u5c1d\u8bd5\u8c03\u63a7\u6750\u6599\u6027\u8d28\uff0c\u8bbe\u8ba1\u7406\u60f3\u6750\u6599\u7684\u575a\u5b9e\u57fa\u7840\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u8c37\u6797\u6559\u6388\u56e2\u961f\uff0c\u4ee5ScS\u4f5c\u4e3a\u7814\u7a76\u5bf9\u8c61\uff0c\u5229\u7528\u4f1a\u805a\u675f\u7535\u5b50\u884d\u5c04\u6280\u672f\u4ee5\u53ca\u591a\u6781\u62df\u5408\u65b9\u6cd5\uff0c\u5bf9\u4e8e\u6750\u6599\u7684\u7a7a\u95f4\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u8fdb\u884c\u4e86\u7cbe\u786e\u91cd\u6784\uff0c\u5e76\u4e14\u5206\u6790\u4e86\u539f\u5b50\u7684\u8f68\u9053\u7535\u5b50\u5360\u636e\u60c5\u51b5\u3002\u7814\u7a76\u8868\u660e\uff0c\u5176\u4e2d\u7684Sc2+<\/sup>\u5177\u6709\u4e0d\u540c\u4e8e\u5176\u5b833d\u8fc7\u6e21\u91d1\u5c5e\u5143\u7d20\u7684\uff0c\u5e76\u4e0e\u4f20\u7edf\u7406\u8bba\u9884\u671f\u6240\u4e0d\u540c\u7684[Ar]4s1<\/sup>\u7535\u5b50\u6784\u578b\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

 <\/p>\n

\n
<\/section>\n<\/section>\n

 <\/p>\n

\"1\"<\/section>\n
\n
\n
\n
\n
\u5728\u5f97\u5230\u7684\u5f62\u53d8\u7535\u8377\u5bc6\u5ea6\u56fe\u4e2d\uff0c\u4e0e\u5df2\u6709\u7684\u5173\u4e8eTiS6<\/sub>\u3001TiO6<\/sub>\u3001MnO6<\/sub>\u7b49\u5178\u578b\u8fc7\u6e21\u91d1\u5c5e\u4e2d\u5fc3\u516b\u9762\u4f53\u4e2d\u7535\u8377\u5bc6\u5ea6\u7684\u7814\u7a76\u4e0d\u540c\uff0cSc\u539f\u5b50\u6240\u5904\u4f4d\u7f6e\u5904\u672a\u80fd\u89c2\u5bdf\u5230\u5178\u578b\u7684d\u8f68\u9053\u7279\u5f81\uff0c\u53cd\u800c\u5c55\u73b0\u51fa\u63a5\u8fd1\u7403\u5f62\u7684\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002\u8fdb\u4e00\u6b65\u7684\u8f68\u9053\u7535\u5b50\u5360\u636e\u5206\u6790\u8868\u660e\uff0cSc2+<\/sup>\u7684t2g<\/sub>\u8f68\u9053\u51e0\u4e4e\u7a7a\u7f6e\uff0c\u800c\u8003\u8651\u5230Sc\u4e0eS\u4e4b\u95f4\u6210\u952e\u6709\u5171\u4ef7\u952e\u6210\u5206\uff0ceg<\/sub>\u8f68\u9053\u4e0a\u7684\u7535\u5b50\u6570\u53ef\u88ab\u8ba4\u4e3a\u6e90\u4e8e\u4e0eS\u76843p\u8f68\u9053\u5171\u7528\u7535\u5b50\u73b0\u8c61\u3002\u57fa\u4e8e\u4e0a\u8ff0\u7ed3\u679c\uff0cScS\u4e2dSc2+<\/sup>\u5269\u4f59\u7684\u5916\u5c42\u4ef7\u7535\u5b50\u503e\u5411\u4e8e\u5360\u636e4s\u8f68\u9053\u800c\u975e\u4f20\u7edf\u8ba4\u77e5\u4e2d\u76843d\u8f68\u9053\u3002\u6b64\u7ed3\u679c\u540c\u6837\u4e0eSc2+<\/sup>\u7684\u81ea\u7531\u539f\u5b50\u5149\u8c31\u6240\u5f97\u7ed3\u679c\u4e0d\u540c\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\n
<\/section>\n<\/section>\n
\"2\"<\/section>\n
\n
\n
\n
\n
\u6b64\u7814\u7a76\u63ed\u793a\u4e86Sc\u57283d\u8fc7\u6e21\u91d1\u5c5e\u4e2d\u6240\u5177\u6709\u7684\u72ec\u7279\u6027\u8d28\uff0c\u4ee5\u53ca\u5728\u5b9e\u9645\u6750\u6599\u4f53\u7cfb\u4e2d\uff0c\u5316\u5b66\u73af\u5883\u4e0e\u6210\u952e\u5177\u6709\u6539\u53d8\u7279\u5b9a\u539f\u5b50\u7684\u7535\u5b50\u7ed3\u6784\u7684\u53ef\u80fd\u6027\u3002\u57fa\u4e8e\u6b64\uff0c\u5bf9\u4e8e\u90e8\u5206\u4e0d\u540c\u8f68\u9053\u80fd\u91cf\u5dee\u8ddd\u4e0d\u9ad8\u7684\u539f\u5b50\uff0c\u901a\u8fc7\u6750\u6599\u4e2d\u6539\u53d8\u5176\u914d\u4f4d\u548c\/\u6216\u914d\u4f53\u6765\u4eba\u5de5\u8c03\u63a7\u5176\u4ef7\u7535\u5b50\u6240\u5360\u636e\u7684\u8f68\u9053\uff0c\u4ee5\u8fdb\u4e00\u6b65\u8c03\u63a7\u6750\u6599\u7279\u5b9a\u6027\u8d28\u7684\u65b9\u6cd5\u6216\u5177\u6709\u5176\u53ef\u884c\u6027\uff0c\u5e76\u6709\u671b\u4e3a\u672a\u6765\u6750\u6599\u76f8\u5173\u9886\u57df\u7814\u7a76\u4e2d\u7684\u62d3\u5c55\u65b0\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\n
<\/section>\n<\/section>\n
\n
\n
\n
\u8bba<\/strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n
\n
<\/section>\n<\/section>\n
\n
\n
\n
\n
<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
An Anomalous Electron Configuration Among 3d\u00a0Transition Metal Atoms<\/p>\n

Zhexin Tang,\u00a0Tongtong Shang,\u00a0Han Xu,\u00a0Ting Lin,\u00a0Ang Gao,\u00a0Weiguang Lin,\u00a0Xinyan Li,\u00a0Shiyu Wang,\u00a0Botao Yu,\u00a0Fanqi Meng,\u00a0Qinghua Zhang,\u00a0Xuefeng Wang,\u00a0Dong Su,\u00a0Qingbo Meng,\u00a0Lijun Wu,\u00a0Lin Gu,\u00a0Ce-Wen Nan<\/p>\n

Angewandte Chemie International Edition<\/em><\/p>\n

DOI:\u00a010.1002\/anie.202216898<\/p>\n<\/section>\n<\/section>\n<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u8fd1\u5e74\u6765\uff0c\u4ef7\u7535\u5b50\u5df2\u7ecf\u6210\u4e3a\u6750\u6599\u4f53\u7cfb\u4e2d\u65b0\u73b0\u8c61\u4e0e\u65b0\u6027\u8d28\u76f8\u5173\u7814\u7a76\u4e2d\u7684\u6838\u5fc3\u5173\u6ce8\u70b9\u4e4b\u4e00\u3002\u5df2\u6709\u7814\u7a76\u8868\u660e\uff0c\u8bf8\u591a\u7269\u7406\u4e0e\u5316\u5b66\u6027\u8d28\u5b9e\u8d28 […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47329","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47329","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47329"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47329\/revisions"}],"predecessor-version":[{"id":47330,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47329\/revisions\/47330"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47329"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47329"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47329"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}