{"id":47313,"date":"2023-03-02T08:07:47","date_gmt":"2023-03-02T00:07:47","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47313"},"modified":"2023-02-15T10:09:02","modified_gmt":"2023-02-15T02:09:02","slug":"%e5%ad%99%e6%99%93%e7%94%ab%e9%9f%a9%e5%b8%83%e5%85%b4%e9%99%a2%e5%a3%abam%ef%bc%9a%e4%b8%8d%e6%8c%91%e9%80%89%e7%8e%af%e5%a2%83%ef%bc%81%e5%8e%9f%e5%ad%90%e5%88%86%e6%95%a3ni-cu%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%ad%99%e6%99%93%e7%94%ab%e9%9f%a9%e5%b8%83%e5%85%b4%e9%99%a2%e5%a3%abam%ef%bc%9a%e4%b8%8d%e6%8c%91%e9%80%89%e7%8e%af%e5%a2%83%ef%bc%81%e5%8e%9f%e5%ad%90%e5%88%86%e6%95%a3ni-cu%e5%82%ac%e5%8c%96\/","title":{"rendered":"\u5b59\u6653\u752b&\u97e9\u5e03\u5174\u9662\u58ebAM\uff1a\u4e0d\u6311\u9009\u73af\u5883\uff01\u539f\u5b50\u5206\u6563Ni-Cu\u50ac\u5316\u5242\u7528\u4e8eCO2\u7535\u8fd8\u539f"},"content":{"rendered":"
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 <\/p>\n

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\"1\"<\/section>\n
\u5728\u65bd\u52a0\u7684\u7535\u4f4d\u4e0b\uff0c\u4ea7\u7269\u53ea\u80fd\u68c0\u6d4b\u5230CO\u548cH2<\/sub>\uff0c\u603b\u6cd5\u62c9\u7b2c\u6548\u7387(FEs)\u7ea6\u4e3a100%\u3002\u5728\u6536\u96c6\u7684\u7535\u89e3\u8d28\u4e2d\u6ca1\u6709\u68c0\u6d4b\u5230\u6db2\u4f53\u4ea7\u7269\u3002\u4e4b\u540e\u5728KHCO3<\/sub>\u6c34\u6eb6\u6db2(0.5 M)\u4e2d\u5bf9Cu\/Ni-NC\u548cNi-NC\u8fdb\u884c\u7535\u5316\u5b66\u6d4b\u8bd5\u4ee5\u8bc4\u4f30\u8d77\u59cb\u7535\u4f4d\u7684\u5dee\u5f02\u3002<\/section>\n
\u7ed3\u679c\u8868\u660e\uff0cCu\/Ni-NC\u5177\u6709\u6bd4Ni-NC\u66f4\u9ad8\u7684\u8d77\u59cb\u7535\u4f4d\u3002Cu\/Ni-NC\u548cNi-NC\u5728-0.8~-1.3 V(\u76f8\u5bf9\u4e8eRHE)\u7684\u7535\u4f4d\u8303\u56f4\u5185\u5747\u8868\u73b0\u51fa>95%\u7684FEs\uff0c\u5728-1.1 V\u65f6\u8fbe\u523099.1%\u7684\u6700\u5927FE\uff0c\u660e\u663e\u4f18\u4e8eCu-NC\u3002\u5728\u78b1\u6027(1M KOH\uff0cpH=14.0)\u548c\u4e2d\u6027(0.5 M KHCO3<\/sub>\uff0cpH=7.5)\u73af\u5883\u4e0b\u7684\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\u51fa\u7c7b\u4f3c\u7684\u8d8b\u52bf\u3002<\/section>\n
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\"2\"<\/section>\n
\u539f\u4f4d\u8868\u5f81\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0c\u91d1\u5c5eNi\u4f4d\u70b9\u662f\u7535\u89e3\u8fc7\u7a0b\u4e2d\u7684\u5438\u9644\u548c\u8f6c\u5316CO2<\/sub>\u7684\u6d3b\u6027\u4f4d\u70b9\u3002Cu\u53ef\u4ee5\u4fee\u9970Ni\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4fc3\u8fdbCO2<\/sub>\u6d3b\u5316\u548c*<\/sup>COOH\u7684\u751f\u6210\u3002\u7814\u7a76\u548c\u8868\u5f81\u8fd8\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86*<\/sup>COOH\u4e2d\u95f4\u4f53\u662f\u5728\u9178\u6027\u548c\u78b1\u6027\u6761\u4ef6\u4e0b\u901a\u8fc7\u4e0d\u540c\u7684\u8d28\u5b50\u5316\u9014\u5f84\u5f62\u6210\u7684\u3002<\/section>\n
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\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u6709\u524d\u666f\u7684\u5728\u5e7f\u6cdb\u7684pH\u8303\u56f4\u5185\u5c06CO2<\/sub>\u7535\u8fd8\u539f\u4e3aCO\u7684\u50ac\u5316\u5242\uff0c\u76f8\u4fe1\u8fd9\u5c06\u4e3a\u514b\u670d\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2dCO2<\/sub>\u7684\u635f\u8017\u63d0\u4f9b\u65b0\u7684\u601d\u8def\uff0c\u6ee1\u8db3\u5b9e\u9645\u5e94\u7528\u7684\u9700\u8981\u3002<\/section>\n
\"3\"<\/section>\n
Atomically Dispersed Ni-Cu Catalysts for pH-Universal CO2<\/sub>\u00a0Electroreduction,\u00a0Advanced Materials<\/em><\/strong>,\u00a02023<\/strong>, DOI: 10.1002\/adma.202209590.<\/section>\n
https:\/\/doi.org\/10.1002\/adma.202209590.<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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