{"id":47307,"date":"2023-03-01T08:49:23","date_gmt":"2023-03-01T00:49:23","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47307"},"modified":"2023-02-14T10:50:15","modified_gmt":"2023-02-14T02:50:15","slug":"angew-chem-%ef%bc%9a%e5%87%a0%e4%bd%95%e6%9e%84%e5%9e%8b%e4%be%9d%e8%b5%96%e7%9a%84%e5%8f%8c%e4%bd%8d%e7%82%b9%e5%90%b8%e9%99%84%e7%ab%9e%e4%ba%89%e4%bf%83%e8%bf%9b%e9%94%82%e7%a1%ab%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%87%a0%e4%bd%95%e6%9e%84%e5%9e%8b%e4%be%9d%e8%b5%96%e7%9a%84%e5%8f%8c%e4%bd%8d%e7%82%b9%e5%90%b8%e9%99%84%e7%ab%9e%e4%ba%89%e4%bf%83%e8%bf%9b%e9%94%82%e7%a1%ab%e7%94%b5\/","title":{"rendered":"Angew. Chem. \uff1a\u51e0\u4f55\u6784\u578b\u4f9d\u8d56\u7684\u53cc\u4f4d\u70b9\u5438\u9644\u7ade\u4e89\u4fc3\u8fdb\u9502\u786b\u7535\u6c60\u4e2d\u591a\u786b\u5316\u7269\u7684\u5438\u9644\u548c\u50ac\u5316\u8f6c\u5316"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u53d7\u9650\u4e8e\u591a\u786b\u5316\u7269\u4e25\u91cd\u7684\u7a7f\u68ad\u4ee5\u53ca\u8fdf\u7f13\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5c06\u591a\u786b\u5316\u7269\u7684\u201c\u5438\u9644-\u50ac\u5316\u8f6c\u5316\u201d\u9650\u57df\u5728\u50ac\u5316\u8f7d\u4f53\u4e2d\u80fd\u6709\u6548\u63d0\u5347\u9502\u786b\u7535\u6c60\u6d3b\u6027\u7269\u8d28\u7684\u5229\u7528\u7387\u3002\u6839\u636eSabatier\u5b9a\u5f8b\uff0c\u5355\u4e00\u6d3b\u6027\u4f4d\u70b9\u5f80\u5f80\u8f83\u96be\u5b9e\u73b0\u591a\u786b\u5316\u7269\u5438\u9644\u548c\u50ac\u5316\u8f6c\u5316\u7684\u52a8\u6001\u5e73\u8861\uff0c\u5de7\u5999\u6784\u7b51\u517c\u5177\u5f3a\u5438\u9644\u548c\u9ad8\u8f6c\u5316\u7684\u53cc\u6d3b\u6027\u4f4d\u70b9\u662f\u884c\u4e4b\u6709\u6548\u7684\u7b56\u7565\u3002\u56e0\u4e3a\u6d3b\u6027\u4f4d\u70b9\u7684\u7535\u5b50\u7ed3\u6784\u51b3\u5b9a\u4e86\u50ac\u5316\u5242\u672c\u5f81\u7684\u50ac\u5316\u6027\u80fd\uff0c\u56e0\u800c\u5b9e\u73b0\u4f4d\u70b9\u7535\u5b50\u7ed3\u6784\u7684\u7cbe\u51c6\u8c03\u63a7\u6709\u52a9\u4e8e\u7406\u89e3\u5185\u5728\u50ac\u5316\u6d3b\u6027\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u6784\u6548\u5173\u7cfb\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230210\/1675998396332964.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u5f20\u4eae\u6559\u6388\u8bfe\u9898\u7ec4\u4ee5\u5c16\u6676\u77f3\u4e3a\u7814\u7a76\u5bf9\u8c61\uff0c\u901a\u8fc7\u6784\u5efaMn<sub>Oh<\/sub>-O-Co<sub>Td<\/sub>\u7684\u51e0\u4f55\u6784\u578b\u5355\u5143\uff0c\u501f\u52a9\u540c\u6b65\u8f90\u5c04\u7b49\u591a\u5c3a\u5ea6\u8868\u5f81\u624b\u6bb5\uff0c\u7834\u8bd1\u51e0\u4f55\u6784\u578b\u4f9d\u8d56\u7684\u7535\u8377-\u81ea\u65cb-\u8f68\u9053\u8026\u5408\u89c4\u5219\uff0c\u6307\u5bfc\u57fa\u4e8e\u53cc\u4f4d\u70b9\u7ade\u4e89\u5438\u9644\u7684\u591a\u786b\u5316\u7269\u50ac\u5316\u8f6c\u5316\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230210\/1675998405100400.png\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5229\u7528\u540c\u6b65\u8f90\u5c04\u8c31\u5b66\u8868\u5f81\u6280\u672f\uff0c\u5b9a\u91cf\u9610\u660e\u4e0d\u540c\u9633\u79bb\u5b50\u7684\u9009\u62e9\u6027\u51e0\u4f55\u4f4d\u70b9\u5360\u636e\u5206\u5e03\uff0c\u6210\u529f\u5408\u6210\u4e86\u5bcc\u542bMn<sub>Oh<\/sub>-O-Co<sub>Td<\/sub>\uff08\u5176\u4e2dMn\u5360\u636e\u516b\u9762\u4f53\uff0cCo\u5360\u636e\u56db\u9762\u4f53\uff09\u9aa8\u67b6\u7684\u5375\u58f3\u72b6\u4e09\u91d1\u5c5e\u5c16\u6676\u77f3\u6c27\u5316\u7269\u7eb3\u7c73\u76d2\uff08CoFeMnO YSNCs\uff09\u3002\u57fa\u4e8e\u6b64\uff0c\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u7ed3\u5408\u5b9e\u9a8c\u9a8c\u8bc1\uff0c\u4ee5Mn<sub>Oh<\/sub>-O-Co<sub>Td<\/sub>\u4e3a\u7814\u7a76\u5bf9\u8c61\uff0c\u5206\u522b\u63a2\u7a76\u56db\u9762\u4f53\u548c\u516b\u9762\u4f53\u6784\u578b\u7684\u6d3b\u6027\u4f4d\u70b9\u4e0e\u591a\u786b\u5316\u7269\u4f5c\u7528\u7684\u7535\u8377-\u81ea\u65cb-\u8f68\u9053\u62d3\u6251\u8c03\u5236\u89c4\u5219\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0b\u96c6\u6210\u7cbe\u51c6\u8c03\u63a7\u51e0\u4f55\u6784\u578b\u4f9d\u8d56\u7684\u50ac\u5316\u6d3b\u6027\u7684\u666e\u9002\u6cd5\u5219\u3002<\/p>\n<p>\u7279\u522b\u5730\uff0c\u901a\u8fc7\u5bf9\u5177\u6709\u4e0d\u540c\u6784\u578b\u7684\u6d3b\u6027\u4f4d\u70b9\u7535\u5b50\u7ed3\u6784\u7684\u5408\u7406\u8bbe\u8ba1\uff0c\u5b9e\u73b0\u5dee\u5f02\u5316\u6027\u8d28\u8c03\u63a7\uff0c\u8fdb\u800c\u8d4b\u4e88\u7279\u5f02\u6027\u529f\u80fd\u5bfc\u5411\u3002\u7ed3\u679c\u8868\u660e\uff0c\u57fa\u4e8e\u81ea\u65cb\u8d85\u4ea4\u6362\u4f5c\u7528\u7684Mn<sub>Oh<\/sub>-O-Co<sub>Td<\/sub>\u9aa8\u67b6\u5145\u5206\u6fc0\u6d3b\u4e86\u4f4d\u70b9\u95f4\u7684\u7535\u8377\u8f6c\u79fb\uff1b\u5904\u4e8e\u56db\u9762\u4f53\u4e2d\u5fc3\u7684\u9ad8\u81ea\u65cbCo<sub>Td<\/sub>\u4ee5\u91d1\u5c5e-\u786b\u5171\u4ef7\u952e\u7684\u5f62\u5f0f\u5f3a\u529b\u5730\u951a\u5b9a\u591a\u786b\u5316\u7269\uff1b\u5904\u4e8e\u516b\u9762\u4f53\u4e2d\u5fc3\u7684\u5177\u6709\u59dc\u6cf0\u52d2\u6d3b\u6027\u7684Mn<sub>Oh<\/sub>\u80fd\u8bf1\u53d1\u8f68\u9053\u7279\u5f02\u6027\u7684\u591a\u786b\u5316\u7269\u8f6c\u5316\uff0c\u4e09\u8005\u534f\u540c\u5730\u5b9e\u73b0\u4e86\u591a\u786b\u5316\u7269\u5728Mn<sub>Oh<\/sub>-O-Co<sub>Td<\/sub>\u9aa8\u67b6\u4e0a\u7684\u5438\u9644\u548c\u50ac\u5316\u8f6c\u5316\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Cooperative Catalysis of Polysulfides in Lithium\u2013Sulfur Batteries through Adsorption Competition by Tuning Cationic Geometric Configuration of Dual-active Sites in Spinel Oxides<\/p>\n<p>Hongtai Li; Pei Shi; Lei Wang; Tianran Yan; Tong Guo; Xiao Xia; Chi Chen; Jing Mao; Dan Sun; Liang Zhang<\/p>\n<p>\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u82cf\u5dde\u5927\u5b66\u7684\u674e\u5b8f\u6cf0\u535a\u58eb\uff0c\u901a\u8baf\u4f5c\u8005\u662f\u82cf\u5dde\u5927\u5b66\u7684\u5f20\u4eae\u6559\u6388\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202216286<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u53d7\u9650\u4e8e\u591a\u786b\u5316\u7269\u4e25\u91cd\u7684\u7a7f\u68ad\u4ee5\u53ca\u8fdf\u7f13\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5c06\u591a\u786b\u5316\u7269\u7684\u201c\u5438\u9644-\u50ac\u5316\u8f6c\u5316\u201d\u9650\u57df\u5728\u50ac\u5316\u8f7d\u4f53\u4e2d\u80fd\u6709\u6548\u63d0\u5347\u9502\u786b\u7535\u6c60 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-47307","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47307","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47307"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47307\/revisions"}],"predecessor-version":[{"id":47308,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47307\/revisions\/47308"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47307"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47307"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47307"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}