{"id":47137,"date":"2023-02-15T08:58:15","date_gmt":"2023-02-15T00:58:15","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=47137"},"modified":"2023-01-31T15:59:13","modified_gmt":"2023-01-31T07:59:13","slug":"%e3%80%90acs-catal-%e3%80%91rieske%e5%9e%8b%e9%9d%9e%e8%a1%80%e7%ba%a2%e7%b4%a0%e9%93%81%e9%85%b6stc2%e5%82%ac%e5%8c%96%e7%9a%84%e5%85%89%e9%a9%b1%e5%8a%a8%e6%b0%a7%e5%8c%96%e8%84%b1%e7%94%b2%e5%9f%ba","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e3%80%90acs-catal-%e3%80%91rieske%e5%9e%8b%e9%9d%9e%e8%a1%80%e7%ba%a2%e7%b4%a0%e9%93%81%e9%85%b6stc2%e5%82%ac%e5%8c%96%e7%9a%84%e5%85%89%e9%a9%b1%e5%8a%a8%e6%b0%a7%e5%8c%96%e8%84%b1%e7%94%b2%e5%9f%ba\/","title":{"rendered":"\u3010ACS Catal.\u3011Rieske\u578b\u975e\u8840\u7ea2\u7d20\u94c1\u9176Stc2\u50ac\u5316\u7684\u5149\u9a71\u52a8\u6c27\u5316\u8131\u7532\u57fa\u53cd\u5e94"},"content":{"rendered":"

Rieske\u578b\u975e\u8840\u7ea2\u7d20\u94c1\u52a0\u6c27\u9176\/\u6c27\u5316\u9176\u50ac\u5316\u591a\u79cd\u751f\u7269\u8f6c\u5316\uff0c\u800c\u5728\u751f\u7269\u4fee\u590d\u6216\u751f\u7269\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u9762\u4e34\u4e24\u4e2a\u5173\u952e\u969c\u788d\uff1a\u9700\u8981\u6602\u8d35\u7684NAD(P)H\u4f5c\u4e3a\u8fd8\u539f\u5242\u548c\u9002\u5f53\u7684\u8fd8\u539f\u9176\u6765\u4ecb\u5bfcNAD(P)H\u5411\u52a0\u6c27\u9176\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u571f\u58e4\u7ec6\u83ccSinorhizobium meliloti<\/em>1021\u4f7f\u7528N\uff0cN-\u4e8c\u7532\u57fa\u812f\u6c28\u9178\u4f5c\u4e3a\u78b3\u6e90\u548c\u6c2e\u6e90\uff0c\u5728stachydrine\uff08\u6c34\u82cf\u78b1\uff09\u5206\u89e3\u4ee3\u8c22\u64cd\u7eb5\u5b50Stc2\/Stc3\/Stc4\u4e2d\uff0cStc2\u662fRieske\u578b\u52a0\u6c27\u9176\uff0cStc3\/Stc4\u662f\u63a8\u6d4b\u7684Stc2\u8fd8\u539f\u9176\u5bf9\u3002\u5728\u8bb8\u591aRieske\u578b\u52a0\u6c27\u9176\u4e2d\uff0c\u8fd8\u539f\u9176\u548c\u94c1\u6c27\u8fd8\u86cb\u767d\u878d\u5408\u4e3a\u4e00\u79cd\u86cb\u767d\u8d28\u3002\u6700\u8fd1\u7684\u6676\u4f53\u5b66\u7814\u7a76\u8868\u660e\uff0cStc2\u662f\u4e00\u79cd\u4ee5\u9996\u5c3e\u65b9\u5f0f\u6392\u5217\u7684\u4e09\u805a\u4f53\uff0c\u7c7b\u4f3c\u4e8e\u5176\u4ed6Rieske\u52a0\u6c27\u9176\u3002<\/p>\n

\"1\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aACS Catal.<\/p>\n

\u4e3a\u4e86\u7ed5\u8fc7\u8fd8\u539f\u9176\u548cNAD(P)H\u7684\u9700\u8981\uff0c\u4ee5Rieske\u578b\u52a0\u6c27\u9176Stc2\u50ac\u5316\u6c27\u5316\u8131\u7532\u57fa\u5316\u4f5c\u4e3a\u6a21\u578b\u7cfb\u7edf\uff0cBoston University\u7684\u5218\u5e73\u534e\u56e2\u961f\u53ca\u5176\u5408\u4f5c\u8005\u62a5\u9053\u4e86\u4f7f\u7528\u66d9\u7ea2Y\/\u4e9a\u786b\u9178\u76d0\u4f5c\u4e3a\u5149\u654f\u5242\/\u727a\u7272\u8bd5\u5242\u5bf9\u7684Stc2\u5149\u50ac\u5316\u3002<\/p>\n

\"2\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aACS Catal.<\/p>\n

\u5229\u7528\u6d41\u52a8\u5316\u5b66\u88c5\u7f6e\u5206\u79bb\u5149\u8fd8\u539f\u534a\u53cd\u5e94\u548c\u6c27\u5316\u534a\u53cd\u5e94\uff0c\u7ed3\u679c\u8868\u660eStc2\u5149\u751f\u7269\u50ac\u5316\u4f18\u4e8eStc2 – NAD(P)H-\u8fd8\u539f\u9176\uff08GbcB\uff09\u7cfb\u7edf\u3002<\/p>\n

\"3\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aACS Catal.<\/p>\n

\u6b64\u5916\uff0c\u5728\u4e00\u4e9b\u5176\u4ed6Rieske\u9176\uff08NdmA\u3001CntA\u548cGbcA\uff09\u548c\u9ec4\u7d20\u4f9d\u8d56\u6027\u9176\uff08\u7898\u916a\u6c28\u9178\u8131\u7898\u9176\uff0cIYD\uff09\u4e2d\uff0c\u66d9\u7ea2Y\/\u4e9a\u786b\u9178\u94a0\u5149\u8fd8\u539f\u5bf9\u4e5f\u53ef\u4ee5\u4f5c\u4e3aNAD(P)H-\u8fd8\u539f\u9176\u7684\u66ff\u4ee3\u7269\u6765\u8fdb\u884c\u50ac\u5316\uff0c\u8fd9\u6697\u793a\u4e86\u8be5\u5149\u8fd8\u539f\u7cfb\u7edf\u5bf9\u5176\u4ed6\u6c27\u5316\u8fd8\u539f\u9176\u7684\u6f5c\u5728\u9002\u7528\u6027\u3002<\/p>\n

\"4\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aACS Catal.<\/p>\n

\u539f\u6587\u6807\u9898\uff1aLight-Driven Oxidative Demethylation Reaction Catalyzed by a Rieske-Type Non-heme Iron Enzyme Stc2<\/p>\n

ACS Catal. 2022, 12, 14559\u221214570<\/p>\n

\u539f\u6587\u4f5c\u8005\uff1aWei-Yao Hu, Kelin Li, Andrew Weitz, Aiwen Wen, Hyomin Kim, Jessica C. Murray, Ronghai Cheng, Baixiong Chen, Nathchar Naowarojna, Mark W. Grinstaff, Sean J. Elliott,* Jie-Sheng Chen,* and Pinghua Liu*<\/p>\n","protected":false},"excerpt":{"rendered":"

Rieske\u578b\u975e\u8840\u7ea2\u7d20\u94c1\u52a0\u6c27\u9176\/\u6c27\u5316\u9176\u50ac\u5316\u591a\u79cd\u751f\u7269\u8f6c\u5316\uff0c\u800c\u5728\u751f\u7269\u4fee\u590d\u6216\u751f\u7269\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u9762\u4e34\u4e24\u4e2a\u5173\u952e\u969c\u788d\uff1a\u9700\u8981\u6602 […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[25],"tags":[],"class_list":["post-47137","post","type-post","status-publish","format-standard","hentry","category-cailiaoredian"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47137","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=47137"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47137\/revisions"}],"predecessor-version":[{"id":47138,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/47137\/revisions\/47138"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=47137"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=47137"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=47137"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}