{"id":17078,"date":"2018-01-29T17:07:47","date_gmt":"2018-01-29T09:07:47","guid":{"rendered":"http:\/\/www.chemhui.com\/?p=17078"},"modified":"2018-01-30T10:09:30","modified_gmt":"2018-01-30T02:09:30","slug":"17078","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/17078\/","title":{"rendered":"\u6d3b\u6027\u70ad\u5b54\u7ed3\u6784\u8c03\u63a7\u6280\u672f\u7814\u7a76\u8fdb\u5c55"},"content":{"rendered":"
\u4e0d\u540c\u5b54\u5f84\u7684\u70ad\u6750\u6599\u5e94\u7528\u9886\u57df\u4e5f\u4e0d\u4e00\u6837\uff0c\u56e0\u6b64\uff0c\u7cbe\u786e\u8c03\u8282\u5b54\u5f84\u4ee5\u6ee1\u8db3\u4e0d\u540c\u884c\u4e1a\u7684\u9700\u6c42\u53d8\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u4e3a\u9002\u5e94\u4e0d\u540c\u5e94\u7528\u9886\u57df\u7684\u8981\u6c42\uff0c\u56fd\u5185\u5916\u5b66\u8005\u7814\u7a76\u4e86\u5404\u79cd\u5de5\u827a\u548c\u6280\u672f\u6765\u5236\u5907\u70ad\u6750\u6599\u5e76\u63a7\u5236\u5176\u5b54\u9699\u7684\u6570\u91cf\u548c\u5c3a\u5bf8\u3002\u8fd1\u5e74\u6765\u7814\u7a76\u7684\u6d3b\u6027\u70ad<\/a>\u5b54\u5f84\u8c03\u63a7\u7814\u7a76\u6210\u4e3a\u70ed\u70b9\uff0c\u7814\u7a76\u7684\u65b0\u5de5\u827a\u53ef\u4ee5\u6ee1\u8db3\u5b54\u7ed3\u6784\u8c03\u63a7\u7684\u8981\u6c42\uff0c\u4f46\u5176\u5de5\u4e1a\u5e94\u7528\u6280\u672f\u4ecd\u6709\u5f85\u7a81\u7834\u3002<\/p>\n 1 \u6d3b\u5316\u6cd5<\/p>\n \u6d3b\u5316\u6cd5\u8c03\u63a7\u5b54\u7ed3\u6784\u901a\u5e38\u6709\u6c14\u4f53\u6d3b\u5316\u6cd5\u548c\u5316\u5b66\u6d3b\u5316\u6cd5\u4e24\u79cd\u3002\u6c14\u4f53\u6d3b\u5316\u6cd5\u4e00\u822c\u4f7f\u7528\u6c34\u84b8\u6c14\u3001 CO2\u3001\u7a7a\u6c14\uff08\u901a\u5e38\u4e0e\u5176\u4ed6\u6c14\u4f53\u6df7\u5408\uff09\u7b49\u6c27\u5316\u6c14\u4f53\uff1b\u5316\u5b66\u6d3b\u5316\u6cd5\u5e38\u4f7f\u7528\u78f7\u9178\u3001 ZnCl2 \u548cKOH \u4f5c\u4e3a\u6d3b\u5316\u5242\u3002\u5728\u6d3b\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5fae\u5b54\u5f62\u6210\u662f\u6700\u5173\u952e\u7684\u4e00\u6b65\u3002\u4f46\u662f\uff0c\u5728\u7edd\u5927\u90e8\u5206\u70ad\u6750\u6599\u4e2d\uff0c\u5927\u5b54\u3001\u4e2d\u5b54\u4e0e\u5fae\u5b54\u540c\u65f6\u5b58\u5728\uff0c\u5373\u6d3b\u5316\u8fc7\u7a0b\u4e2d\u5f97\u5230\u5927\u91cf\u5fae\u5b54\u7684\u540c\u65f6\u4e5f\u5f62\u6210\u4e86\u5f88\u591a\u5927\u5b54\u548c\u4e2d\u5b54\u3002\u5728\u5438\u9644\u548c\u8131\u9644\u8fc7\u7a0b\u4e2d\uff0c\u5927\u5b54\u4f5c\u4e3a\u901a\u9053\uff0c\u7ecf\u4e2d\u5b54\u8fc7\u6e21\uff0c\u6700\u540e\u8fdb\u5165\u5fae\u5b54\uff0c\u56e0\u6b64\u5fae\u5b54\u7684\u5438\u9644\u4f5c\u7528\u662f\u5728\u5927\u5b54\u7684\u901a\u9053\u4f5c\u7528\u548c\u4e2d\u5b54\u7684\u8fc7\u6e21\u4f5c\u7528\u57fa\u7840\u4e0a\u8fdb\u884c\u3002\u4ee5\u6930\u58f3\u3001\u6728\u5c51\u7b49\u751f\u7269\u8d28\u4e3a\u539f\u6599\u5236\u5907\u7684\u6d3b\u6027\u70ad\uff0c\u5927\u5b54\uff08 \u6709\u673a\u751f\u7269\u8d28\u7ec6\u80de\u7ed3\u6784\u7684\u4e00\u90e8\u5206\uff09\u5728\u70ad\u5316\u8fc7\u7a0b\u4e2d\u5df2\u7ecf\u5f62\u6210\uff0c\u6d3b\u5316\u5242\u5bb9\u6613\u6e17\u900f\u5165\u70ad\u5316\u6599\u5185\u90e8\uff0c\u56e0\u6b64\u6d3b\u5316\u65f6\u8f83\u5bb9\u6613\u5f97\u5230\u4e30\u5bcc\u7684\u5fae\u5b54\u3002<\/p>\n \u7814\u7a76\u8005\u5bf9\u7a7a\u6c14\u6c27\u5316\u6cd5\u6784\u9020\u70ad\u6750\u6599\u7eb3\u7c73\u5b54\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff0c\u4f7f\u7528\u6e29\u548c\u7684\u6e29\u5ea6\u8fdb\u884c\u6d3b\u5316\uff0c\u539f\u6599\u4e3a\u5e02\u573a\u4e0a\u8d2d\u5f97\u7684\u915a\u919b\u6811\u8102\u7403\u72b6\u70ad\uff08\u76f4\u5f84\u7ea6 15 \u03bcm\uff0c B.E.T \u6bd4\u8868\u9762\u79ef\u5f88\u5c0f\uff09\uff0c\u5e72\u7a7a\u6c14\u4f5c\u4e3a\u6d3b\u5316\u5242\uff0c\u91c7\u7528\u4e0d\u540c\u6d3b\u5316\u6e29\u5ea6\uff08 355\uff5e430 \u2103 \uff09\u3001\u4e0d\u540c\u505c\u7559\u65f6\u95f4\uff08 1\uff5e10 h\uff09\u8fdb\u884c\u6d3b\u5316\u3002\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u6c27\u5316\u7ed3\u679c\u8868\u660e\uff0c\u540c\u4e00\u6e29\u5ea6\u4e0b\u7684\u6c27\u5316\u7ed3\u679c\u4e0e\u505c\u7559\u65f6\u95f4\u5448\u5bf9\u6570\u5173\u7cfb\uff0c400 \u2103 \u4e0b\u6c27\u5316\u6548\u679c\u8f83\u4f73\u3002\u4f4d\u79fb\u56e0\u5b50\u4e0e\u6e29\u5ea6\u5448\u7ebf\u6027\u5173\u7cfb\uff0c\u6e29\u5ea6\u8d8a\u9ad8\u4f4d\u79fb\u56e0\u5b50\u8d8a\u5c0f\u3002\u5728\u6700\u521d\u76841 h\uff08 400 \u2103 \uff09\u6c27\u5316\u8fc7\u7a0b\u4e2d\uff0c\u9996\u5148\u5f62\u6210\u6781\u5fae\u5b54\uff1b\u81f3 6 h \u65f6\uff0c\u8d85\u6781\u5b54\u9010\u6e10\u51cf\u5c11\uff0c\u8d85\u5fae\u5b54\u9010\u6e10\u589e\u52a0\uff1b\u5f53\u6c27\u5316\u65f6\u95f4\u8d85\u8fc7 10 h \u65f6\uff0c\u6781\u5fae\u5b54\u548c\u8d85\u5fae\u5b54\u6570\u91cf\u90fd\u6025\u5267\u4e0b\u964d\uff0c\u4e2d\u5b54\u6570\u91cf\u5f00\u59cb\u7f13\u6162\u4e0a\u5347\uff0c\u6700\u7ec8\u5bfc\u81f4\u6bd4\u8868\u9762\u79ef\u964d\u4f4e\u3002 \u5728\u6c27\u5316\u7684\u6700\u521d 1 h \u5185 \uff08 400 \u2103 \uff09\uff0c B.E.T \u6bd4\u8868\u9762\u79ef\u4e0a\u5347\u81f3 400 m2\/g\uff0c \u5f62\u6210\u7684\u5b54\u9699\u5927\u90e8\u5206\u4e3a\u5fae\u5b54\u3002\u8fd9\u662f\u7531\u4e8e\u915a\u919b\u6811\u8102\u524d\u9a71\u4f53\u70ad\u5316\u8fc7\u7a0b\u4e2d\u5c01\u95ed\u5b54\u8f6c\u53d8\u4e3a\u5f00\u53e3\u5b54\u7684\u7f18\u6545\u3002\u5b9e\u9a8c\u8bc1\u660e\uff0c\u6c27\u5316\u53cd\u5e94\u9996\u5148\u53d1\u751f\u5728\u7403\u4f53\u8868\u9762\uff0c\u4f9d\u6b21\u901a\u8fc7\u5927\u5b54\u3001\u4e2d\u5b54\u3001\u5fae\u6700\u540e\u8fdb\u5165\u7403\u4f53\u5185\u90e8\u3002<\/p>\n \u6d3b\u5316\u8fc7\u7a0b\u5b58\u5728\u4ee5\u4e0b\u51e0\u4e2a\u7f3a\u70b9\uff1a 1\uff09\u4e2d\u5b54\u901a\u5e38\u662f\u5fae\u5b54\u6269\u5927\u540e\u5f97\u5230\u7684\uff0c\u5373\u4e2d\u5b54\u6d88\u8017\u4e86\u90e8\u5206\u5fae\u5b54\uff1b 2\uff09\u6d3b\u5316\u8fc7\u7a0b\u4e2d\u90e8\u5206\u78b3\u539f\u5b50\u6c14\u5316\u8f6c\u53d8\u6210 CO \u548c\uff08\u6216\uff09 CO2\uff0c\u5bfc\u81f4\u6d3b\u6027\u70ad\u6700\u7ec8\u5f97\u7387\u964d\u4f4e[36]\uff1b 3\uff09\u901a\u5e38\u6d3b\u5316\u8fc7\u7a0b\u9700\u8981\u6d88\u8017\u5927\u91cf\u7684\u9ad8\u6e29\u6c34\u84b8\u6c14\u6216\u5316\u5b66\u836f\u5242\u4f5c\u4e3a\u6d3b\u5316\u5242\u3002\u4e0a\u8ff0\u7f3a\u70b9\u5bfc\u81f4\u6d3b\u6027\u70ad\u751f\u4ea7\u6210\u672c\u5c45\u9ad8\u4e0d\u4e0b\uff0c\u4f46\u540c\u65f6\u4e5f\u4e3a\u5f00\u53d1\u591a\u5b54\u70ad\u6750\u6599\u5236\u5907\u65b0\u5de5\u827a\u63d0\u4f9b\u4e86\u7a81\u7834\u53e3\u3002<\/p>\n \u6c14\u4f53\u6c27\u5316\u4e24\u6b65\u6d3b\u5316\u6cd5\u8bf8\u591a\u6587\u732e\u4e2d\u90fd\u6709\u62a5\u5bfc\uff0c\u7b2c\u4e00\u6b65\u662f\u8f83\u77ed\u505c\u7559\u65f6\u95f4\u4e0b\u9ad8\u6e29\u5904\u7406\uff0c\u7b2c\u4e8c\u6b65\u662f\u4f4e\u6e29\u4e0b\u957f\u65f6\u95f4\u505c\u7559\u3002\u4ee5\u7403\u72b6\u70ad\u6d3b\u5316\u4e3a\u4f8b\uff0c \u9996\u5148\u5728 500 \u2103 \u4e0b\u505c\u7559 3 h\uff0c \u7b2c\u4e8c\u6b65\u5728 415 \u2103\u4e0b\u505c\u7559\u8f83\u957f\u65f6\u95f4\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5236\u5907\u76f8\u540c\u6bd4\u8868\u9762\u79ef\u7684\u4ea7\u54c1\u65f6\uff0c\u4e24\u6b65\u6d3b\u5316\u6cd5\u7684\u4ea7\u54c1\u5f97\u7387\u6bd4\u4e00\u6b65\u6cd5\u9ad8\u5c06\u8fd1 10 %\u3002<\/p>\n 2 \u6a21\u677f\u6cd5<\/p>\n \u7814\u7a76\u8005\u4f7f\u7528\u6a21\u677f\u70ad\u5316\u65b9\u6cd5\uff0c\u5c06\u6cb8\u77f3\u7eb3\u7c73\u901a\u9053\u4e2d\u7684\u70ad\u524d\u9a71\u4f53\u70ad\u5316\uff0c\u5f97\u5230\u7684\u6700\u5927\u6bd4\u8868\u9762\u79ef\u5c06\u8fd1 4000 m2\/g\uff0c\u6700\u5927\u5b54\u5bb9 1.8 mL\/g\u3002\u56e0\u4e3a\u6cb8\u77f3\u5b54\u9053\u7684\u5927\u5c0f\u548c\u5f62\u72b6\u53d6\u51b3\u4e8e\u5176\u6676\u4f53\u7ed3\u6784\uff0c\u5408\u6210\u7684\u70ad\u5b54\u9699\u5f62\u6001\u9057\u4f20\u6cb8\u77f3\u901a\u9053\u7684\u5f62\u6001\uff0c\u6240\u4ee5\u6a21\u677f\u6cd5\u5236\u5f97\u7684\u5fae\u5b54\u5c3a\u5bf8\u4e00\u81f4\u3001\u5747\u4e00\u6027\u597d\u3002Kyotani T \u7b49\u7814\u7a76\u4e86\u6a21\u677f\u6cd5\u5236\u5907\u5fae\u5b54\u4e30\u5bcc\u70ad\u6750\u6599\u7684\u5177\u4f53\u5236\u5907\u8fc7\u7a0b\u3002\u4f4e\u6e29\u771f\u7a7a\u4e0b\u5c06\u7ce0\u9187\uff08 FA\uff09\u6d78\u80f6\u6ce8\u5165\u6cb8\u77f3\u901a\u9053\u4e2d\uff0c\u7528\u7532\u82ef\u6d17\u53bb\u9644\u7740\u5728\u6cb8\u77f3\u5fae\u7c92\u8868\u9762\u7684\u591a\u4f59\u7ce0\u9187\uff0c 150 \u2103 \u4e0b\u505c\u7559 8 h\uff0c\u53ef\u6eb6\u6027\u7ce0\u9187\u4e0e\u6cb8\u77f3\u5fae\u7c92\u53d1\u751f\u805a\u5408\u53cd\u5e94\u6700\u7ec8\u5f97\u5230\u7ce0\u9187\u6cb8\u77f3\u590d\u5408\u7c92\u5b50\u3002 700 \u2103 \u4e0b\u70ad\u5316\uff0c\u7136\u540e\u7528 46 %\uff5e48 %\u7684 HF \u6eb6\u6db2\u5c06\u6cb8\u77f3\u6a21\u677f\u6eb6\u89e3\uff0c\u6700\u7ec8\u5f97\u5230\u7684\u70ad\u6750\u6599\u5fae\u5b54\u542b\u91cf\u4e30\u5bcc\uff0c\u70ad\u7684\u5fae\u5b54\u5b54\u5f84\u5747\u4e00\uff0c\u5c3a\u5bf8\u63a5\u8fd1 1.3 nm\u3002 X \u5c04\u7ebf\u884d\u5c04\u56fe\u4e2d\u5728 2\u03b8 <\/i>\u63a5\u8fd1 6\u00b0\u7684\u4f4d\u7f6e\u6709\u884d\u5c04\u5cf0\uff0c\u8be5\u4f4d\u7f6e\u4e0e\u6cb8\u77f3\u6a21\u677f\u7684 X \u5c04\u7ebf\u884d\u5c04\u7ed3\u679c\u4e00\u81f4\u3002<\/p>\n \u6bd4\u8f83\u6cb8\u77f3\u6a21\u677f\u6cd5\u5236\u5907\u7684\u70ad\uff08 ZTC\uff09\u3001\u5e02\u552e\u70ad\uff08 MSC-30\uff09\u3001\u6d3b\u6027\u70ad\u7ea4\u7ef4\uff08 A-20\uff09 3 \u79cd\u70ad\u6750\u6599\u7684 N2 \u7b49\u6e29\u5438\u9644-\u8131\u9644\u548c\u5b54\u5f84\u5206\u5e03\u3002 ZTC \u5fae\u5b54\u4e30\u5bcc\uff0c\u6bd4\u8868\u9762\u79ef\u8fdc\u9ad8\u4e8e\u53e6\u5916 2 \u79cd\uff0c\u4e2d\u5b54\u6570\u91cf\u5f88\u5c11\uff0c\u4e14\u5236\u5907\u8fc7\u7a0b\u4e0d\u9700\u8981\u6d3b\u5316\u3002\u5176\u4e2d MSC-30 \u662f\u5e02\u552e\u4e2d\u5b54\u70ad\u6bd4\u8868\u9762\u79ef\u6700\u9ad8\u7684\u4e00\u79cd\u3002\u6781\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u8bf4\u660e\u70ad\u6750\u6599\u5b58\u5728\u5f2f\u66f2\u8868\u9762\uff0c\u7814\u7a76\u8005\u7528\u5de8\u6b63\u5219\u7cfb\u7efc\u8499\u7279\u5361\u7f57\u6a21\u62df\u6cd5\u5df2\u7ecf\u8bc1\u5b9e\u4e86\u8be5\u7406\u8bba\u3002<\/p>\n \u5c06\u70ed\u5851\u6027\u524d\u4f53\uff08\u5982\u805a\u4e59\u70ef\u9187 PVA\u3001\u7f9f\u4e19\u57fa\u7ea4\u7ef4\u7d20 HPC \u7b49\uff09\u8fdb\u884c\u70ed\u5904\u7406\uff0c\u4f7f\u5176\u6536\u7f29\u8fdb\u5165\u5404\u79cd\u9676\u74f7\u4e0e\u4e4b\u5171\u5b58\uff0c\u8fd9\u6837\u5c31\u80fd\u8986\u76d6\u9676\u74f7\u5fae\u7c92\u4ece\u800c\u5f97\u5230\u8f83\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u591a\u5b54\u70ad\u3002\u5b9e\u9a8c\u4e2d\u4f7f\u7528 MgO \u4f5c\u4e3a\u9676\u74f7\u57fa\u677f\uff0c\u5c06 PVC \u524d\u4f53\u52a0\u70ed\u81f3 900 \u2103 \uff0c\u6700\u540e\u7528\u7a00\u9178\u6eb6\u89e3 MgO \u57fa\u677f\uff0c\u83b7\u5f97\u5206\u5b50\u7b5b\u578b\u6d3b\u6027\u70ad\u3002<\/p>\n \u7528 \u03b1S-plot \u548c N2 \u7b49\u6e29\u5438\u9644\u6cd5\u5206\u6790\u7531\u918b\u9178\u9541\uff08\u67e0\u6aac\u9178\u9541\uff09\u4e0e PVC \u5728\u6c34\u6eb6\u6db2\u4e2d\u6df7\u5408\u5236\u5907\u7684\u591a\u5b54\u70ad\u7ed3\u6784\u3002 \u591a\u5b54\u70ad\u4e2d\u5b54\u5c3a\u5bf8\u5927\u5c0f\u51e0\u4e4e\u4e0e MgO \u5fae\u7c92 \uff08\u7531\u9541\u5316\u5408\u7269\u7ecf\u70ed\u89e3\u5f97\u5230\uff09\u4e00\u6837\u3002<\/p>\n \u4f7f\u7528\u77e9\u5f62\u5f62\u6001\u7684 MgO \u5fae\u7c92\uff0c SEM \u8868\u5f81\u7ed3\u679c\u663e\u793a\u6240\u5408\u6210\u7684\u70ad\u4e5f\u5177\u6709\u540c\u6837\u5c3a\u5bf8\u7684\u77e9\u5f62\u5b54\u3002\u7528 DFT\u3001 BJH \u65b9\u6cd5\u8868\u5f81\u5fae\u5b54\u3001\u4e2d\u5b54\u7684\u5b54\u5f84\u5206\u5e03\u60c5\u51b5\u3002\u7ed3\u679c\u5982\u4e0b\uff1a MgO \u5fae\u7c92\u8868\u9762\u6613\u5f62\u6210\u5fae\u5b54\uff0c\u5c3a\u5bf8\u5927\u90e8\u5206\u5728 1 nm \u9644\u8fd1\u3002\u4e2d\u5b54\u5927\u5c0f\u53d6\u51b3\u4e8e\u52a0\u5165\u7684 MgO \u524d\u4f53\uff1a\u918b\u9178\u9541\u4e0e PVC \u6df7\u5408\u6db2\u5236\u5f97\u7684\u4e2d\u5b54\u5b54\u5f84\u7ea6 10 nm\uff1b\u67e0\u6aac\u9178\u9541\u4e0e PVC \u6df7\u5408\u6db2\u5236\u5907\u7684\u4e2d\u5b54\u5b54\u5f84\u5728 5 nm \u5de6\u53f3\uff1b\u7531\u8461\u7cd6\u9178\u9541\u5f97\u5230\u7684\u4e2d\u5b54\u5b54\u5f84\u5728 2\uff5e4 nm \u4e4b\u95f4\u3002\u7531\u918b\u9178\u9541\u3001 PVC \u6df7\u5408\u6db2\u6240\u5f97\u4e2d\u5b54\u5b54\u5f84\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f9d\u8d56\u4e8e\u6df7\u5408\u65b9\u6cd5\uff1a\u7c89\u672b\u6df7\u5408\u5f97\u5230\u7684\u4e2d\u5b54\u5b54\u5f84\u5206\u5e03\u8303\u56f4\u8f83\u5bbd\uff0c\u6eb6\u6db2\u6df7\u5408\u6240\u5f97\u4e2d\u5b54\u5b54\u5f84\u96c6\u4e2d\u5728 10 nm \u5de6\u53f3\u3002\u800c\u4f7f\u7528\u67e0\u6aac\u9178\u9541\u5219\u4e24\u79cd\u6df7\u5408\u65b9\u6cd5\u6240\u5f97\u4e2d\u5b54\u5c3a\u5bf8\u4e00\u81f4\u3002\u7528 MgO \u4f5c\u57fa\u677f\u8fd8\u6709\u4e00\u4e2a\u597d\u5904\uff0c MgO \u5728\u5e38\u6e29\u4e0b\u7528 1 mol\/L \u7684\u7a00\u67e0\u6aac\u9178\u5373\u53ef\u6eb6\u89e3\uff0c\u6613\u4e8e\u56de\u6536\u3002<\/p>\n \u7814\u7a76\u8005\u4ee5\u6c22\u6c27\u5316\u954d\u4e3a\u6a21\u677f\u5236\u5907\u5f97\u5230\u4e86\u540c\u65f6\u542b\u6709\u5fae\u5b54\u548c\u4e2d\u5b54\u7684\u591a\u5b54\u70ad\u3002\u8be5\u5236\u5907\u65b9\u6cd5\u5f97\u5230\u7684\u591a\u5b54\u70ad\u6bd4\u8868\u9762\u79ef\u4e3a 970 2\/g\uff0c\u5b54\u5bb9\u79ef\u4e3a 0.69 mL\/g\uff0c\u5176\u4e2d\u5fae\u5b54\u5b54\u5bb9\u4e3a 0.3 mL\/g\uff0c\u5fae\u5b54\u5b54\u5f84\u5927\u90e8\u5206\u5728 0.8 nm \u5de6\u53f3\uff0c\u4e2d\u5b54\u5b54\u5f84\u5219\u591a\u6570\u5904\u4e8e 15 nm \u9644\u8fd1\u3002<\/p>\n 3 \u70ad\u6c14\u51dd\u80f6\u6cd5<\/p>\n \u70ad\u6c14\u51dd\u80f6\u662f\u4e00\u79cd\u5e38\u7528\u7684\u4e2d\u5b54\u70ad\uff0c\u7531\u6709\u673a\u51dd\u80f6\u7ecf\u8d85\u4e34\u754c\u5e72\u71e5\u3001\u70ad\u5316\u800c\u6210\u3002\u5927\u91cf\u7814\u7a76\u96c6\u4e2d\u5728\u70ad\u6c14\u51dd\u80f6\u7684\u5b54\u7ed3\u6784\u6216\u8005\u5728\u5176\u4e2d\u63ba\u6742\u4e00\u4e9b\u91d1\u5c5e\u3002<\/p>\n \u70ad\u6c14\u51dd\u80f6\u7684\u5b54\u7ed3\u6784\u51b3\u5b9a\u4e8e\u6709\u673a\u51dd\u80f6\u524d\u9a71\u4f53\uff0c\u800c\u6709\u673a\u51dd\u80f6\u524d\u4f53\u7684\u7ed3\u6784\u540c\u65f6\u53d7\u5230\u95f4\u82ef\u4e8c\u915a\u4e0e\u7532\u919b\uff08 R\/F\uff09\u3001\u95f4\u82ef\u4e8c\u915a\u4e0e\u6c34(R\/W)\u3001\u95f4\u82ef\u4e8c\u915a\u4e0e\u78b1\u6027\u50ac\u5316\u5242 Na2CO3(R\/C)\u7684\u6469\u5c14\u6bd4\u5f71\u54cd\u3002\u5408\u6210\u6c34\u51dd\u80f6\u7ecf CO2 \u8d85\u4e34\u754c\u5e72\u71e5\uff0c\u8131\u9664\u5b54\u9699\u95f4\u7684\u6c34\uff0c\u5373\u53ef\u5f97\u5230\u7f51\u72b6\u7ed3\u6784\u7684\u6709\u673a\u6c14\u51dd\u80f6\u3002\u5c06\u539f\u6709\u6709\u673a\u6c14\u51dd\u80f6\u548c\u5408\u6210\u70ad\u6c14\u51dd\u80f6\u4e2d\u5b54\u533a\u57df\u5b54\u5f84\u5206\u5e03\u4e0e R\/W \u4e4b\u95f4\u7684\u51fd\u6570\u5173\u7cfb\u8fdb\u884c\u5bf9\u6bd4\uff08 R\/F \u548c R\/C \u5206\u522b\u4e3a\u5e38\u6570 0.5 \u548c 75\uff09\u3002\u7ed3\u679c\u8868\u660e\uff0c\u539f\u6709\u6709\u673a\u6c14\u51dd\u80f6\u5b54\u5f84\u5206\u5e03\u8303\u56f4\u8f83\u7a84\uff0c\u4e14\u968f\u7740 R\/W \u6bd4\u7387\u589e\u5927\uff0c\u5176\u6700\u5927\u503c\u9010\u6e10\u51cf\u5c0f\uff1b\u8fd9\u4e9b\u6709\u673a\u6c14\u51dd\u80f6\u7ecf\u70ad\u5316\u5f97\u5230\u7684\u70ad\u6c14\u51dd\u80f6\u5b54\u5f84\u5c3a\u5bf8\u7565\u5c0f\uff0c\u8fd9\u4e3b\u8981\u662f\u7531\u4e8e\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u51dd\u80f6\u6536\u7f29\u7684\u7f18\u6545\u3002 \u5c06\u70ad\u6c14\u51dd\u80f6\u5728 900 \u2103 \u4e0b\u901a CO2 \u6c14\u4f53\uff0c\u505c\u7559 1\uff5e7 h\uff0c\u70ad\u6c14\u51dd\u80f6\u4e0e CO2 \u53d1\u751f\u6d3b\u5316\u53cd\u5e94\uff0c\u6700\u7ec8\u5f97\u5230\u5fae\u5b54\u542b\u91cf\u4e30\u5bcc\u7684\u6d3b\u6027\u70ad\u3002\u6d3b\u5316\u81f3 5 h \u65f6\uff0c\u5fae\u5b54\u548c\u4e2d\u5b54\u540c\u65f6\u589e\u52a0\uff0c\u5b54\u5bb9\u79ef\u5206\u522b\u4e3a0.68 mL\/g \u548c 2.04 mL\/g\uff0c\u6bd4\u8868\u9762\u79ef\u5206\u522b\u4e3a 1750 m2\/g \u548c 510 m2\/g\u3002<\/p>\n Tamon \u548c Hamzawa \u7b49\u5c06\u6811\u8102\u915a(R)\u548c\u7532\u919b(F)\u7684\u6c34\u6eb6\u6db2\u4fdd\u5b58\u5728 20 \u2103 \u7684\u73bb\u7483\u5bb9\u5668\u4e2d\uff0c\u4f7f R \u548c F \u5171\u805a\u5408\u51dd\u80f6\uff0c\u53d1\u751f\u7c07\u72b6\u6784\u9020\u548c\u51dd\u80f6\u4f5c\u7528\u3002\u4e3a\u4e86\u4fdd\u6301\u6eb6\u80f6\u7684\u7f51\u72b6\u7ed3\u6784\u548c\u5728\u5e72\u71e5\u8fc7\u7a0b\u4f7f\u5176\u6536\u7f29\u6700\u5c0f\uff0c\u518d\u91c7\u7528 CO2 \u8d85\u4e34\u754c\u5e72\u71e5\uff0c\u7136\u540e\u5c06\u6709\u673a\u6c14\u51dd\u80f6\u5728 1000 \u2103 \u70ad\u5316\uff0c\u5728 900 \u2103\u65f6\u901a CO2 \u6d3b\u5316\uff0c\u5f97\u5230\u517c\u5177\u5fae\u5b54\u548c\u4e2d\u5b54\u7684\u6d3b\u6027\u70ad\u3002<\/p>\n \u6709\u7814\u7a76\u8005\u4f7f\u7528\u51b7\u51bb\u5e72\u71e5\u6cd5\u4ee3\u66ff\u8d85\u4e34\u754c\u5e72\u71e5\u6cd5\u5236\u5907\u51fa\u4e86\u70ad\u6c14\u51dd\u80f6\u3002\u51b7\u51bb\u5e72\u71e5\u6cd5\u53ef\u4ee5\u5927\u5927\u51cf\u5c11\u51dd\u80f6\u5728\u70ad\u5316\u8fc7\u7a0b\u4e2d\u7684\u6536\u7f29\u7a0b\u5ea6\u3002\u56e0\u6b64\uff0c\u5bf9\u6eb6\u80f6-\u51dd\u80f6\u7f29\u5408\u6cd5\u5f97\u5230\u95f4\u82ef\u4e8c\u915a-\u7532\u919b\u51dd\u80f6\u7684\u5236\u5907\u5de5\u827a\u53ca\u51b7\u51bb\u5e72\u71e5\u6761\u4ef6\u8fdb\u884c\u7814\u7a76\uff0c \u4ee5\u8fbe\u5230\u63a7\u5236\u70ad\u6c14\u51dd\u80f6\u4e2d\u5b54\u7387\u7684\u76ee\u7684\u3002\u540c\u65f6\u7814\u7a76\u4e86\u51b7\u51bb\u5e72\u71e5\u3001\u5fae\u6ce2\u5e72\u71e5\u3001 \u70ed\u7a7a\u6c14\u5e72\u71e5\u4e09\u79cd\u4e0d\u540c\u5e72\u71e5\u65b9\u6cd5\u5bf9\u5b54\u7ed3\u6784\u7684\u5f71\u54cd\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u524d\u4e24\u79cd\u5e72\u71e5\u65b9\u6cd5\u662f\u5236\u5907\u4e2d\u5b54\u70ad\u7684\u6709\u6548\u9014\u5f84\u3002\u95f4\u82ef\u4e8c\u915a-\u7532\u919b\u51b7\u51bb\u51dd\u80f6\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u524d\u9a71\u4f53\u5236\u5907\u5f97\u5230\u4e2d\u5b54\u70ad\u3002\u5408\u6210\u7684\u70ad\u5b54\u7ed3\u6784\u53d7\u6eb6\u6db2 pH \u503c\u7684\u5f71\u54cd\uff0c R\/C \u6bd4\u7387\u4e0d\u540c\uff0c\u6eb6\u6db2\u7684 pH\u503c\u4e5f\u4e0d\u540c\uff0c\u5373\u5408\u6210\u70ad\u7684\u5b54\u7ed3\u6784\u4e0e R\/C \u6bd4\u7387\u6709\u4e00\u5b9a\u5173\u7cfb\u3002\u5f53 pH \u503c\u4e3a8.0 \u65f6\uff08 R\/C=25\uff09\uff0c\u5f97\u5230\u7684\u70ad\u6ca1\u6709\u5b54\uff1b pH \u503c\u5728 7.0\uff5e8.0 \u4e4b\u95f4\u65f6\u624d\u4f1a\u5f62\u6210\u591a\u5b54\u70ad\uff0c\u4e3b\u8981\u96c6\u4e2d\u5728 pH \u503c 7.3\uff5e7.7 \u8303\u56f4\u5185\u3002\u70ad\u6c14\u51dd\u80f6\u53ef\u4f5c\u4e3a\u6a21\u677f\u5236\u5907\u4e2d\u5b54\u901a\u9053\u89c4\u6574\u7684\u9ad8\u7ed3\u6676\u6cb8\u77f3\uff08 ZSM-5 \u548c Y \u578b\u5206\u5b50\u7b5b\uff09\u3002<\/p>\n 4 \u805a\u5408\u7269\u5171\u6df7\u6cd5<\/p>\n \u805a\u5408\u7269\u5171\u6df7\u6cd5\u53ef\u7528\u6765\u5236\u5907\u5404\u79cd\u4e0d\u540c\u5b54\u5f84\u7684\u70ad\u6750\u6599\u3002\u805a\u5408\u7269\u4e2d\u4e00\u79cd\u4e3a\u78b3\u542b\u91cf\u9ad8\u7684\u805a\u5408\u7269\uff0c\u5982\u805a\u5408\u7ce0\u9187\uff1b\u53e6\u5916\u4e00\u79cd\u5219\u4e3a\u78b3\u542b\u91cf\u4f4e\u7684\u805a\u5408\u7269\uff0c\u5982\u805a\u4e59\u70ef\u3002 Hulicova D \u7b49\u7814\u7a76\u4e86\u70ad\u6c14\u56ca\u3001\u70ad\u5fae\u7c92\u3001\u591a\u5b54\u70ad\u7684\u805a\u5408\u7269\u5171\u6df7\u6cd5\u5236\u5907\u65b9\u6cd5\uff0c\u5f00\u53d1\u4e86\u805a\u5408\u7269\u6df7\u7eba\u65b9\u6cd5\uff0c\u5e76\u6210\u529f\u5236\u5907\u51fa\u70ad\u7eb3\u7c73\u7ea4\u7ef4\u3002<\/p>\n \u5305\u4e3d\u9896\u7b49\u4ee5\u915a\u919b\u6811\u8102\u4e3a\u524d\u9a71\u4f53\uff0c\u4ee5\u805a\u4e59\u4e8c\u9187\u4e3a\u9020\u5b54\u5242\uff0c\u91c7\u7528\u805a\u5408\u7269\u5171\u6df7\u6cd5\u5f97\u5230\u4e2d\u5b54\u7387\u4e3a 59.7 %\u7684\u6d3b\u6027\u70ad\u3002\u6bd4\u7535\u5bb9\u4e3a 32 F\/g\uff0c\u5927\u7535\u6d41\u6027\u80fd\u548c\u5faa\u73af\u6027\u826f\u597d\uff0c\u4f7f\u5f97\u8fd9\u79cd\u6750\u6599\u53ef\u4f5c\u7535\u6781\u6750\u6599\u5236\u5907\u8d85\u7ea7\u7535\u5bb9\u5668\u3002\u4ee5\u7ce0\u919b\u6811\u8102\u3001\u7ce0\u9187\u4e3a\u524d\u9a71\u4f53\uff0c\u4e59\u4e8c\u9187\u4e3a\u9020\u5b54\u5242\uff0c\u82ef\u78fa\u9178\u4e3a\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u8c03\u8282\u7ce0\u919b\u6811\u8102\u3001\u7ce0\u9187\u3001\u4e59\u4e8c\u9187\u7684\u6bd4\u4f8b\u6765\u63a7\u5236\u6d3b\u6027\u70ad\u7684\u5b54\u5f84\u7ed3\u6784\uff0c\u5f97\u5230\u5e73\u5747\u5b54\u5f84\u4ecb\u4e8e0.008\uff5e5\u03bcm \u4e4b\u95f4\u7684\u6d3b\u6027\u70ad\u3002<\/p>\n \u805a\u6c28\u916f-\u9170\u4e9a\u80fa\u8584\u819c\u7ecf\u70ad\u5316\u53ef\u5f97\u5230\u70ad\u819c\uff0c\u901a\u8fc7\u6539\u53d8\u805a\u6c28\u916f\u9884\u805a\u4f53\u5206\u5b50\u7ed3\u6784\u53ef\u4ee5\u63a7\u5236\u78b3\u8584\u819c\u5927\u5b54\u7684\u7ed3\u6784\u3002\u7531\u805a\u6c28\u916f\uff08 PU\uff09\u5f97\u5230\u805a\u9170\u4e9a\u80fa\uff08 PI\uff09\uff0c\u518d\u5c06\u5176\u4e0e\u805a\u6c28\u9178\u6df7\u5408\u53cd\u5e94\u4ece \u800c\u5f97\u5230\u805a\u6c28\u9178-\u9170\u4e9a\u80fa\uff08 PUI\uff09\u8584\u819c\u3002\u5c06 PUI \u52a0\u70ed\u81f3 200 \u2103 \u65f6\u4f1a\u751f\u6210 PI \u548c PU\uff0c\u524d\u8005\u4f1a\u5f62\u6210\u57fa\u4f53\uff0c\u540e\u8005\u5219\u6210\u4e3a\u4e00\u4e2a\u4e2a\u5c0f\u5c9b\u72b6\u7269\u8d28\u3002\u5f53\u70ed\u5904\u7406\u6e29\u5ea6\u5347\u5230 400 \u2103 \u65f6\uff0c PU \u5316\u5408\u7269\u5c06\u70ed\u89e3\u53d8\u6210\u6c14\u4f53\u6700\u7ec8\u5bfc\u81f4 PI \u8584\u819c\u4e0a\u5f62\u6210\u5b54\u72b6\u7ed3\u6784\uff0c\u7ecf\u70ad\u5316\u540e\u8f83\u5bb9\u6613\u5f97\u5230\u70ad\u8584\u819c\u3002\u8be5\u70ad\u8584\u819c\u7684\u5b54\u5f84\u4e0e PI\u3001 PU \u6df7\u5408\u6bd4\u7387\u53ca PU \u5206\u5b50\u7ed3\u6784\u6709\u5173\u3002<\/p>\n 5 \u9009\u62e9\u7279\u5b9a\u524d\u9a71\u4f53\u65b9\u6cd5<\/p>\n \u9664\u4e0a\u8ff0\u51e0\u79cd\u56e0\u7d20\u5916\uff0c\u70ad\u524d\u9a71\u4f53\u7684\u6027\u8d28\u4e5f\u662f\u5f71\u54cd\u6d3b\u6027\u70ad\u6027\u80fd\u7684\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u4e0d\u540c\u7279\u5f81\u7684\u524d\u9a71\u4f53\u5236\u5907\u7684\u70ad\u6750\u6599\u5b54\u5f84\u5206\u5e03\u4e5f\u6709\u6240\u4e0d\u540c\u3002\u6587\u732e\u62a5\u9053\uff0c\u4ee5\u7ea2\u9ebb\uff08\u53c8\u79f0\u5927\u9ebb\u69ff\uff09\u5236\u6210\u7684\u6d3b\u6027\u70ad B.E.T \u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe 2700 m2\/g\uff0c ,\u7ecf 450 \u2103 \u4f4e\u6e29\u70ad\u5316\u5236\u5907\u9ebb\u70ad\u524d\u9a71\u4f53\uff0c\u5728\u7ecf\u9ad8\u6e29\u70ad\u5316\u5904\u7406\u5373\u53ef\u5f97\u5230\u4ea7\u54c1[62]\u3002\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u539f\u6599\u4e2d\u7684\u91d1\u5c5e\u6742\u8d28\uff08\u4e3b\u8981\u662f K\uff09\u5728\u70ad\u5316\u8fc7\u7a0b\u4e2d\u88ab\u6d17\u9664\u3002\u4ee5\u67cf\u6728\u7247\u4e3a\u539f\u6599\uff0c\u8fde\u7eed\u901a\u5165\u8fc7\u70ed\u84b8\u6c14\u8fdb\u884c\u70ed\u5904\u7406\uff0c\u6210\u529f\u5236\u5907\u51fa\u591a\u5b54\u70ad\u3002\u6539\u53d8\u70ad\u5316\u5de5\u827a\u6761\u4ef6\uff08\u8fc7\u70ed\u84b8\u6c14\u6e29\u5ea6\u3001 \u6728\u7247\u7528\u91cf\u3001\u6728\u7247\u8f6c\u79fb\u7387\uff09\u53ef\u4ee5\u63a7\u5236\u67cf\u6728\u70ad\u7684\u5b54\u7ed3\u6784\uff0c\u7814\u7a76\u79f0\uff0c\u5fae\u5b54\u6bd4\u8868\u9762\u79ef\u3001\u5916\u6bd4\u8868\u9762\u79ef\u3001\u603b\u6bd4\u8868\u9762\u79ef\u4e0e\u70ad\u5316\u6e29\u5ea6\uff08\u5373\u8fc7\u70ed\u84b8\u6c14\u7684\u6e29\u5ea6\uff09\u4e4b\u95f4\u5b58\u5728\u4e00\u5b9a\u7684\u51fd\u6570\u5173\u7cfb\u3002 800 \u2103 \u70ad\u5316\u6e29\u5ea6\u4e0b\uff0c\u5f97\u5230\u7684\u6728\u70ad\u4e2d\u5b54\u6570\u91cf\u8f83\u591a\uff0c\u5176\u5fae\u5b54\u6bd4\u8868\u9762\u79ef\u7ea6500 m2\/g\uff1b\u5f53\u70ad\u5316\u6e29\u5ea6\u8d85\u8fc7 900 \u2103 \u65f6\u5c06\u5f97\u5230\u5fae\u5b54\u4e30\u5bcc\u7684\u6728\u70ad\uff0c\u5176\u5fae\u5b54\u6bd4\u8868\u9762\u79ef\u63a5\u8fd1 900m2\/g\u3002<\/p>\n <\/p>\n <\/p>\n \u4e0d\u540c\u5b54\u5f84\u7684\u70ad\u6750\u6599\u5e94\u7528\u9886\u57df\u4e5f\u4e0d\u4e00\u6837\uff0c\u56e0\u6b64\uff0c\u7cbe\u786e\u8c03\u8282\u5b54\u5f84\u4ee5\u6ee1\u8db3\u4e0d\u540c\u884c\u4e1a\u7684\u9700\u6c42\u53d8\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u4e3a\u9002\u5e94\u4e0d\u540c\u5e94\u7528\u9886\u57df\u7684\u8981\u6c42 […]<\/p>\n","protected":false},"author":36,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[24],"tags":[],"class_list":["post-17078","post","type-post","status-publish","format-standard","hentry","category-huoxingtan"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/17078","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/36"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=17078"}],"version-history":[{"count":2,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/17078\/revisions"}],"predecessor-version":[{"id":17100,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/17078\/revisions\/17100"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=17078"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=17078"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=17078"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\n\u5bf9\u4f53\u79ef\u5bc6\u5ea6\u4e3a 0.4 g\/cm\u7684\u70ad\u51dd\u80f6\u8fdb\u884c TEM \u5206\u6790\u77e5\uff0c\u5927\u90e8\u5206\u70ad\u5fae\u7c92\u5c3a\u5bf8\u5927\u5c0f\u5728 4\uff5e9 nm\u4e4b\u95f4\uff0c\u7c92\u5b50\u95f4\u76f8\u4e92\u8fde\u63a5\u5f62\u6210\u7f51\u72b6\u7ed3\u6784\u3002\u7b49\u6e29\u5438\u9644\u66f2\u7ebf\u5c5e\u4e8e\u7b2c\u2163 \u7c7b\u66f2\u7ebf\uff0c\u6709\u660e\u663e\u7684\u6ede\u540e\u73af\u3002\u7531\u95f4\u82ef\u4e8c\u915a\u548c\u7532\u919b\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5236\u5f97\u4e00\u7cfb\u5217\u70ad\u6c14\u51dd\u80f6\uff0c\u6240\u5f97\u5b54\u9699\u4ee5\u4e2d\u5b54\u4e3a\u4e3b\uff0c\u8fd9\u4e9b\u4e2d\u5b54\u662f\u7531\u70ad\u5fae\u7c92\u76f8\u4e92\u8fde\u63a5\u5f62\u6210\u4e09\u7ef4\u7f51\u7edc\u800c\u6784\u6210\u7684\uff0c\u4ec5\u6709\u5c11\u91cf\u7c92\u5185\u5fae\u5b54\u5728\u4e00\u6b21\u70ad\u7c92\u5b50\u4e4b\u95f4\u5f62\u6210\u3002<\/p>\n\u7279\u6b8a\u78b3\u6750\u6599<\/h4>\n
\n